Citation: Xingyuan Gao, Huilin Deng, Yuanbin Fang, Yuyan Li, Xihong Lu. Surface engineering towards high-energy carbon cathode for advanced aqueous zinc-ion hybrid capacitors[J]. Chinese Chemical Letters, ;2023, 34(8): 107919. doi: 10.1016/j.cclet.2022.107919 shu

Surface engineering towards high-energy carbon cathode for advanced aqueous zinc-ion hybrid capacitors

Xingyuan Gao ^{a, b} ,
Huilin Deng ^a ,
Yuanbin Fang ^b ,
Yuyan Li ^a ,
Xihong Lu ^{b, *,}

a.
Faculty of Chemistry and Material Science, Guangdong University of Education, Engineering Technology Development Center of Advanced Materials & Energy Saving and Emission Reduction in Guangdong Colleges and Universities, Guangzhou 510303, China
b.
MOE of the Key Laboratory of Bioinorganic and Synthetic Chemistry, The Key Lab of Low-carbon Chem & Energy Conservation of Guangdong Province, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

luxh6@mail.sysu.edu.cn

Received Date: 15 September 2022
Revised Date: 8 October 2022
Accepted Date: 17 October 2022
Available Online: 19 October 2022

Figures(4)

Opportunities coexist with challenges for the development of carbon-based cathodes with a high energy density applied for zinc ion hybrid capacitors (ZIHCs). In the present study, a facile and effective surface engineering approach is demonstrated to greatly improve the energy storage ability of commercial carbon paper (CP) in ZIHC. Benefiting from the introduced oxygen functional groups, larger surface area and improved surface wettability upon air calcination, the assembled aqueous ZIHC with the functionalized carbon paper (FCP) exhibits a much higher areal capacity of 0.22 mAh/cm² at 1 mA/cm², outperforming the counterpart with blank CP by over 5000 times. More importantly, a superior energy density and power density of 130.8 µWh/cm² and 7460.5 µW/cm², are respectively delivered. Furthermore, more than 90% of the initial capacity is retained over 10000 cycles. This surface engineering strategy to improve the energy storage capability is potentially applicable to developing a wide range of high-energy carbon electrode materials.
- Zinc ion hybrid capacitor,
- Carbon cathode,
- Air activation,
- Pseudocapacitance,
- Surface engineering
1. [1]
  P. Simon, Y. Gogotsi, B. Dunn, Science 343 (2014) 1210. doi: 10.1126/science.1249625
2. [2]
  C. Yang, J. Chen, X. Ji, et al., Nature 569 (2019) 245–250. doi: 10.1038/s41586-019-1175-6
3. [3]
  N.S. Choi, Z. Chen, S.A. Freunberger, et al., Angew. Chem. Int. Ed. 51 (2012) 9994–10024. doi: 10.1002/anie.201201429
4. [4]
  X. He, H. Zhang, X. Zhao, et al., Adv. Sci. 6 (2019) 1900151. doi: 10.1002/advs.201900151
5. [5]
  M. Song, H. Tan, D. Chao, H.J. Fan, Adv. Funct. Mater. 28 (2018) 1802564. doi: 10.1002/adfm.201802564
6. [6]
  Y. Geng, L. Pan, Z. Peng, et al., Energy Storage Mater. 51 (2022) 733–755. doi: 10.1016/j.ensm.2022.07.017
7. [7]
  Q. Li, L. Han, Q. Luo, X. Liu, J. Yi, Batter. Supercaps 5 (2022) e202100417. doi: 10.1002/batt.202100417
8. [8]
  K. Wu, J. Cui, J. Yi, et al., ACS Appl. Mater. Inter. 14 (2022) 34612–34619. doi: 10.1021/acsami.2c05887
9. [9]
  N. Jabeen, A. Hussain, Q. Xia, et al., Adv. Mater. 29 (2017) 1700804. doi: 10.1002/adma.201700804
10. [10]
  H. Xu, Y. Wang, X. Liao, B. Shi, J. Energy Chem. 47 (2020) 324–332. doi: 10.1016/j.jechem.2020.02.001
11. [11]
  P. Zhang, Y. Li, G. Wang, et al., Adv. Mater. 31 (2019) 1806005. doi: 10.1002/adma.201806005
12. [12]
  G.A. Snook, P. Kao, A.S. Best, J. Power Sources 196 (2011) 1–12. doi: 10.1016/j.jpowsour.2010.06.084
13. [13]
  L. Dong, X. Ma, Y. Li, et al., Energy Storage Mater. 13 (2018) 96–102. doi: 10.1016/j.ensm.2018.01.003
14. [14]
  N. Guo, W. Huo, X. Dong, et al., Small Methods 6 (2022) 2200597. doi: 10.1002/smtd.202200597
15. [15]
  K. Wu, F. Ning, J. Yi, et al., J. Energy Chem. 69 (2022) 237–243. doi: 10.1016/j.jechem.2022.01.037
16. [16]
  L. Zhang, L. Miao, W. Xin, et al., Energy Storage Mater. 44 (2022) 408–415. doi: 10.1016/j.ensm.2021.10.033
17. [17]
  M. Yang, Z. Yan, J. Xiao, et al., Angew. Chem. Int. Ed. 61 (2022) e202212666. doi: 10.1002/anie.202212666
18. [18]
  M. Wang, Y. Meng, K. Li, et al., eScience 2 (2022) 509–517. doi: 10.1016/j.esci.2022.04.003
19. [19]
  Q. Liu, H. Zhang, J. Xie, X. Liu, X. Lu, Carbon Energy 2 (2020) 521–539. doi: 10.1002/cey2.69
20. [20]
  H.Z. Zhang, Q.Y. Liu, Y.B. Fang, et al., Adv. Mater. 31 (2019) 1904948. doi: 10.1002/adma.201904948
21. [21]
  G. Sun, H. Yang, G. Zhang, et al., Energy Environ. Sci. 11 (2018) 3367–3374. doi: 10.1039/C8EE02567C
22. [22]
  L. Dong, W. Yang, W. Yang, et al., J. Mater. Chem. A 7 (2019) 13810–13832. doi: 10.1039/C9TA02678A
23. [23]
  G. Wang, H. Wang, X. Lu, et al., Adv. Mater. 26 (2014) 2676–2682. doi: 10.1002/adma.201304756
24. [24]
  B. Liu, Y.J. Liu, H.B. Chen, M. Yang, H.M. Li, J. Power Sources 341 (2017) 309–317. doi: 10.1016/j.jpowsour.2016.12.022
25. [25]
  J.H. Park, H.J. Lee, J.Y. Cho, et al., ACS Appl. Mater. Interfaces 12 (2020) 1322–1329. doi: 10.1021/acsami.9b17311
26. [26]
  M. Yu, Y. Huang, C. Li, et al., Adv. Funct. Mater. 25 (2015) 324–330. doi: 10.1002/adfm.201402964
27. [27]
  Y. Lu, Z. Li, Z. Bai, et al., Nano Energy 66 (2019) 104132. doi: 10.1016/j.nanoen.2019.104132
28. [28]
  W. Wang, W. Liu, Y. Zeng, et al., Adv. Mater. 27 (2015) 3572–3578. doi: 10.1002/adma.201500707
29. [29]
  H. Zhang, W. Qiu, Y. Zhang, et al., J. Mater. Chem. A 4 (2016) 18639–18645. doi: 10.1039/C6TA08138J
30. [30]
  M. Yu, X. Chen, Y. Zeng, et al., Angew. Chem. Int. Ed. 55 (2016) 6762–6766. doi: 10.1002/anie.201602631
31. [31]
  Y. Tian, R. Amal, D.W. Wang, Front. Energy Res. 4 (2016) 34.
32. [32]
  S. Chen, L. Ma, K. Zhang, et al., J. Mater. Chem. A 7 (2019) 7784–7790. doi: 10.1039/C9TA00733D
33. [33]
  Y. Han, Y. Lu, S. Shen, et al., Adv. Funct. Mater. 29 (2019) 1806329. doi: 10.1002/adfm.201806329
34. [34]
  H. Li, Q. Yang, F. Mo, et al., Energy Storage Mater. 19 (2019) 94–101. doi: 10.1016/j.ensm.2018.10.005
35. [35]
  J. Wang, J. Polleux, J. Lim, B. Dunn, J. Phys. Chem. C 111 (2007) 14925–14931. doi: 10.1021/jp074464w
36. [36]
  T. Brezesinski, J. Wang, S.H. Tolbert, B. Dunn, Nat. Mater. 9 (2010) 146–151. doi: 10.1038/nmat2612
37. [37]
  P. Liu, W. Liu, Y. Huang, et al., Energy Storage Mater. 25 (2020) 858–865. doi: 10.1016/j.ensm.2019.09.004
38. [38]
  Y. Zheng, W. Zhao, D. Jia, L. Cui, J. Liu, Chem. Eng. J. 364 (2019) 70–78. doi: 10.1016/j.cej.2019.01.076
39. [39]
  K. Li, X. Liu, S. Chen, W. Pan, J. Zhang, J. Energy Chem. 32 (2019) 166–173. doi: 10.1016/j.jechem.2018.07.014
40. [40]
  Y. Zou, Z. Zhang, W. Zhong, W. Yang, J. Mater. Chem. A 6 (2018) 9245–9256. doi: 10.1039/C8TA01366G
41. [41]
  Q. Wang, Y. Wang, T. Zhang, et al., Electrochim. Acta 407 (2022) 139869. doi: 10.1016/j.electacta.2022.139869
42. [42]
  K. Zhu, M. Li, C. Li, X. Xuan, H. Li, Chem. Eng. J. 433 (2022) 133576. doi: 10.1016/j.cej.2021.133576
43. [43]
  G. Sun, Y. Xiao, B. Lu, et al., ACS Appl. Mater. Inter. 12 (2020) 7239–7248. doi: 10.1021/acsami.9b20629
1. [1]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
2. [2]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
3. [3]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
4. [4]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
5. [5]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
6. [6]
  Xianxu Chu , Lu Wang , Junru Li , Hui Xu . Surface chemical microenvironment engineering of catalysts by organic molecules for boosting electrocatalytic reaction. Chinese Chemical Letters, 2024, 35(8): 109105-. doi: 10.1016/j.cclet.2023.109105
7. [7]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
8. [8]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
9. [9]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
10. [10]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
11. [11]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
12. [12]
  Chao-Long Chen , Rong Chen , La-Sheng Long , Lan-Sun Zheng , Xiang-Jian Kong . Anchoring heterometallic cluster on P-doped carbon nitride for efficient photocatalytic nitrogen fixation in water and air ambient. Chinese Chemical Letters, 2024, 35(4): 108795-. doi: 10.1016/j.cclet.2023.108795
13. [13]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
14. [14]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
15. [15]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
16. [16]
  Wu-Jian Long , Yang Yu , Chuang He . A novel and promising engineering application of carbon dots: Enhancing the chloride binding performance of cement. Chinese Chemical Letters, 2024, 35(6): 108943-. doi: 10.1016/j.cclet.2023.108943
17. [17]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
18. [18]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
19. [19]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
20. [20]
  Yufeng Wu , Mingjun Jing , Juan Li , Wenhui Deng , Mingguang Yi , Zhanpeng Chen , Meixia Yang , Jinyang Wu , Xinkai Xu , Yanson Bai , Xiaoqing Zou , Tianjing Wu , Xianyou Wang . Collaborative integration of Fe-N_x active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries. Chinese Chemical Letters, 2024, 35(9): 109269-. doi: 10.1016/j.cclet.2023.109269

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(142)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142