Citation: Jinjie Li, Huixian Jin, Zhikun Shang, Jie Wang, Donglai Tian, Yun Ding, Aiguo Hu. Synthesis of cycloparaphenylene under spatial nanoconfinement[J]. Chinese Chemical Letters, ;2023, 34(6): 107912. doi: 10.1016/j.cclet.2022.107912 shu

Synthesis of cycloparaphenylene under spatial nanoconfinement

Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

hagmhsn@ecust.edu.cn

Received Date: 6 September 2022
Revised Date: 8 October 2022
Accepted Date: 17 October 2022
Available Online: 19 October 2022

Figures(3)

Suzuki coupling reactions between symmetrical monomers were conducted in various mesoporous silica nanoreactors grafted with palladium catalysts, enabling the selective formation of [12]cycloparaphenylene precursor with separate yield up to 25% in one-pot reactions, much higher than that in homogeneous reaction. The spatial nanoconfinement of the nanoreactors promotes the macrocyclization while limits the concomitant linear oligomer formation, offering more possibilities for the synthesis of macrocycles from symmetrical monomers in one-pot reaction.
- Nanoreactor,
- Spatial confinement,
- Cyclization reaction,
- One-pot reaction,
- Suzuki coupling reaction
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