Citation: Yutong Wu, Chuangwei Liu, Yinglei Liu, Gaowu Qin, Song Li. Oxygen promoted hydrogen production from formaldehyde reforming with oxide-derived Cu nanowires at room temperature[J]. Chinese Chemical Letters, ;2023, 34(6): 107905. doi: 10.1016/j.cclet.2022.107905 shu

Oxygen promoted hydrogen production from formaldehyde reforming with oxide-derived Cu nanowires at room temperature

Yutong Wu ^a ,
Chuangwei Liu ^a ,
Yinglei Liu ^a ,
Gaowu Qin ^b ,
Song Li ^{a, b, *,}

a.
Key Lab for Anisotropy and Texture of Materials (MoE), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
b.
Institute for Frontier Technologies of Low-Carbon Steelmaking, Shenyang 110819, China

lis@atm.neu.edu.cn

Received Date: 14 June 2022
Revised Date: 26 September 2022
Accepted Date: 13 October 2022
Available Online: 17 October 2022

Figures(6)

This work demonstrates a two-step method to produce oxide-derived Cu nanowires on Cu mesh surface to offer a monolithic catalyst that outstandingly improves the hydrogen production from reforming formaldehyde and water under ambient conditions. Our results not only reveal that the special oxide-derived nanostructure can significantly improve the formaldehyde reforming performance of Cu, but also display that the hydrogen production has a linear relationship with oxygen pressure. Specially, a maximum of 36 times increment in hydrogen generation rate is observed than that without oxygen during the reaction. Density functional theory calculations show that the formaldehyde molecule is adsorbed on Cu surface only when the adsorbed oxygen is in adjacency, and hydrogen release process is the rate-determining step. This work highlights that the activity of deliberately synthesized catalyst can further be promoted by dynamic chemical modulation of surface states during working.
- Hydrogen production,
- Oxide-derived Cu,
- Dynamic chemical modulation,
- Reforming formaldehyde,
- Monolithic catalyst
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