Citation: Rui Li, Junjun Liu, Chunlei Xia, Tanglue Feng, Zhicheng Zhu, Bai Yang. Highly efficient solid-state luminescence of carbonized polymer dots without matrix[J]. Chinese Chemical Letters, ;2023, 34(6): 107900. doi: 10.1016/j.cclet.2022.107900 shu

Highly efficient solid-state luminescence of carbonized polymer dots without matrix

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

byangchem@jlu.edu.cn

Received Date: 8 July 2022
Revised Date: 10 October 2022
Accepted Date: 11 October 2022
Available Online: 17 October 2022

Figures(4)

Development of high-performance solid state luminescent carbon-based nanomaterials remains challenging. Here, strong blue-green fluorescent carbonized polymer dots (CPDs) from o-aminobenzenethiol and thiosalicylic acid (oABT-TSA-CPDs) with an absolute photoluminescence quantum yield (PLQY) of 76% in solid state without matrix were synthesized. Through adjusting the reaction temperature and time, the PL centers were proved to be carbon core state and surface state associated to carbonyl group which was the source of strong fluorescence emission in solid state. The mechanism of the unique phenomenon of enhanced emission from ethanol solution (PLQY = 7%) to powder (PLQY = 76%) was investigated by analyzing the chemical properties and structures of oABT-TSA-CPDs at different temperatures and oABT-TSA-CPDs/PVC composites, and was confirmed as fixation of PL centers.
- Carbonized polymer dots,
- Solid-state fluorescence,
- Matrix-free,
- High performance,
- Enhanced photoluminescence quantum yield
1. [1]
  B. Wang, S. Lu, Matter 5 (2022) 110–149. doi: 10.1016/j.matt.2021.10.016
2. [2]
  J. Liu, S. Lu, Q. Tang, et al., Nanoscale 9 (2017) 7135–7142. doi: 10.1039/C7NR02128C
3. [3]
  G. Filippini, F. Amato, C. Rosso, et al., Chem 6 (2020) 3022–3037. doi: 10.1016/j.chempr.2020.08.009
4. [4]
  F. Yuan, T. Yuan, L. Sui, et al., Nat. Commun. 9 (2018) 2249. doi: 10.1038/s41467-018-04635-5
5. [5]
  F. Yuan, Y. Wang, G. Sharma, et al., Nat. Photonics 14 (2020) 171–176. doi: 10.1038/s41566-019-0557-5
6. [6]
  K. Bramhaiah, R. Bhuyan, S. Mandal, et al., J. Phys. Chem. C 125 (2021) 4299–4309. doi: 10.1021/acs.jpcc.1c00004
7. [7]
  E. Liu, D. Li, X. Zhou, et al., ACS Sustainable Chem. Eng. 7 (2019) 9301–9308. doi: 10.1021/acssuschemeng.9b00325
8. [8]
  A. Xu, G. Wang, Y. Li, et al., Small 16 (2020) 2004621. doi: 10.1002/smll.202004621
9. [9]
  C. Wang, T. Hu, Y. Chen, et al., ACS Appl. Mater. Interfaces 11 (2019) 22332–22338. doi: 10.1021/acsami.9b04345
10. [10]
  Y. Wu, H. Zhang, A. Pan, et al., Adv. Sci. 6 (2019) 1801432. doi: 10.1002/advs.201801432
11. [11]
  F. Yan, Y. Jiang, X. Sun, et al., Nano. Res. 13 (2020) 52–60. doi: 10.1007/s12274-019-2569-3
12. [12]
  W. Liu, S. Xu, S. Guan, et al., Adv. Mater. 30 (2018) 1704376. doi: 10.1002/adma.201704376
13. [13]
  Y. Ding, S. Cheng, Q. Chang, et al., ACS Sustainable Chem. Eng. 7 (2019) 14677–14684. doi: 10.1021/acssuschemeng.9b02600
14. [14]
  J. Shao, S. Zhu, H. Liu, et al., Adv. Sci. 4 (2017) 1700395. doi: 10.1002/advs.201700395
15. [15]
  Q. Chang, S. Yang, C. Xue, et al., Nanoscale 11 (2019) 7247–7255. doi: 10.1039/c9nr01224a
16. [16]
  J. Liu, R. Li, B. Yang, ACS Cent. Sci. 6 (2020) 2179–2195. doi: 10.1021/acscentsci.0c01306
17. [17]
  Q. Zeng, T. Feng, S. Tao, S. Zhu, B. Yang, Light Sci. Appl. 10 (2021) 142. doi: 10.1038/s41377-021-00579-6
18. [18]
  Z. Zhou, P. Tian, X. Liu, et al., Adv. Sci. 5 (2018) 1800369. doi: 10.1002/advs.201800369
19. [19]
  H. Yang, Y. Liu, Z. Guo, et al., Nat. Commun. 10 (2019) 1789. doi: 10.1038/s41467-019-09830-6
20. [20]
  Q. Wang, S. Zhang, B. Wang, et al., Nanoscale Horiz. 4 (2019) 1227–1231. doi: 10.1039/c9nh00287a
21. [21]
  T. Feng, Q. Zeng, S. Lu, et al., ACS Photonics 5 (2017) 502–510.
22. [22]
  B. Wang, Z. Wei, L. Sui, et al., Light Sci. Appl. 11 (2022) 172. doi: 10.1038/s41377-022-00865-x
23. [23]
  X. Yang, L. Ai, J. Yu, et al., Sci. Bull. 67 (2022) 1450–1457. doi: 10.1016/j.scib.2022.06.013
24. [24]
  Y. Song, S. Zhu, S. Zhang, et al., J. Mater. Chem. C 3 (2015) 5976–5984. doi: 10.1039/C5TC00813A
25. [25]
  D. Chao, W. Lyu, Y. Liu, et al., J. Mater. Chem. C 6 (2018) 7527–7532. doi: 10.1039/C8TC02184H
26. [26]
  S. Tao, S. Lu, Y. Geng, et al., Angew. Chem. Int. Ed. 57 (2018) 2393–2398. doi: 10.1002/anie.201712662
27. [27]
  S. Tao, S. Zhu, T. Feng, C. Zheng, B. Yang, Angew. Chem. Int. Ed. 59 (2020) 9826–9840. doi: 10.1002/anie.201916591
28. [28]
  S. Zhu, Y. Song, J. Shao, X. Zhao, B. Yang, Angew. Chem. Int. Ed. 54 (2015) 14626–14637. doi: 10.1002/anie.201504951
29. [29]
  Y. Zhang, X. Liu, Y. Fan, et al., Nanoscale 8 (2016) 15281–15287. doi: 10.1039/C6NR03125K
30. [30]
  C. Xia, S. Zhu, S. Zhang, et al., ACS Appl. Mater. Interfaces 12 (2020) 38593–38601. doi: 10.1021/acsami.0c11867
31. [31]
  T. Meng, T. Yuan, X. Li, et al., Chem. Commun. 55 (2019) 6531–6534. doi: 10.1039/c9cc01794a
32. [32]
  D. Zhou, P. Jing, Y. Wang, et al., Nanoscale Horiz. 4 (2019) 388–395. doi: 10.1039/c8nh00247a
33. [33]
  S. Tao, C. Zhou, C. Kang, et al., Light Sci. Appl. 11 (2022) 56. doi: 10.1038/s41377-022-00745-4
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