Citation: Chuanxin Wei, Jianfeng Wang, Yanni Zhang, Xuehua Ding, Yanze Jiang, Qiang Zhao, Jinyi Lin, Jianfeng Zhao, Linghai Xie, Wei Huang. Hierarchical structures, surface morphology and mechanical elasticity of lamellar crystals dominated by halogen effects[J]. Chinese Chemical Letters, ;2023, 34(8): 107896. doi: 10.1016/j.cclet.2022.107896 shu

Hierarchical structures, surface morphology and mechanical elasticity of lamellar crystals dominated by halogen effects

Chuanxin Wei ^{a, b, 1} ,
Jianfeng Wang ^{a, 1} ,
Yanni Zhang ^a ,
Xuehua Ding ^a ,
Yanze Jiang ^a ,
Qiang Zhao ^{a, b} ,
Jinyi Lin ^{a, *,} ,
Jianfeng Zhao ^{a, *,} ,
Linghai Xie ^{b, *,} ,
Wei Huang ^{a, b, c, *,}

a.
Key Laboratory of Flexible Electronics (KLOFE), Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211816, China
b.
Key Laboratory for Organic Electronics and Information Displays, Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
c.
Institute of Flexible Electronics (IFE), Northwestern Polytechnical University (NPU), Xi'an 710072, China

^☆

^th

iamjylin@njtech.edu.cn

iamjfzhao@njtech.edu.cn

iamlhxie@njupt.edu.cn

iamwhuang@njtech.edu.cn

Received Date: 31 August 2022
Revised Date: 26 September 2022
Accepted Date: 12 October 2022
Available Online: 17 October 2022

Figures(5)

To understand the deformation mechanism of molecular crystals under mechanical forces will accelerate the molecular design and preparation of deformable crystals. Herein, the relationship between structural halogenation and molecular-level stacking, micro/nanoscale surface morphology, and macroscopic mechanical properties are investigated. Elastic crystals of halo-pyrimidinyl carbazoles (CzM-Cl, CzM-Br and CzM-Ⅰ) with lamellar structure and brittle crystal (CzM-F) were quantitatively analyzed by crystal energy framework (CEF) providing the inter/intralayer interaction energy (Inter/Intra-IE). It is revealed that the elastic crystals bend under external force as a result from stronger Intra-IE to prevent cleavage and weaker Inter-IE for the short-range movement of molecules on the slip plane. This research will provide an insight for the molecular design of flexible crystals and facilitate the development of next-generation smart crystal materials.
- Halogen,
- Lamellar crystal,
- Elasticity,
- Crystal energy framework (CEF),
- Inter/intralayer interaction energy (Inter/Intra-IE)
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