Citation: Lin Wei, Jialing Li, Chengyun Zhou, Biao Song, Fanzhi Qin, Wenjun Wang, Hanzhuo Luo, Deyu Qin, Cheng Huang, Chen Zhang, Yang Yang. Design of copper oxide and oxygen codoped graphitic carbon nitride activator for efficient radical and nonradical activation of peroxymonosulfate[J]. Chinese Chemical Letters, ;2023, 34(6): 107893. doi: 10.1016/j.cclet.2022.107893 shu

Design of copper oxide and oxygen codoped graphitic carbon nitride activator for efficient radical and nonradical activation of peroxymonosulfate

Lin Wei ^{a, 1} ,
Jialing Li ^{b, 1} ,
Chengyun Zhou ^a ,
Biao Song ^a ,
Fanzhi Qin ^a ,
Wenjun Wang ^c ,
Hanzhuo Luo ^a ,
Deyu Qin ^a ,
Cheng Huang ^a ,
Chen Zhang ^{a, *,} ,
Yang Yang ^{d, *,}

a.
College of Environmental Science and Engineering, Hunan University and Key Laboratory of Environmental Biology and Pollution Control, Ministry of Education (Hunan University), Changsha 410082, China
b.
School of Design, Hunan University, Changsha 410082, China
c.
School of Resources and Environment, Hunan University of Technology and Business, Changsha 410205, China
d.
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 1H9, Canada

zhangchen@hnu.edu.cn

yyang34@ualberta.ca

Received Date: 30 June 2022
Revised Date: 21 September 2022
Accepted Date: 7 October 2022
Available Online: 12 October 2022

Figures(4)

Rational regulation of stable graphitic carbon nitride (CN) for superior peroxymonosulfate (PMS) activation is important in the catalytic degradation of water contaminants. In this work, the copper oxide and oxygen co-doped graphitic carbon nitride (CuO/O-CN) was prepared via one-step synthesis and applied in activating PMS for oxytetracycline (OTC) degradation, displaying superior catalytic performance. Systematic characterization and theoretical calculations indicated that the synergistic effect between the oxygen site of CN and CuO can modulate the electronic structure of the whole composite further facilitating the formation of non-radical ¹O₂ and various reactive radicals. Results of the influencing factor experiments revealed that CuO/O-CN has a strong resistance to the environmental impact. The degradation efficiency of OTC in the real water environment even exceeded that in the deionized water. After four successive runs of the optimal catalyst, the OTC removal rate was still as high as 91.3%. This work developed a high-efficiency PMS activator to remove refractory pollutants via both radical pathway and non-radical pathway, which showed a promising potential in the treatment of wastewaters.
- Graphitic carbon nitride,
- Codoping,
- Peroxymonosulfate,
- Antibiotics,
- Advanced oxidation process
1. [1]
  P. Yang, Y. Ye, Z. Yan, et al., Chin. Chem. Lett. 32 (2021) 2823–2827. doi: 10.1016/j.cclet.2021.02.028
2. [2]
  A.M. Jacobsen, B. Halling-Sørensen, F. Ingerslev, S.H. Hansen, J. Chromatogr. A 1038 (2004) 157–170. doi: 10.1016/j.chroma.2004.03.034
3. [3]
  S. Lian, X. Shi, M. Lu, et al., Chem. Eng. J. 425 (2021) 130499. doi: 10.1016/j.cej.2021.130499
4. [4]
  R. Pei, J. Cha, K.H. Carlson, A. Pruden, Environ. Sci. Technol. 41 (2007) 5108–5113. doi: 10.1021/es070051x
5. [5]
  Y. Yang, C. Zhang, D. Huang, et al., Appl. Catal. B 245 (2019) 87–99. doi: 10.1016/j.apcatb.2018.12.049
6. [6]
  G. Chen, L.C. Nengzi, Y. Gao, et al., Chin. Chem. Lett. 31 (2020) 2730–2736. doi: 10.1016/j.cclet.2020.02.033
7. [7]
  C. Zhang, S. Tian, F. Qin, et al., Water Res. 194 (2021) 116915. doi: 10.1016/j.watres.2021.116915
8. [8]
  X.H. Jiang, F. Yu, D.S. Wu, et al., Chin. Chem. Lett. 32 (2021) 2782–2786. doi: 10.1016/j.cclet.2021.01.011
9. [9]
  X. Yu, Y. Mao, D. Huang, Z. Sun, T. Li, Adv. Civ. Eng. 2021 (2021) 9934004.
10. [10]
  F. Guo, J. Lu, Q. Liu, et al., Chemosphere 205 (2018) 297–307. doi: 10.1016/j.chemosphere.2018.04.139
11. [11]
  H. Li, C. Shan, B. Pan, Environ. Sci. Technol. 52 (2018) 2197–2205. doi: 10.1021/acs.est.7b05563
12. [12]
  M. Xie, J. Tang, L. Kong, et al., Chem. Eng. J. 360 (2019) 1213–1222. doi: 10.1016/j.cej.2018.10.130
13. [13]
  Q. Wang, D. Zhou, K. Lin, X. Chen, Chem. Eng. J. 419 (2021) 129667. doi: 10.1016/j.cej.2021.129667
14. [14]
  Y. Gao, Y. Zhu, L. Lyu, et al., Environ. Sci. Technol. 52 (2018) 14371–14380. doi: 10.1021/acs.est.8b05246
15. [15]
  F. Chen, L.L. Liu, J.J. Chen, et al., Water Res. 191 (2021) 116799. doi: 10.1016/j.watres.2020.116799
16. [16]
  C. He, W. Xia, C. Zhou, et al., Chem. Eng. J. 430 (2022) 132751. doi: 10.1016/j.cej.2021.132751
17. [17]
  H. Liu, T.A. Bruton, F.M. Doyle, D.L. Sedlak, Environ. Sci. Technol. 48 (2014) 10330–10336. doi: 10.1021/es502056d
18. [18]
  X. Pang, Y. Guo, Y. Zhang, B. Xu, F. Qi, Chem. Eng. J. 304 (2016) 897–907. doi: 10.1016/j.cej.2016.07.027
19. [19]
  T. Chen, Z. Zhu, Y. Bao, et al., Environ. Sci. 8 (2021) 2618–2628.
20. [20]
  J. Liu, J. Li, S. He, et al., Sep. Purif. Technol. 234 (2020) 116120. doi: 10.1016/j.seppur.2019.116120
21. [21]
  C. Zhang, Z. Ouyang, Y. Yang, et al., Chem. Eng. J. 448 (2022) 137370. doi: 10.1016/j.cej.2022.137370
22. [22]
  S. Xu, H. Zhu, W. Cao, et al., Appl. Catal. B 234 (2018) 223–233. doi: 10.1016/j.apcatb.2018.04.029
23. [23]
  P.J. Larkin, M.P. Makowski, N.B. Colthup, Spectrochim. Acta, Part A 55 (1999) 1011–1020. doi: 10.1016/S1386-1425(98)00244-3
24. [24]
  A.C. Ferrari, S.E. Rodil, J. Robertson, Phys. Rev. B 67 (2003) 155306. doi: 10.1103/PhysRevB.67.155306
25. [25]
  L. Sun, W. Wang, C. Zhang, et al., Chem. Eng. J. 446 (2022) 137027. doi: 10.1016/j.cej.2022.137027
26. [26]
  H. Gao, H. Yang, J. Xu, S. Zhang, J. Li, Small 14 (2018) 1801353. doi: 10.1002/smll.201801353
27. [27]
  C. Jin, M. Wang, Z. Li, et al., Chem. Eng. J. 398 (2020) 125569. doi: 10.1016/j.cej.2020.125569
28. [28]
  Y. Yu, S. Wu, J. Gu, et al., J. Hazard. Mater. 384 (2020) 121247. doi: 10.1016/j.jhazmat.2019.121247
29. [29]
  X. Yuan, S. Qu, X. Huang, et al., Chem. Eng. J. 416 (2021) 129148. doi: 10.1016/j.cej.2021.129148
30. [30]
  Z. Wei, M. Liu, Z. Zhang, et al., Energy Environ. Sci. 11 (2018) 2581–2589. doi: 10.1039/C8EE01316K
31. [31]
  L. Lyu, D. Yan, G. Yu, W. Cao, C. Hu, Environ. Sci. Technol. 52 (2018) 4294–4304. doi: 10.1021/acs.est.7b06545
32. [32]
  K.A. Simonov, N.A. Vinogradov, A.S. Vinogradov, et al., ACS Nano 9 (2015) 8997–9011. doi: 10.1021/acsnano.5b03280
33. [33]
  C. Zhang, D. Qin, Y. Zhou, et al., Appl. Catal. B 303 (2022) 120904. doi: 10.1016/j.apcatb.2021.120904
34. [34]
  H. Wang, J. Zhang, P. Wang, et al., Chin. Chem. Lett. 31 (2020) 2789–2794. doi: 10.1016/j.cclet.2020.07.043
35. [35]
  L. Lyu, L. Zhang, C. Hu, Chem. Eng. J. 274 (2015) 298–306. doi: 10.1016/j.cej.2015.03.137
36. [36]
  J. Zhu, Q. He, Y. Liu, et al., J. Mater. Chem. A 7 (2019) 16999–17007. doi: 10.1039/C9TA04035H
37. [37]
  C. Song, X. Li, L. Hu, et al., ACS Appl. Mater. Interfaces 12 (2020) 8006–8015. doi: 10.1021/acsami.9b22782
38. [38]
  S. Zuo, Z. Guan, D. Xia, et al., Chem. Eng. J. 420 (2021) 127619. doi: 10.1016/j.cej.2020.127619
39. [39]
  H. Song, Z. Liu, Z. Guan, et al., Sci. Total Environ. 762 (2021) 143127. doi: 10.1016/j.scitotenv.2020.143127
40. [40]
  Q. Zhong, Q. Lin, R. Huang, et al., Chem. Eng. J. 380 (2020) 122608. doi: 10.1016/j.cej.2019.122608
41. [41]
  Y.C. Lee, Y. f. Li, M.J. Chen, et al., Water Res. 174 (2020) 115618. doi: 10.1016/j.watres.2020.115618
42. [42]
  J. Peng, H. Zhou, W. Liu, et al., Chem. Eng. J. 397 (2020) 125387. doi: 10.1016/j.cej.2020.125387
43. [43]
  S. Wang, J. Wang, Chem. Eng. J. 385 (2020) 123933. doi: 10.1016/j.cej.2019.123933
44. [44]
  K.Y.A. Lin, H.K. Lai, S. Tong, J. Colloid Interface Sci. 514 (2018) 272–280. doi: 10.1016/j.jcis.2017.12.040
45. [45]
  R.A. Figueroa, A.A. MacKay, Environ. Sci. Technol. 39 (2005) 6664–6671. doi: 10.1021/es048044l
46. [46]
  Z. Li, M. Wang, C. Jin, et al., Chem. Eng. J. 392 (2020) 123789. doi: 10.1016/j.cej.2019.123789
47. [47]
  Y. Ji, Y. Fan, K. Liu, D. Kong, J. Lu, Water Res. 87 (2015) 1–9. doi: 10.1016/j.watres.2015.09.005
48. [48]
  R. Yuan, S.N. Ramjaun, Z. Wang, J. Liu, J. Hazard. Mater. 196 (2011) 173–179. doi: 10.1016/j.jhazmat.2011.09.007
49. [49]
  P. Xie, J. Ma, W. Liu, et al., Water Res. 69 (2015) 223–233. doi: 10.1016/j.watres.2014.11.029
50. [50]
  W. Huang, A. Bianco, M. Brigante, G. Mailhot, J. Hazard. Mater. 347 (2018) 279–287. doi: 10.1016/j.jhazmat.2018.01.006
51. [51]
  S.H. Ho, Y. d. Chen, R. Li, et al., Water Res. 159 (2019) 77–86. doi: 10.1016/j.watres.2019.05.008
52. [52]
  S. Guo, H. Tang, L. You, et al., Chin. Chem. Lett. 32 (2021) 2828–2832. doi: 10.1016/j.cclet.2021.01.019
53. [53]
  J. Hu, H. Dong, J. Qu, Z. Qiang, Water Res. 112 (2017) 1–8. doi: 10.1016/j.watres.2017.01.025
54. [54]
  J. Ali, L. Wenli, A. Shahzad, et al., Water Res. 181 (2020) 115862. doi: 10.1016/j.watres.2020.115862
55. [55]
  G.R. Buettner, Free Radical Biol. Med. 3 (1987) 259–303. doi: 10.1016/S0891-5849(87)80033-3
56. [56]
  N. Jiang, H. Xu, L. Wang, J. Jiang, T. Zhang, Environ. Sci. Technol. 54 (2020) 14057–14065. doi: 10.1021/acs.est.0c04867
57. [57]
  S. Wang, Y. Liu, J. Wang, Environ. Sci. Technol. 54 (2020) 10361–10369. doi: 10.1021/acs.est.0c03256
58. [58]
  S. Yang, P. Wu, J. Liu, et al., Chem. Eng. J. 350 (2018) 484–495. doi: 10.1016/j.cej.2018.04.175
59. [59]
  G. Fang, J. Li, C. Zhang, et al., Environ. Pollut. 300 (2022) 118939. doi: 10.1016/j.envpol.2022.118939
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3. [3]
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4. [4]
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