Citation: Yue Li, Bo Yu, Huimin Li, Bo Liu, Xiang Yu, Kewei Zhang, Gang Qin, Jiahao Lu, Lihui Zhang, Longlu Wang. Activation of hydrogen peroxide by molybdenum disulfide as Fenton-like catalyst and cocatalyst: Phase-dependent catalytic performance and degradation mechanism[J]. Chinese Chemical Letters, ;2023, 34(5): 107874. doi: 10.1016/j.cclet.2022.107874 shu

Activation of hydrogen peroxide by molybdenum disulfide as Fenton-like catalyst and cocatalyst: Phase-dependent catalytic performance and degradation mechanism

Yue Li ^{a, 1} ,
Bo Yu ^{a, b, 1} ,
Huimin Li ^{a, b} ,
Bo Liu ^a ,
Xiang Yu ^a ,
Kewei Zhang ^a ,
Gang Qin ^{b, *,} ,
Jiahao Lu ^a ,
Lihui Zhang ^a ,
Longlu Wang ^{c, *,}

a.
School of Chemical and Printing-Dyeing Engineering, Henan International Joint Laboratory of Rare Earth Composite Materials, Henan University of Engineering, Xinzheng 451191, China
b.
School of Material Science and Engineering, Henan Polytechnic University, Jiaozuo 454001, China
c.
College of Electronic and Optical Engineering & College of Microelectronics, Institute of Flexible Electronics (Future Technology), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

clqingang@126.com

wanglonglu@hnu.edu.cn

Received Date: 21 May 2022
Revised Date: 16 August 2022
Accepted Date: 29 September 2022
Available Online: 4 October 2022

Figures(4)

Molybdenum disulfide (MoS₂) has attracted great attention in hydrogen peroxide (H₂O₂) activation as a Fenton-like catalyst and cocatalyst, but the distinct mechanism of generating ^•OH remains unclear. In this paper, the metallic 1T phase and semiconducting 2H phase of MoS₂ nanosheets were prepared and applied in MoS₂/H₂O₂ and MoS₂/Fe²⁺/H₂O₂ systems with and without light irradiation. Compared with 2H-MoS₂, 1T-MoS₂ exhibited superior removal rates in degrading organic pollutants in the two systems under light irradiation. However, the phase had little effect on activating H₂O₂ in the MoS₂/H₂O₂ system under dark conditions. This is because it was difficult for the surface ^•OH_ads generated in the MoS₂/H₂O₂ system to diffuse into solution, while the ^•OH_free radicals were mainly responsible for degrading organic pollutants. When introducing light irradiation, external energy may accelerate the desorption of ^•OH_ads into ^•OH_free. Interestingly, the conversion between Mo⁴⁺ and Mo⁵⁺ triggered the decomposition of H₂O₂ in the Fenton-like reaction, while the cycle of Mo⁴⁺/Mo⁶⁺ promoted the regeneration of Fe³⁺ when employing 1T-MoS₂ as a cocatalyst. Meanwhile, the 1T-MoS₂ catalysts exhibited excellent stability and ability to degrade various organics in the two systems. This work offers deeper insight into the MoS₂-based Fenton-like and cocatalytic mechanisms.
- Molybdenum sulfate,
- Phase,
- Fenton-like catalyst,
- Cocatalyst,
- Catalytic mechanism
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