Citation: Wenli Zhao, Wenhao Wang, Fancang Meng, Yang Du, Qingmin Ji, Heng-Dao Quan. One-pot synthesis of bimetallic Fe/Co incorporated silica hollow spheres with superior peroxidase-like activity[J]. Chinese Chemical Letters, ;2023, 34(7): 107858. doi: 10.1016/j.cclet.2022.107858 shu

One-pot synthesis of bimetallic Fe/Co incorporated silica hollow spheres with superior peroxidase-like activity

Wenli Zhao ^{a, 1} ,
Wenhao Wang ^{a, 1} ,
Fancang Meng ^a ,
Yang Du ^{b, *,} ,
Qingmin Ji ^{a, *,} ,
Heng-Dao Quan ^c

a.
Herbert Gleiter Institute for Nanoscience, School of Materials Science and Engineering, Nanjing University of Science & Technology, Nanjing 210094, China
b.
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
c.
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

duy@njust.edu.cn

jiqingmin@njust.edu.cn

Received Date: 27 May 2022
Revised Date: 9 August 2022
Accepted Date: 26 September 2022
Available Online: 29 September 2022

Figures(3)

Mesoporous silica hollow spheres with a homogenous and high content distribution of Fe and Co were synthesized by a facile one-pot hydrothermal process. The sub-nanometer bimetallic components inside the silica framework facilitate the stable fixation and the open accessibility to active sites. The co-doped Fe/Co in the spheres showed excellent peroxidase-like activity and much higher catalytic performance than their monometallic-supported spheres. The synergistic effect between Fe and Co promotes the continuous formation of functional radicals during the oxidation process and thus accelerates the reaction rate. When used for colorimetric detection of hydrogen peroxide (H₂O₂), the Fe/Co incorporated silica hollow spheres show the capability of detection of H₂O₂ in a wide range (10-250 µmol/L) and with the low detection limit of 0.012 ppm.
- Bimetallic doping,
- Mesoporous silica,
- Hollow sphere,
- Supported catalyst,
- Peroxidase-like activity
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