Citation: Pin Hao, Xu Dong, Houguang Wen, Ruirui Xu, Junfeng Xie, Qian Wang, Guanwei Cui, Jian Tian, Bo Tang. In-situ assembly of 2D/3D porous nickel cobalt sulfide solid solution as superior pre-catalysts to boost multi-functional electrocatalytic oxidation[J]. Chinese Chemical Letters, ;2023, 34(5): 107843. doi: 10.1016/j.cclet.2022.107843 shu

In-situ assembly of 2D/3D porous nickel cobalt sulfide solid solution as superior pre-catalysts to boost multi-functional electrocatalytic oxidation

Pin Hao ^{a, 1, *,} ,
Xu Dong ^{a, 1} ,
Houguang Wen ^a ,
Ruirui Xu ^a ,
Junfeng Xie ^a ,
Qian Wang ^a ,
Guanwei Cui ^a ,
Jian Tian ^{b, *,} ,
Bo Tang ^a

a.
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Ji'nan 250014, China
b.
School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China

haopin@sdnu.edu.cn

jiantian@sdust.edu.cn

Received Date: 14 June 2022
Revised Date: 4 September 2022
Accepted Date: 21 September 2022
Available Online: 24 September 2022

Figures(4)

In this work, we fabricated an efficient pre-catalyst based on (Ni, Co)S₂ solid solution with hierarchical architecture and high porosity to boost urea oxidation reaction and electrocatalytic oxidation of organic small molecules. The interaction between Ni and Co can optimize the electronic structure, resulting in the improved conductivity and accelerated charge transfer rate. The 2D/3D architecture can enrich more active species and endow the mass and electron transport to facilitate the surface oxidation and the following catalytic process. Post-structure and catalytic characterizations confirm the surface oxidation of (Ni, Co)S₂ during the stability test, and the in-situ formed Co(Ni) based (oxy)hydroxides exhibit superior catalytic activity and facilitated charge transfer ability. As a result, the optimal (Ni, Co)S₂ solid solution pre-catalyst displays facilitated catalytic behavior and good stability for multifunctional electrocatalytic oxidation, in which a high conversion of benzyl alcohol (97.50%), a good selectivity to benzoic acid (93.78%) and a satisfied faraday efficiency (91.86%) can be achieved.
- Electrocatalytic oxidation,
- (Ni, Co)S₂ solid solution,
- Pre-catalyst,
- Urea oxidation reaction,
- 2D/3D architecture
1. [1]
  X. Wang, L. Yu, B.Y. Guan, S. Song, X.W. Lou, Adv. Mater. 30 (2018) 1801211. doi: 10.1002/adma.201801211
2. [2]
  L. Wang, Y. Zhu, Y. Wen, et al., Angew. Chem. Int. Ed. 60 (2021) 10577–10582. doi: 10.1002/anie.202100610
3. [3]
  P. Hao, W. Zhu, L. Li, et al., Electrochim. Acta 338 (2020) 135883. doi: 10.1016/j.electacta.2020.135883
4. [4]
  Z. Li, J. Zhang, X. Jing, et al., J. Mater. Chem. A 9 (2021) 6152–6159. doi: 10.1039/D0TA09421H
5. [5]
  X. Chen, X. Zhong, B. Yuan, et al., Green Chem. 21 (2019) 578–588. doi: 10.1039/C8GC03451F
6. [6]
  M. Zhou, Q. Weng, X. Zhang, et al., J. Mater. Chem. A 5 (2017) 4335–4342. doi: 10.1039/C6TA09366C
7. [7]
  A. Haeussler, S. Abanades, J. Jouannaux, et al., AIMS Mater. Sci. 6 (2019) 657–684. doi: 10.3934/matersci.2019.5.657
8. [8]
  Z. Ji, Y. Song, S. Zhao, et al., ACS Catal. 12 (2022) 569–579. doi: 10.1021/acscatal.1c05190
9. [9]
  P. Hao, Y. Xin, J. Tian, et al., Sci. Chin. Chem. 63 (2020) 1030–1039. doi: 10.1007/s11426-020-9770-5
10. [10]
  P. Hao, W. Zhu, L. Li, et al., Chem. Commun. 55 (2019) 10138–10141. doi: 10.1039/C9CC05115E
11. [11]
  K. Rui, G. Zhao, Y. Chen, et al., Adv. Funct. Mater. 28 (2018) 1801554. doi: 10.1002/adfm.201801554
12. [12]
  P. Hao, H. Wen, Q. Wang, et al., J. Mater. Chem. A 9 (2021) 8576–8585. doi: 10.1039/D1TA00043H
13. [13]
  H. Tan, Z. Liu, D. Chao, et al., Adv. Energy Mater. 8 (2018) 1800685. doi: 10.1002/aenm.201800685
14. [14]
  Y. Lu, D. Fan, Z. Chen, et al., Sci. Bull. 65 (2020) 460–466. doi: 10.1016/j.scib.2019.12.020
15. [15]
  F. Li, P. Wang, X. Huang, et al., Angew. Chem. Int. Ed. 58 (2019) 7051–7056. doi: 10.1002/anie.201902588
16. [16]
  Q. Zhang, F.M. Kazim, S. Ma, et al., Appl. Catal. B 280 (2021) 119436. doi: 10.1016/j.apcatb.2020.119436
17. [17]
  Z. Cao, T. Zhou, X. Ma, et al., ACS Sustain. Chem. Eng. 8 (2020) 11007–11015.
18. [18]
  H. Liu, S. Zhu, Z. Cui, et al., Nanoscale 13 (2021) 1759–1769. doi: 10.1039/D0NR08025J
19. [19]
  Q. Li, N. Li, J. An, H. Pang, Inorg. Chem. Front. 7 (2020) 2089–2096. doi: 10.1039/D0QI00316F
20. [20]
  W. Han, X. Li, L. Lu, et al., Chem. Commun. 56 (2020) 11038–11041. doi: 10.1039/D0CC03177A
21. [21]
  M. Yuan, X. Guo, N. Li, H. Pang, J. Colloid Interface Sci. 589 (2021) 56–64. doi: 10.1016/j.jcis.2020.12.100
22. [22]
  N. Chen, Y. Du, G. Zhang, W. Lu, F. Cao, Nano Energy 81 (2021) 105605. doi: 10.1016/j.nanoen.2020.105605
1. [1]
  Rui Deng , Wenjie Jiang , Tianqi Yu , Jiali Lu , Boyao Feng , Panagiotis Tsiakaras , Shibin Yin . Cycad-leaf-like crystalline-amorphous heterostructures for efficient urea oxidation-assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(7): 100290-100290. doi: 10.1016/j.cjsc.2024.100290
2. [2]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
3. [3]
  Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
4. [4]
  Tao Tang , Chen Li , Sipu Li , Zhong Qiu , Tianqi Yang , Beirong Ye , Shaojun Shi , Chunyang Wu , Feng Cao , Xinhui Xia , Minghua Chen , Xinqi Liang , Xinping He , Xin Liu , Yongqi Zhang . One-step constructing advanced N-doped carbon@metal nitride as ultra-stable electrocatalysts via urea plasma under room temperature. Chinese Chemical Letters, 2024, 35(11): 109887-. doi: 10.1016/j.cclet.2024.109887
5. [5]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
6. [6]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
7. [7]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
8. [8]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
9. [9]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
10. [10]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
11. [11]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
12. [12]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
13. [13]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
14. [14]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
15. [15]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
16. [16]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
17. [17]
  Meng Wang , Yan Zhang , Yunbo Yu , Wenpo Shan , Hong He . High-temperature calcination dramatically promotes the activity of Cs/Co/Ce-Sn catalyst for soot oxidation. Chinese Chemical Letters, 2025, 36(1): 109928-. doi: 10.1016/j.cclet.2024.109928
18. [18]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
19. [19]
  Yuchen Wang , Zhenhao Xu , Kai Yan . Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules. Chinese Journal of Structural Chemistry, 2025, 44(1): 100418-100418. doi: 10.1016/j.cjsc.2024.100418
20. [20]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(674)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142