Citation: Pin Hao, Xu Dong, Houguang Wen, Ruirui Xu, Junfeng Xie, Qian Wang, Guanwei Cui, Jian Tian, Bo Tang. In-situ assembly of 2D/3D porous nickel cobalt sulfide solid solution as superior pre-catalysts to boost multi-functional electrocatalytic oxidation[J]. Chinese Chemical Letters, ;2023, 34(5): 107843. doi: 10.1016/j.cclet.2022.107843 shu

In-situ assembly of 2D/3D porous nickel cobalt sulfide solid solution as superior pre-catalysts to boost multi-functional electrocatalytic oxidation

Pin Hao ^{a, 1, *,} ,
Xu Dong ^{a, 1} ,
Houguang Wen ^a ,
Ruirui Xu ^a ,
Junfeng Xie ^a ,
Qian Wang ^a ,
Guanwei Cui ^a ,
Jian Tian ^{b, *,} ,
Bo Tang ^a

a.
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Ji'nan 250014, China
b.
School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China

haopin@sdnu.edu.cn

jiantian@sdust.edu.cn

Received Date: 14 June 2022
Revised Date: 4 September 2022
Accepted Date: 21 September 2022
Available Online: 24 September 2022

Figures(4)

In this work, we fabricated an efficient pre-catalyst based on (Ni, Co)S₂ solid solution with hierarchical architecture and high porosity to boost urea oxidation reaction and electrocatalytic oxidation of organic small molecules. The interaction between Ni and Co can optimize the electronic structure, resulting in the improved conductivity and accelerated charge transfer rate. The 2D/3D architecture can enrich more active species and endow the mass and electron transport to facilitate the surface oxidation and the following catalytic process. Post-structure and catalytic characterizations confirm the surface oxidation of (Ni, Co)S₂ during the stability test, and the in-situ formed Co(Ni) based (oxy)hydroxides exhibit superior catalytic activity and facilitated charge transfer ability. As a result, the optimal (Ni, Co)S₂ solid solution pre-catalyst displays facilitated catalytic behavior and good stability for multifunctional electrocatalytic oxidation, in which a high conversion of benzyl alcohol (97.50%), a good selectivity to benzoic acid (93.78%) and a satisfied faraday efficiency (91.86%) can be achieved.
- Electrocatalytic oxidation,
- (Ni, Co)S₂ solid solution,
- Pre-catalyst,
- Urea oxidation reaction,
- 2D/3D architecture
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