Citation: Xuemin Yin, Tao Liu, Xiuping Yin, Xiaochen Feng, Yiming Liu, Qinhao Shi, Xingli Zou, Yufeng Zhao. Free-standing SnNb₂O₆@CSN film as flexible anode for high performance sodium-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(7): 107840. doi: 10.1016/j.cclet.2022.107840 shu

Free-standing SnNb₂O₆@CSN film as flexible anode for high performance sodium-ion batteries

Xuemin Yin ^a ,
Tao Liu ^a ,
Xiuping Yin ^a ,
Xiaochen Feng ^a ,
Yiming Liu ^a ,
Qinhao Shi ^a ,
Xingli Zou ^b ,
Yufeng Zhao ^{a, *,}

a.
Institute for Sustainable Energy and College of Sciences, Shanghai University, Shanghai 200444, China
b.
Department of Materials Science and Engineering, Shanghai University, Shanghai 200072, China

yufengzhao@shu.edu.cn

Received Date: 5 August 2022
Revised Date: 13 September 2022
Accepted Date: 20 September 2022
Available Online: 11 May 2023

Figures(4)

Free-standing electrodes are promising candidates for flexible rechargeable batteries, toward the application of flexible energy storage devices, due to their merits of additive-free, lightweight, and high energy density. Herein, we report a free-standing SnNb₂O₆@CSN flexible film with SnNb₂O₆ encapsulated in 3D carbon skeleton nanofibers by electrospinning and carbonization processes as flexible anode for sodium-ion batteries (SIBs). The 3D carbon skeleton nanofibers serve as ion/electron transport pathway to improve the electrochemical reaction kinetics and meanwhile alleviate the volume changes of SnNb₂O₆ during charge-discharge processes. The as-constructed half-cell (SnNb₂O₆@CSN‖Na) exhibits excellent cycling stability of 99.2 mAh/g at 0.5 A/g after 950 cycles (coulombic efficiency of ~100%) and a high rate performance of 108.6 mAh/g at 10 A/g. In addition, the pouch cell can light up the LEDs at different bending angles (0°, 90°, 180°). This research shows a promising anode material for flexible energy storage electronics.
- Free-standing,
- SnNb₂O₆@CSN,
- Anode,
- Sodium-ion batteries,
- Flexible material
1. [1]
  X. Wang, X. Yin, X. Feng, et al., Chem. Eng. J. 428 (2022) 130990. doi: 10.1016/j.cej.2021.130990
2. [2]
  X. Feng, Y. Li, Q. Shi, et al., J. Energy Chem. 69 (2022) 442–449. doi: 10.1016/j.jechem.2022.01.032
3. [3]
  L. Shen, Y. Li, S. Roy, et al., Chin. Chem. Lett. 32 (2021) 3570–3574. doi: 10.1016/j.cclet.2021.03.005
4. [4]
  Y. Li, Y.F. Yuan, Y. Bai, et al., Adv. Energy Mater. 8 (2018) 1702781. doi: 10.1002/aenm.201702781
5. [5]
  Y. Liu, J. Li, Q. Shen, et al., eScience 2 (2022) 10–31. doi: 10.1016/j.esci.2021.12.008
6. [6]
  J.A.S. Oh, J. Sun, M. Goh, et al., Adv. Energy Mater. 11 (2021) 2101228. doi: 10.1002/aenm.202101228
7. [7]
  L. Zhao, Z. Qu, J. Energy Chem. 71 (2022) 108–128. doi: 10.1016/j.jechem.2022.03.008
8. [8]
  Y.H. Xu, Y.J. Zhu, Y.H. Liu, et al., Adv. Energy Mater. 3 (2013) 128–133. doi: 10.1002/aenm.201200346
9. [9]
  Y. Wang, Y. Liu, Y. Liu, et al., J. Energy Chem. 54 (2021) 225–241. doi: 10.1016/j.jechem.2020.05.065
10. [10]
  C.D. Zhao, J.Z. Guo, Z.Y. Gu, et al., Nano Res. 15 (2022) 925–932. doi: 10.1007/s12274-021-3577-7
11. [11]
  X.P. Yin, Z.X. Lu, J. Wang, et al., Adv. Mater. 34 (2022) 2109282. doi: 10.1002/adma.202109282
12. [12]
  X. Yin, Y. Zhao, X. Wang, et al., Small 18 (2022) e2105568. doi: 10.1002/smll.202105568
13. [13]
  D.H. Youn, A. Heller, C.B. Mullins, Chem. Mater. 28 (2016) 1343–1347. doi: 10.1021/acs.chemmater.5b04282
14. [14]
  A. Rudola, K. Saravanan, C.W. Mason, et al., J. Mater. Chem. A 1 (2013) 2653–2662. doi: 10.1039/c2ta01057g
15. [15]
  P. Wei, Y.X. Liu, Y.R. Su, et al., ACS Appl. Mater. Interfaces 11 (2019) 3116–3124. doi: 10.1021/acsami.8b19637
16. [16]
  X. Wu, X. Lan, R. Hu, et al., Adv. Mater. 34 (2022) e2106895. doi: 10.1002/adma.202106895
17. [17]
  L. Zhao, J.M. Zhao, Y.S. Hu, et al., Adv. Energy Mater. 2 (2012) 962–965. doi: 10.1002/aenm.201200166
18. [18]
  H. Park, H.B. Wu, T. Song, et al., Adv. Energy Mater. 5 (2015) 1401945. doi: 10.1002/aenm.201401945
19. [19]
  K. Tang, X.K. Mu, P.A. van Aken, et al., Adv. Energy Mater. 3 (2013) 49–53. doi: 10.1002/aenm.201200396
20. [20]
  A.M.L. Cruz, N.L. Alcaraz, A.F. Fuentes, et al., J. Power Sources 81 (1999) 255–258.
21. [21]
  M. Huang, J.X. Liu, P. Huang, et al., Rare Met. 40 (2021) 425–432. doi: 10.1007/s12598-020-01527-w
22. [22]
  J. Yu, J. Deli, L. Di, et al., Catal. Sci. Technol. 7 (2017) 2308–2317. doi: 10.1111/ejn.13669
23. [23]
  H. Wang, J. Yu, X. Zhan, et al., Appl. Surf. Sci. 528 (2020) 146938. doi: 10.1016/j.apsusc.2020.146938
24. [24]
  T. Liu, X.M. Yin, X.P. Yin, et al., Chem. Asian J. 17 (2022) e202200288.
25. [25]
  L. David, R. Bhandavat, U. Barrera, et al., Nat. Commun. 7 (2016) 10998. doi: 10.1038/ncomms10998
26. [26]
  S.T. Li, G. Liu, J. Liu, et al., J. Mater. Chem. A 17 (2016) 6426–6432. doi: 10.1039/C6TA00728G
27. [27]
  D. Zhang, H. Li, A. Riaz, et al., Energy Environ. Sci. 15 (2022) 185–195. doi: 10.1039/D1EE02013G
28. [28]
  T. Zhang, Z. Mao, X. Shi, et al., Energy Environ. Sci. 15 (2022) 158–168. doi: 10.1039/d1ee03214c
29. [29]
  S.S. Shi, Z. Li, L.Y. Shen, et al., Energy Storage Mater. 29 (2020) 78–83. doi: 10.1016/j.ensm.2020.03.029
30. [30]
  M.K. Shobana, J. Alloy. Compd. 831 (2020) 154844–154861. doi: 10.1016/j.jallcom.2020.154844
31. [31]
  S. Li, H. Guo, S. He, et al., Mater. Des. 214 (2022) 110406. doi: 10.1016/j.matdes.2022.110406
32. [32]
  B.H. Hou, Y.Y. Wang, Q.L. Ning, et al., Adv. Mater. 31 (2019) e1903125. doi: 10.1002/adma.201903125
33. [33]
  S. Xiao, X. Li, W. Zhang, et al., ACS Nano 15 (2021) 13307–13318. doi: 10.1021/acsnano.1c03056
34. [34]
  X.X. Liu, C. Chen, Q. He, et al., Chem. Rec. 1 (2022) e202100294.
35. [35]
  Z. Liang, H. Tu, K. Zhang, et al., Chem. Eng. J. 437 (2022) 135421. doi: 10.1016/j.cej.2022.135421
36. [36]
  Y. Jin, D. Jiang, D. Li, et al., ACS Sustain. Chem. Eng. 5 (2017) 9749–9757. doi: 10.1021/acssuschemeng.7b01548
37. [37]
  B. Luo, Y. Hong, D. Li, et al., ACS Sustain. Chem. Eng. 6 (2018) 14332–14339. doi: 10.1021/acssuschemeng.8b03006
38. [38]
  Z. Zhang, D. Jiang, D. Li, et al., Appl. Catal. B: Environ. 183 (2016) 113–123. doi: 10.1016/j.apcatb.2015.10.022
39. [39]
  J.S. Meng, Q. He, L.H. Xu, et al., Adv. Energy Mater. 9 (2019) 1802695. doi: 10.1002/aenm.201802695
40. [40]
  X. Liu, H. Wang, S. Zhang, et al., Electrochim. Acta 292 (2018) 759–768. doi: 10.1016/j.electacta.2018.09.133
41. [41]
  J. Wang, G. Zhu, X. Liu, et al., J. Colloid Interface Sci. 533 (2019) 733–741. doi: 10.3390/electronics8070733
42. [42]
  X. Zhou, L. Wan, Y. Guo, Adv. Mater. 25 (2013) 2152–2157. doi: 10.1002/adma.201300071
43. [43]
  J. Lin, Y. Yuan, Q. Su, et al., Electrochim. Acta 292 (2018) 63–71. doi: 10.1016/j.electacta.2018.09.138
44. [44]
  Z. Chen, W. Chen, H. Wang, et al., Nanoscale 12 (2020) 18673–18681. doi: 10.1039/d0nr04922k
45. [45]
  C. Wang, D. Higgins, F. Wang, et al., Nano Energy 9 (2014) 334–344. doi: 10.1016/j.nanoen.2014.08.009
46. [46]
  S. Lou, X. Cheng, L. Wang, et al., J. Power Sources 361 (2017) 80–86. doi: 10.1016/j.jpowsour.2017.06.023
47. [47]
  L. Zhou, Z. Cao, W. Wahyudi, et al., ACS Energy Lett. 5 (2020) 766–776. doi: 10.1021/acsenergylett.0c00148
48. [48]
  F.F. Liu, X.L. Cheng, R. Xu, et al., Adv. Funct. Mater. 28 (2018) 1800394. doi: 10.1002/adfm.201800394
49. [49]
  L. She, Z. Yan, L. Kang, et al., ACS Omega 3 (2018) 15943–15951. doi: 10.1021/acsomega.8b02141
50. [50]
  L. Shen, Y. Wang, H. Lv, et al., Adv. Mater. 30 (2018) 1804378. doi: 10.1002/adma.201804378
51. [51]
  Z. Tong, S. Liu, Y. Zhou, et al., Energy Storage Mater. 13 (2018) 223–232. doi: 10.1016/j.ensm.2017.12.005
52. [52]
  B. Shang, Q. Peng, X. Jiao, et al., Ionics 25 (2019) 1679–1688. doi: 10.1007/s11581-018-2784-z
53. [53]
  Y. Huang, X. Li, J. Luo, et al., ACS Appl. Mater. Interfaces 9 (2017) 8696–8703. doi: 10.1021/acsami.6b15887
54. [54]
  Y. Wu, X. Fan, Y. Chen, et al., J. Mater. Chem. A 7 (2019) 20813–20823. doi: 10.1039/c9ta07320e
55. [55]
  K.Y. Xie, W.F. Wei, H.R. Yu, et al., RSC Adv. 6 (2016) 35746–35750. doi: 10.1039/C6RA02530G
56. [56]
  L. Wang, X. Bi, S. Yang, Adv. Mater. 28 (2016) 7672–7679. doi: 10.1002/adma.201601723
57. [57]
  C. Lin, S. Deng, D.J. Kautz, et al., Small 13 (2017) 1702903. doi: 10.1002/smll.201702903
58. [58]
  H. Zhang, X. Zhang, H. Li, et al., J. Colloid Interface Sci. 583 (2021) 652–660. doi: 10.1016/j.jcis.2020.09.076
59. [59]
  Y. Yang, Y. Yue, L. Wang, et al., Int. J. Hydrog. Energy 45 (2020) 12583–12592. doi: 10.1016/j.ijhydene.2020.02.214
1. [1]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
2. [2]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
3. [3]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
4. [4]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
5. [5]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
6. [6]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
7. [7]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
8. [8]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
9. [9]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
10. [10]
  Haiying Lu , Weijie Li . The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(11): 100334-100334. doi: 10.1016/j.cjsc.2024.100334
11. [11]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
12. [12]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567
13. [13]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
14. [14]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309
15. [15]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
16. [16]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
17. [17]
  Shuo Zhang , Haitao Liao , Zhi-Qun Liu , Chong Yan , Jia-Qi Huang . Re-evaluating the nano-sized inorganic protective layer on Cu current collector for anode free lithium metal batteries. Chinese Chemical Letters, 2024, 35(7): 109284-. doi: 10.1016/j.cclet.2023.109284
18. [18]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
19. [19]
  Haixia Wu , Kailu Guo . Iodized polyacrylonitrile as fast-charging anode for lithium-ion battery. Chinese Chemical Letters, 2024, 35(10): 109550-. doi: 10.1016/j.cclet.2024.109550
20. [20]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(550)
HTML views(24)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Free-standing SnNb2O6@CSN film as flexible anode for high performance sodium-ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

Free-standing SnNb₂O₆@CSN film as flexible anode for high performance sodium-ion batteries