Citation: Lulu Chen, Yelong Zhang, Jianbo Jia. Nitrogen-doped mesoporous carbon nanospheres loaded with cobalt nanoparticles for oxygen reduction and Zn–air batteries[J]. Chinese Chemical Letters, ;2023, 34(7): 107815. doi: 10.1016/j.cclet.2022.107815 shu

Nitrogen-doped mesoporous carbon nanospheres loaded with cobalt nanoparticles for oxygen reduction and Zn–air batteries

Lulu Chen ^a ,
Yelong Zhang ^b ,
Jianbo Jia ^{a, *,}

a.
School of Biotechnology and Health Sciences, Wuyi University, Jiangmen 529020, China
b.
School of Applied Physics and Materials, Wuyi University, Jiangmen 529020, China

jbjiagu@163.com

Received Date: 17 June 2022
Revised Date: 14 August 2022
Accepted Date: 6 September 2022
Available Online: 10 September 2022

Figures(6)

Mesoporous carbon supported with transition metals nanoparticles performs desired activities for oxygen reduction reaction (ORR) and clean energy conversion devices such as Zn–air batteries. In this work, we synthesized N-doped mesoporous carbon loaded with cobalt nanoparticles (CoMCN) through self-assembly method. There are sufficient mesopores on the carbon substrate which stem from the pore-forming agent. These mesopores can provide enough accessible active sites and profitable charge/mass transport for ORR. The high content of pyridinic and graphitic N is beneficial for promoting O₂ adsorption and reduction. The smaller value of I_D/I_G indicates the higher degree of graphitization of CoMCN, providing better electronic conductivity. The half-wave potential of CoMCN is 0.865 V in basic solution, which is 24 mV more positive than that of the commercial Pt/C (0.841 V). In addition, CoMCN performs excellent methanol tolerance and stability under both basic and acidic conditions. The Zn–air battery assembled with CoMCN performs the larger power density and open-circuit voltage than the commercial Pt/C-based battery, indicating the potential application in energy conversion systems. This work provides thoughtful ideas for fabricating transition metal nanoparticles based porous carbon for electrocatalysis and metal–air batteries.
- Nitrogen-doped carbon,
- Mesoporous carbon,
- Metallic cobalt nanoparticles,
- Oxygen reduction reaction,
- Zn–air batteries
1. [1]
  C. Xie, Z. Niu, D. Kim, M. Li, P. Yang, Chem. Rev. 120 (2020) 1184-1249. doi: 10.1021/acs.chemrev.9b00220
2. [2]
  G. Yang, J. Zhu, P. Yuan, et al., Nat. Commun. 12 (2021) 1734. doi: 10.1038/s41467-021-21919-5
3. [3]
  H. Liu, Q. Liu, Y. Wang, et al., Chin. Chem. Lett. 33 (2022) 683-692. doi: 10.1016/j.cclet.2021.07.038
4. [4]
  A. Sumboja, J. Liu, W.G. Zheng, et al., Chem. Soc. Rev. 47 (2018) 5919-5945. doi: 10.1039/C8CS00237A
5. [5]
  M. Sun, D. Davenport, H. Liu, et al., J. Mater. Chem. A 6 (2018) 2527-2539. doi: 10.1039/C7TA09187G
6. [6]
  M. Zhang, B. Yang, T. Yang, Y. Yang, Z. Xiang, Chin. Chem. Lett. 33 (2022) 362-367. doi: 10.1016/j.cclet.2021.06.054
7. [7]
  H. Zhao, Y. Zhang, L. Li, et al., Chin. Chem. Lett. 32 (2021) 140-145. doi: 10.1016/j.cclet.2020.11.035
8. [8]
  D. Barrera, M. Florent, M. Kulko, T.J. Bandosz, J. Mater. Chem. A 7 (2019) 27110-27123. doi: 10.1039/c9ta10850e
9. [9]
  L. Du, L. Xing, G. Zhang, S. Sun, Carbon 156 (2020) 77-92. doi: 10.1016/j.carbon.2019.09.029
10. [10]
  J. Zhang, J. Chen, Y. Luo, et al., Carbon 159 (2020) 16-24. doi: 10.1089/dna.2019.5111
11. [11]
  T. Yang, Y. Chen, Y. Liu, X. Liu, S. Gao, Chin. Chem. Lett. 33 (2022) 2171-2177. doi: 10.1016/j.cclet.2021.09.014
12. [12]
  R. Zhong, C. Zhi, Y. Wu, et al., Chin. Chem. Lett. 31 (2020) 1588-1592. doi: 10.1016/j.cclet.2019.12.004
13. [13]
  L. Chen, X. Xu, W. Yang, J. Jia, Chin. Chem. Lett. 31 (2020) 626-634. doi: 10.1016/j.cclet.2019.08.008
14. [14]
  L. Zhang, L. Li, H. Chen, Z. Wei, Chem 26 (2019) 3973-3990. doi: 10.3390/su11143973
15. [15]
  M. Jafari, H. Gharibi, M. Parnian, M. Nasrollahpour, M. Vafaee, ACS Appl. Nano Mater. 1 (2021) 459. doi: 10.1021/acsanm.0c02774
16. [16]
  H.W. Kim, V.J. Bukas, H. Park, et al., ACS Catal. 10 (2019) 852-863.
17. [17]
  L. Yang, J. Shui, L. Du, et al., Adv. Mater. 31 (2019) 1804799. doi: 10.1002/adma.201804799
18. [18]
  X. Wu, R. Wang, W. Li, B. Feng, W. Hu, ACS Appl. Nano Mater. 4 (2021) 3369. doi: 10.1021/acsanm.0c03126
19. [19]
  K.P. Gong, F. Du, Z.H. Xia, M. Durstock, L.M. Dai, Science 323 (2009) 760-764. doi: 10.1126/science.1168049
20. [20]
  J. Yang, F. Xiang, H. Guo, L. Wang, X. Niu, Carbon 156 (2020) 514-522. doi: 10.1016/j.carbon.2019.09.087
21. [21]
  Y. Yin, J. Wang, T. Li, et al., ACS Nano 15 (2021) 13240. doi: 10.1021/acsnano.1c02950
22. [22]
  S. Zhao, J. Yang, M. Han, et al., Appl. Catal. B: Environ. 260 (2020) 118207. doi: 10.1016/j.apcatb.2019.118207
23. [23]
  L. Chen, Y. Zhang, X. Liu, et al., Chem. Commun. 55 (2019) 5651-5654. doi: 10.1039/c9cc01705d
24. [24]
  J. Zhang, M. Zhang, Y. Zeng, et al., Small 15 (2019) 1900307. doi: 10.1002/smll.201900307
25. [25]
  S. Wan, J. Wu, D. Wang, et al., Chin. Chem. Lett. 32 (2021) 816-821. doi: 10.1016/j.cclet.2020.04.040
26. [26]
  L. Guo, S. Hwang, B. Li, et al., ACS Nano 15 (2021) 6886-6899. doi: 10.1021/acsnano.0c10637
27. [27]
  S. Li, C. Cheng, X. Zhao, J. Schmidt, A. Thomas, Angew. Chem. Int. Ed. 57 (2018) 1856-1862. doi: 10.1002/anie.201710852
28. [28]
  J. Zhang, M. Zhang, L. Qiu, et al., J. Mater. Chem. A 7 (2019) 19045-19059. doi: 10.1039/c9ta06852j
29. [29]
  Y. Jia, F. Zhang, Q. Liu, et al., Chin. Chem. Lett. 33 (2022) 1070-1073. doi: 10.1016/j.cclet.2021.05.052
30. [30]
  Z. Liang, H. Guo, H. Lei, R. Cao, Chin. Chem. Lett. 33 (2022) 3999-4002. doi: 10.1016/j.cclet.2021.11.055
31. [31]
  B. Liu, H. Zhou, H. Jin, et al., Chin. Chem. Lett. 32 (2021) 535-538. doi: 10.1016/j.cclet.2020.04.002
32. [32]
  C. Guo, Y. Li, W. Liao, et al., J. Mater. Chem. A 6 (2018) 13050-13061. doi: 10.1039/c8ta03759k
33. [33]
  Y. He, Q. Shi, W. Shan, et al., Angew. Chem. Int. Ed. 60 (2021) 9516-9526. doi: 10.1002/anie.202017288
34. [34]
  W. Peng, X. Yang, L. Mao, et al., Chem. Eng. J. 407 (2021) 127157. doi: 10.1016/j.cej.2020.127157
35. [35]
  J. Ban, X. Wen, H. Xu, et al., Adv. Fun. Mater. 31 (2021) 2010472. doi: 10.1002/adfm.202010472
36. [36]
  J. Ban, G. Xu, L. Zhang, et al., Nanoscale 10 (2018) 9077-9086. doi: 10.1039/C8NR01457D
37. [37]
  X. Zhang, S. Zhang, Y. Yang, et al., Adv. Mater. 32 (2020) 1906905. doi: 10.1002/adma.201906905
38. [38]
  S. Zhao, L. Ban, J. Zhang, et al., Chem. Eng. J. 409 (2020) 128171.
39. [39]
  Q. Lu, H. Wu, X. Zheng, et al., Adv. Sci. 8 (2021) 2101438. doi: 10.1002/advs.202101438
40. [40]
  Y. Li, T. Liu, W. Yang, et al., Nanoscale 11 (2019) 19506-19511. doi: 10.1039/c9nr05726a
41. [41]
  S. Zhu, N. Zhao, J. Li, et al., Nano Today 29 (2019) 100796. doi: 10.1016/j.nantod.2019.100796
42. [42]
  C. Zhu, Q. Shi, B.Z. Xu, et al., Adv. Energy Mater. 8 (2018) 1801956. doi: 10.1002/aenm.201801956
43. [43]
  H. Liu, W. Zeng, Y. Yang, et al., J. Mater. Chem. A 9 (2021) 1260. doi: 10.1039/d0ta10179f
44. [44]
  Q. Ma, H. Jin, J. Zhu, et al., Adv. Sci. 8 (2021) 2102209. doi: 10.1002/advs.202102209
45. [45]
  T. Sun, P. Zhang, W. Chen, et al., Chem. Commun. 56 (2020) 798-801. doi: 10.1039/c9cc07772c
46. [46]
  J. Liu, L. Xu, Y. Deng, et al., J. Mater. Chem. A 7 (2019) 14291-14301. doi: 10.1039/c9ta01234f
47. [47]
  X. Chen, X. Zhen, H. Gong, et al., Chin. Chem. Lett. 30 (2019) 681-685. doi: 10.1016/j.cclet.2018.09.017
48. [48]
  S.G. Peera, J. Balamurugan, N.H. Kim, J.H. Lee, Small 14 (2018) 1800441. doi: 10.1002/smll.201800441
49. [49]
  S.H. Ahn, A. Manthiram, Small 13 (2017) 1603437. doi: 10.1002/smll.201603437
50. [50]
  Z. Li, M. Shao, L. Zhou, et al., Adv. Mater. 28 (2016) 2337-2344. doi: 10.1002/adma.201505086
51. [51]
  A. Zitolo, N. Ranjbar-Sahraie, T. Mineva, et al., Nat. Commun. 8 (2017) 957. doi: 10.1038/s41467-017-01100-7
52. [52]
  X. Li, X. Huang, S. Xi, et al., J. Am. Chem. Soc. 140 (2018) 12469-12475. doi: 10.1021/jacs.8b05992
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