Citation: Bingying Xia, Guangjin Wang, Shasha Cui, Jinyu Guo, Hong Xu, Zhijuan Liu, Shuang-Quan Zang. High-valance molybdenum doped Co₃O₄ nanowires: Origin of the superior activity for 5-hydroxymethyl-furfural oxidation[J]. Chinese Chemical Letters, ;2023, 34(7): 107810. doi: 10.1016/j.cclet.2022.107810 shu

High-valance molybdenum doped Co₃O₄ nanowires: Origin of the superior activity for 5-hydroxymethyl-furfural oxidation

Bingying Xia ^{a, 1} ,
Guangjin Wang ^{b, 1} ,
Shasha Cui ^a ,
Jinyu Guo ^a ,
Hong Xu ^a ,
Zhijuan Liu ^{a, *,} ,
Shuang-Quan Zang ^{a, *,}

a.
Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan International Joint Laboratory of Tumor Theranostical Cluster Materials, Green Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
b.
School of Materials Science and Energy Engineering, Foshan University, Foshan 528000, China

zhijuanliu@zzu.edu.cn

zangsqzg@zzu.edu.cn

Received Date: 6 July 2022
Revised Date: 20 August 2022
Accepted Date: 6 September 2022
Available Online: 10 September 2022

Figures(5)

Co₃O₄ has been widely explored in electrocatalytic 5-hydroxymethyl-furfural (HMF) oxidation. However, the poor intrinsic ability has seriously limited its electrochemical ability. Heteroatom-doping is an efficient method to enhance the electrocatalytic ability of catalyst by regulating electronic structure. Herein, we have modulated the electronic structure of Co₃O₄ by high valance Mo⁶⁺-doping. With the introduction of Mo⁶⁺, the content of Co²⁺ was increased and metal-oxygen bond was strength. Electrochemical results suggested that the electrocatalytic ability of Co₃O₄ towards HMF oxidation has been dramatically improved and reaction kinetics has been fasten. Theoretical calculations demonstrated that the surrounding cobalt sites after Mo⁶⁺-doping with assembled electron has a strong adsorption ability towards HMF molecule leading to more favourable oxidation of HMF. Post characterizations demonstrated pristine Co₃O₄ structure was kept after electrolysis cycles and CoOOH active species were formed. This work provides a valuable reference for developing efficient heteroatom-doped electrocatalysts for HMF oxidation.
- Spinel Co₃O₄,
- High-valance Mo⁶⁺-doping,
- Electronic structure,
- Adsorption ability,
- 5-Hydroxymethyl-furfural oxidation
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High-valance molybdenum doped Co3O4 nanowires: Origin of the superior activity for 5-hydroxymethyl-furfural oxidation

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通讯作者: 陈斌, bchen63@163.com

High-valance molybdenum doped Co₃O₄ nanowires: Origin of the superior activity for 5-hydroxymethyl-furfural oxidation