Citation: Yiyan Fan, Shiqing Q. Deng, Tianyu Li, Qinghua Zhang, Shuai Xu, Hao Li, Chuanrui Huo, Jiaou Wang, Lin Gu, Kuijuan Jin, Oswaldo Diéguez, Er-Jia Guo, Jun Chen. Improved multiferroic in EuTiO₃ films by interphase strain engineering[J]. Chinese Chemical Letters, ;2023, 34(7): 107796. doi: 10.1016/j.cclet.2022.107796 shu

Improved multiferroic in EuTiO₃ films by interphase strain engineering

Yiyan Fan ^a ,
Shiqing Q. Deng ^{a, b, *,} ,
Tianyu Li ^a ,
Qinghua Zhang ^c ,
Shuai Xu ^c ,
Hao Li ^a ,
Chuanrui Huo ^a ,
Jiaou Wang ^d ,
Lin Gu ^{c, g} ,
Kuijuan Jin ^{c, e, f} ,
Oswaldo Diéguez ^h ,
Er-Jia Guo ^{c, e, f, **,} ,
Jun Chen ^{a, *,}

a.
Beijing Advanced Innovation Center for Materials Genome Engineering, Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, China
b.
School of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083, China
c.
Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
d.
Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
e.
Department of Physics, University of Chinese Academy of Sciences, Beijing 100049, China
f.
Songshan Lake Materials Laboratory, Dongguan 523808, China
g.
National Center for Electron Microscopy in Beijing, School of Materials science and Engineering, Tsinghua University, Beijing 100084, China
h.
Department of Materials Science and Engineering, Faculty of Engineering, Tel Aviv University, Tel Aviv 6997801, Israel

^**

sqdeng@ustb.edu.cn

ejguo@iphy.ac.cn

junchen@ustb.edu.cn

Received Date: 26 July 2022
Revised Date: 20 August 2022
Accepted Date: 1 September 2022
Available Online: 7 September 2022

Figures(4)

Interphase strain engineering provides a unique methodology to significantly modify the lattice structure across a single film, enabling the emergence and manipulation of novel functionalities that are inaccessible in the context of traditional strain engineering methods. In this work, by using the interphase strain, we achieve a ferromagnetic state with enhanced Curie temperature and a room-temperature polar state in EuO secondary phase-tunned EuTiO₃ thin films. A combination of atomic-scale electron microscopy and synchrotron X-ray spectroscopy unravels the underlying mechanisms of the ferroelectric and ferromagnetic properties enhancement. Wherein, the EuO secondary phase is found to be able to dramatically distort the TiO₆ octahedra, which favors the non-centrosymmetric polar state, weakens antiferromagnetic Eu-Ti-Eu interactions, and enhances ferromagnetic Eu-O-Eu interactions. Our work demonstrates the feasibility and effectiveness of interphase strain engineering in simultaneously promoting ferroelectric and ferromagnetic performance, which would provide new thinking on the property regulation of numerous strongly correlated functional materials.
- EuTiO₃,
- Magnetic phase transition,
- Polar state,
- Interphase strain engineering
1. [1]
  J.P. Locquet, J. Perret, J. Fompeyrine, et al., Nature 394 (1998) 453–456. doi: 10.1038/28810
2. [2]
  R. V Helmolt, J. Wecker, B. Holzapfel, et al., Phys. Rev. Lett. 71 (1993) 2331–2333. doi: 10.1103/PhysRevLett.71.2331
3. [3]
  J. Wang, J.B. Neaton, H. Zheng, et al., Science 299 (2003) 1719–1722. doi: 10.1126/science.1080615
4. [4]
  A.R. Damodaran, E. Breckenfeld, Z. Chen, et al., Adv. Mater. 26 (2014) 6341–6347. doi: 10.1002/adma.201400254
5. [5]
  D. Kan, V. Anbusathaiah, I. Takeuchi, Adv. Mater. 23 (2011) 1765–1769. doi: 10.1002/adma.201004503
6. [6]
  D.G. Schlom, L.Q. Chen, C.J. Fennie, et al., MRS Bull. 39 (2014) 118–130. doi: 10.1557/mrs.2014.1
7. [7]
  S.V. Kalinin, N.A. Spaldin, Science 341 (2013) 858–859. doi: 10.1126/science.1243098
8. [8]
  T.R. McGuire, M.W. Shafer, R.J. Joenk, H.A. Alperin, S.J. Pickart, J. Appl. Phys. 37 (1966) 981–982. doi: 10.1063/1.1708549
9. [9]
  C.L. Chien, S. DeBenedetti, Phys. Rev. B 10 (1974) 3913–3922. doi: 10.1103/PhysRevB.10.3913
10. [10]
  N.A. Hill, J. Phys. Chem. B 104 (2000) 6694–6709. doi: 10.1021/jp000114x
11. [11]
  C.J. Fennie, K.M. Rabe, Phys. Rev. Lett. 97 (2006) 267602. doi: 10.1103/PhysRevLett.97.267602
12. [12]
  J. Ma, J. Hu, Z. Li, C.W. Nan, Adv. Mater. 23 (2011) 1062–1087. doi: 10.1002/adma.201003636
13. [13]
  N.A. Spaldin, R. Ramesh, Nat. Mater. 18 (2019) 203–212. doi: 10.1038/s41563-018-0275-2
14. [14]
  D. Kan, L. Pálová, V. Anbusathaiah, et al., Adv. Funct. Mater. 20 (2010) 1108–1115. doi: 10.1002/adfm.200902017
15. [15]
  K.J. Choi, M. Biegalski, Y.L. Li, et al., Science 306 (2004) 1005–1009. doi: 10.1126/science.1103218
16. [16]
  L.X. Zhang, J. Chen, L.L. Fan, et al., Science 361 (2018) 494–497. doi: 10.1126/science.aan2433
17. [17]
  Z. Chen, X. Zou, W. Ren, et al., Phys. Rev. B 86 (2012) 235125. doi: 10.1103/PhysRevB.86.235125
18. [18]
  E.J. Guo, R.D. Desautels, D. Keavney, et al., Phys. Rev. Mater. 3 (2019) 014407. doi: 10.1103/PhysRevMaterials.3.014407
19. [19]
  J.H. Haeni, P. Irvin, W. Chang, et al., Nature 430 (2004) 758–761. doi: 10.1038/nature02773
20. [20]
  K. Tanaka, K. Fujita, Y. Maruyama, et al., MRS Proc. 1454 (2012) 149–159. doi: 10.1557/opl.2012.962
21. [21]
  J.H. Lee, L. Fang, E. Vlahos, et al., Nature 466 (2010) 954–958. doi: 10.1038/nature09331
22. [22]
  A.R. Chaudhuri, M. Arredondo, A. Hähnel, et al., Phys. Rev. B 84 (2011) 054112. doi: 10.1103/PhysRevB.84.054112
23. [23]
  W. Li, R. Zhao, L. Wang, et al., Sci. Rep. 3 (2013) 2618. doi: 10.1038/srep02618
24. [24]
  T.Y. Li, S.Q. Deng, H. Liu, et al., Adv. Mater. 33 (2021) e2008316. doi: 10.1002/adma.202008316
25. [25]
  Y. Lin, E.M. Choi, P. Lu, et al., ACS Appl. Mater. Interfaces 12 (2020) 8513–8521. doi: 10.1021/acsami.9b17887
26. [26]
  K. Fujita, N. Wakasugi, S. Murai, et al., Appl. Phys. Lett. 94 (2009) 062512. doi: 10.1063/1.3072598
27. [27]
  V. Goian, S. Kamba, O. Pacherová, et al., Phys. Rev. B 86 (2012) 054112. doi: 10.1103/PhysRevB.86.054112
28. [28]
  H.J. Liu, H.J. Wu, K.P. Ong, et al., Science 369 (2020) 292. doi: 10.1126/science.abb3209
29. [29]
  A. Bussmann-Holder, J. Köhler, R.K. Kremer, J.M. Law, Phys. Rev. B 83 (2011) 212102. doi: 10.1103/PhysRevB.83.212102
30. [30]
  Y.R. Shen, Annu. Rev. Phys. Chem. 40 (1989) 327–350. doi: 10.1146/annurev.pc.40.100189.001551
31. [31]
  M. Trassin, G.D. Luca, S. Manz, M. Fiebig, Adv. Mater. 27 (2015) 4871–4876. doi: 10.1002/adma.201501636
32. [32]
  N.J.C. Ingle, I.S. Elfimov, Phys. Rev. B 77 (2008) 121202. doi: 10.1103/PhysRevB.77.121202
33. [33]
  M. Allieta, M. Scavini, L.J. Spalek, et al., Phys. Rev. B 85 (2012) 184107. doi: 10.1103/PhysRevB.85.184107
34. [34]
  H. Akamatsu, Y. Kumagai, F. Oba, K. Fujita, K. Tanaka, et al., Adv. Funct. Mater. 23 (2013) 1864–1872. doi: 10.1002/adfm.201202477
35. [35]
  S. Morpurgo, J. Chem. Educ. 84 (2007) 151–155. doi: 10.1021/ed084p151
36. [36]
  A.J. Millis, Phys. Rev. B 53 (1996) 8434–8441. doi: 10.1103/PhysRevB.53.8434
37. [37]
  Y. Cao, X. Liu, M. Kareev, et al., Nat. Commun. 7 (2016) 10418. doi: 10.1038/ncomms10418
38. [38]
  P.W. Anderson, Phys. Rev. 79 (1950) 350–356. doi: 10.1103/PhysRev.79.350
39. [39]
  H. Akamatsu, Y. Kumagai, F. Oba, et al., Phys. Rev. B 83 (2011) 214421. doi: 10.1103/PhysRevB.83.214421
40. [40]
  J.B. Goodenough, Phys. Rev. 100 (1955) 564–573. doi: 10.1103/PhysRev.100.564
41. [41]
  J. KanamorI, J. Phys. Chem. Solids 10 (1959) 87–98. doi: 10.1016/0022-3697(59)90061-7
42. [42]
  P.W. Anders, Solid State Phys. 14 (1963) 99–214.
43. [43]
  T. Kasuya, IBM J. Res. Dev. 14 (1970) 214–223. doi: 10.1147/rd.143.0214
44. [44]
  R. Ranjan, H. Sadat Nabi, R. Pentcheva, J. Phys. Condens. Matter 19 (2007) 406217. doi: 10.1088/0953-8984/19/40/406217
45. [45]
  R. Ranjan, H.S. Nabi, R. Pentcheva, J. Appl. Phys. 105 (2009) 053905. doi: 10.1063/1.3079791
46. [46]
  J.B. Goodenou, Book Rev. 458 (1963) 1273.
47. [47]
  D. Shina, I. Kimb, S. Songc, et al., J. Am. Ceram. Soc. (2021) 1–8. doi: 10.1111/jace.17870
48. [48]
  J.H. Lee, X. Ke, N.J. Podraza, et al., Appl. Phys. Let. 94 (2009) 202509. doi: 10.1063/1.3133354
49. [49]
  X.Y. Wang, S.Q. Zhen, Y. Min, et al., J. Appl. Phys. 122 (2017) 194102. doi: 10.1063/1.4998665
1. [1]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
2. [2]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
3. [3]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
4. [4]
  Zhaohong Chen , Mengzhen Li , Jinfei Lan , Shengqian Hu , Xiaogang Chen . Organic ferroelastic enantiomers with high T_c and large dielectric switching ratio triggered by order-disorder and displacive phase transition. Chinese Chemical Letters, 2024, 35(10): 109548-. doi: 10.1016/j.cclet.2024.109548
5. [5]
  Zhi-Yuan Yue , Hua-Kai Li , Na Wang , Shan-Shan Liu , Le-Ping Miao , Heng-Yun Ye , Chao Shi . Dehydration-triggered structural phase transition-associated ferroelectricity in a hybrid perovskite-type crystal. Chinese Chemical Letters, 2024, 35(10): 109355-. doi: 10.1016/j.cclet.2023.109355
6. [6]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
7. [7]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
8. [8]
  Zizhuo Liang , Fuming Du , Ning Zhao , Xiangxin Guo . Revealing the reason for the unsuccessful fabrication of Li3Zr2Si2PO12 by solid state reaction. Chinese Journal of Structural Chemistry, 2023, 42(11): 100108-100108. doi: 10.1016/j.cjsc.2023.100108
9. [9]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
10. [10]
  Feibin Wei , Yongfang Rao , Yu Huang , Wei Wang , Hui Mei . The new challenges for the development of NH₃-SCR catalysts under new situation of energy transition in power generation industry. Chinese Chemical Letters, 2024, 35(6): 108931-. doi: 10.1016/j.cclet.2023.108931
11. [11]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
12. [12]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
13. [13]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
14. [14]
  Kezhen Qi , Shu-yuan Liu , Ruchun Li . Selective dissolution for stabilizing solid electrolyte interphase. Chinese Chemical Letters, 2024, 35(5): 109460-. doi: 10.1016/j.cclet.2023.109460
15. [15]
  Jie Wu , Xiaoqing Yu , Guoxing Li , Su Chen . Engineering particles towards 3D supraballs-based passive cooling via grafting CDs onto colloidal photonic crystals. Chinese Chemical Letters, 2024, 35(4): 109234-. doi: 10.1016/j.cclet.2023.109234
16. [16]
  Xin Dong , Tianqi Chen , Jing Liang , Lei Wang , Huajie Wu , Zhijin Xu , Junhua Luo , Li-Na Li . Structure design of lead-free chiral-polar perovskites for sensitive self-powered X-ray detection. Chinese Journal of Structural Chemistry, 2024, 43(6): 100256-100256. doi: 10.1016/j.cjsc.2024.100256
17. [17]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
18. [18]
  Mengwen Wang , Qintao Sun , Yue Liu , Zhengan Yan , Qiyu Xu , Yuchen Wu , Tao Cheng . Impact of lithium nitrate additives on the solid electrolyte interphase in lithium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(2): 100203-100203. doi: 10.1016/j.cjsc.2023.100203
19. [19]
  Chuan Li , Yangyang Han , Yanan Zhai , Ke Li , Xingzhong Liu , Zhuan Zhang , Cai Jia , Yongsheng Che . Phomaketals A and B, pentacyclic meroterpenoids from a eupC overexpressed mutant strain of Phoma sp.. Chinese Chemical Letters, 2024, 35(7): 109019-. doi: 10.1016/j.cclet.2023.109019
20. [20]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(562)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Improved multiferroic in EuTiO3 films by interphase strain engineering

Metrics

通讯作者: 陈斌, bchen63@163.com

Improved multiferroic in EuTiO₃ films by interphase strain engineering