Citation: Miaomiao Zhou, Jianjun Zhao, Xiaodong Wang, Ji Shen, Wenhao Tang, Yirui Deng, Ruiping Liu. Surface engineering for high stable lithium-rich manganese-based cathode materials[J]. Chinese Chemical Letters, ;2023, 34(6): 107793. doi: 10.1016/j.cclet.2022.107793 shu

Surface engineering for high stable lithium-rich manganese-based cathode materials

Miaomiao Zhou ^{a, 1} ,
Jianjun Zhao ^{b, 1} ,
Xiaodong Wang ^{a, 1} ,
Ji Shen ^c ,
Wenhao Tang ^a ,
Yirui Deng ^a ,
Ruiping Liu ^{a, c, *,}

a.
School of Chemical & Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
b.
State Key Laboratory of Chemical Resources Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
c.
Department of Materials Science and Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China

lrp@cumtb.edu.cn

Received Date: 16 June 2022
Revised Date: 10 July 2022
Accepted Date: 12 August 2022
Available Online: 2 September 2022

Figures(4)

Lithium-rich manganese-based material shows great potential as the high specific cathode materials due to its low cost, environmental friendliness, high operating voltage and simple preparation process. However, the poor capacity retention and cycling performance caused by its unstable structure during cycling restrict the commercialization. In this work, Li_1.2Ni_0.16Mn_0.56Co_0.08O₂ was synthesized utilizing a Co-precipitation method and different amount of La(PO₃)₃ (La(PO₃)₃ = 2 wt%, 4 wt% and 6 wt%) was selected as the coating layer to resolve the above issues. During the calcination process, La(PO₃)₃ reacts with impurities such as LiOH and Li₂CO₃ on the lithium-rich surface to reduce the residual lithium on the surface, thus improving the interfacial stability, slowing down the corrosion of the electrolyte, and finally enhancing its electrochemical performance. The cathode materials coated with 4% of La(PO₃)₃ showed the best electrochemical performance in terms of capacity retention and cycling performance compared to the pristine NCM. The high initial discharge capacity of 214.21 mAh/g and capacity retention of 94.2% after 100 cycles at 0.1 C can be obtained. This work provides an effective strategy to protect the cathode from corrosion and will promote its further practical applications in high specific Li-ion batteries.
- Li-rich layered oxide,
- Li-ion batteries,
- La(PO₃)₃ coating,
- Electrochemical performance,
- Structure stability
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