Citation: Xinxin Hang, Rui Yang, Yadan Xue, Shasha Zheng, Yuying Shan, Meng Du, Jiawei Zhao, Huan Pang. The introduction of cobalt element into nickel-organic framework for enhanced supercapacitive performance[J]. Chinese Chemical Letters, ;2023, 34(7): 107787. doi: 10.1016/j.cclet.2022.107787 shu

The introduction of cobalt element into nickel-organic framework for enhanced supercapacitive performance

School of Chemistry and Chemical Engineering and Institute for Innovative Materials and Energy, Yangzhou University, Yangzhou 225009, China

hangxinxin@yzu.edu.cn

panghuan@yzu.edu.cn

huanpangchem@hotmail.com

Received Date: 6 June 2022
Revised Date: 27 June 2022
Accepted Date: 24 August 2022
Available Online: 28 August 2022

Figures(7)

Metal-organic frameworks (MOFs) as promising electrodes for supercapacitors are attracting increasing research interest. Herein, we report an effective strategy to improve the electrochemical performance of Ni-MOF for supercapacitor by introducing a secondary Co ion. The Co substitution of Ni in Ni-MOF can improve the intrinsic reactivity and stability. As a result, the bimetallic Co/Ni-MOF-1:15 with an optimal Co/Ni ratio delivers high specific capacitance (359 F/g at 0.5 A/g), good rate performance (81.5% retention at 5 A/g) and cycling stability (81% retention after 5000 cycles). These results demonstrate that the bimetallic synergistic strategy is an effective way to improve the pseudocapacitive performance of MOFs.
- Metal-organic frameworks,
- Bimetallic,
- Cobalt-nickel synergistic effect,
- Micro/nanostructures,
- Supercapacitors
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