Citation: Zeng-Kui Zhu, Ya-Yun Lin, Rong-Da Lai, Xin-Xiong Li, Yan-Qiong Sun, Shou-Tian Zheng. A series of high-nuclear planar equilateral triangle-shaped {Ln₆(μ₃-OH)₆} cluster encapsulated polyoxoniobates with frequency dependent magnetic property[J]. Chinese Chemical Letters, ;2023, 34(7): 107773. doi: 10.1016/j.cclet.2022.107773 shu

A series of high-nuclear planar equilateral triangle-shaped {Ln₆(μ₃-OH)₆} cluster encapsulated polyoxoniobates with frequency dependent magnetic property

State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350108, China

sunyq@fzu.edu.cn

stzheng@fzu.edu.cn

Received Date: 21 June 2022
Revised Date: 15 July 2022
Accepted Date: 22 August 2022
Available Online: 28 August 2022

Figures(3)

The integration of lanthanide (Ln) ions and polyoxoniobates (PONbs) is challenging, and the known Ln-substituted PONbs are still scarce. This work introduces high-nuclear iso-Ln-oxo clusters into the PONb system. The first series of high-nuclear Ln-oxo clusters encapsulated heterometallic polyoxoniobates H₉[Na(H₂O)₄][Cu(en)₂]₁₀{Ln₆(μ₃-OH)₆(SiNb₁₈O₅₄)₃}·18H₂O (1-Ln, en = ethylenediamine, Ln = Dy, Gd, Tb, Ho, Er, Tm, Yb, Lu) based on flower-like {Ln₆(μ₃-OH)₆(SiNb₁₈O₅₄)₃} ({Ln₆Si₃Nb₅₄}) clusters have been successfully synthesized via one-pot hydrothermal synthesis strategy. The flower-like polyoxoanion {Ln₆Si₃Nb₅₄} is consisted of three heteropolyoxoniobate {SiNb₁₈O₅₄} clusters and one unique planar equilateral triangle-shaped {Ln₆(μ₃-OH)₆} cluster, which presents the highest nuclear iso-Ln-oxo cluster in PONb chemistry. In {Ln₆(μ₃-OH)₆} cluster, each pair of μ₃-OH groups link three Dy³⁺ ions to form a small approximate equilateral triangle-shaped {Dy₃(OH)₂} cluster. Furthermore, the three {Dy₃(OH)₂} clusters comprise a bigger approximate equilateral triangle-shaped {Dy₆(μ₃-OH)₆} cluster. The reported hexanuclear {Ln₆} cluster skeletons are mostly octahedral, however, such equilateral triangle-shaped skeleton of the hexanuclear Ln-oxo cluster is first observed. The 1-Dy exhibits good water vapor adsorption capacity and ferromagnetic properties.
- Heteropolyoxoniobate,
- Hexanuclear iso-Ln-oxo cluster,
- Copper complexes,
- Water vapor adsorption,
- Ferromagnetism
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通讯作者: 陈斌, bchen63@163.com

A series of high-nuclear planar equilateral triangle-shaped {Ln₆(μ₃-OH)₆} cluster encapsulated polyoxoniobates with frequency dependent magnetic property