Citation: Xingyuan Wang, Bao Zhang, Zhiming Xiao, Lei Ming, Minghuang Li, Lei Cheng, Xing Ou. Enhanced rate capability and mitigated capacity decay of ultrahigh-nickel cobalt-free LiNi_0.9Mn_0.1O₂ cathode at high-voltage by selective tungsten substitution[J]. Chinese Chemical Letters, ;2023, 34(7): 107772. doi: 10.1016/j.cclet.2022.107772 shu

Enhanced rate capability and mitigated capacity decay of ultrahigh-nickel cobalt-free LiNi_0.9Mn_0.1O₂ cathode at high-voltage by selective tungsten substitution

Engineering Research Center of the Ministry of Education for Advanced Battery Materials, School of Metallurgy and Environment, Central South University, Changsha 410083, China

minglei666@csu.edu.cn

ouxing@csu.edu.cn

Received Date: 20 June 2022
Revised Date: 23 July 2022
Accepted Date: 22 August 2022
Available Online: 28 August 2022

Figures(4)

Owing to the further requirement for electric vehicle market, it is appropriate to lower the cost and improve the energy density of lithium-ion batteries by adopting the Co-free and Ni-rich layered cathodes. However, their practical application is severely limited by structural instability and slow kinetics. Herein, ultrahigh-nickel cobalt-free LiNi_0.9Mn_0.1O₂ cathode is elaborate designed via in-situ trace substitution of tungsten by a wet co-precipitation method following by high-temperature sintering. It is revealed that the in-situ doping strategy of high valence W⁶⁺ can effectively improve the structure stability by reducing irreversible phase transition and suppressing the formation of microcracks. Moreover, the transformed fine particles determined by W-doping can facilitate the kinetic characteristics by shortening Li⁺ diffusion paths. As expected, 0.3 mol% W-doped LiNi_0.9Mn_0.1O₂ cathode exhibits a high specific capacity of 143.5 mAh/g after 200 cycles at high rate of 5 C in the wide potential range of 2.8-4.5 V, representing a potential next-generation cathode with low-cost, high energy-density and fast-charging capabilities.
- Lithium-ion batteries,
- Ultrahigh-nickel cobalt-free cathode,
- In-situ tungsten doping,
- High cut-off voltage,
- Rapid charge performance
1. [1]
  X. Fan, X. Ou, W. Zhao, et al., Nat. Commun. 12 (2021) 5320. doi: 10.1038/s41467-021-25611-6
2. [2]
  L. Ni, H. Chen, W. Deng, et al., Adv. Energy Mater. (2022) 2103757. doi: 10.1002/aenm.202103757
3. [3]
  J. Hu, L. Li, Y. Bi, et al., Energy Storage Mater. 47 (2022) 195–202. doi: 10.1016/j.ensm.2022.02.025
4. [4]
  H. Ye, D. Lei, L. Shen, et al., Chin. Chem. Lett. 31 (2020) 570–574. doi: 10.1016/j.cclet.2019.04.047
5. [5]
  C. Wen, T. Zhu, X. Li, et al., Chin. Chem. Lett. 31 (2020) 1000–1003. doi: 10.1016/j.cclet.2019.09.028
6. [6]
  J. Wei, D. Liang, Y. Ji, et al., J. Colloid Interface Sci. 616 (2022) 520–531. doi: 10.1016/j.jcis.2022.02.095
7. [7]
  W. Zhao, L. Zou, L. Zhang, et al., Small (2022) 2107357. doi: 10.1002/smll.202107357
8. [8]
  R. Yue, F. Xia, R. Qi, et al., Chin. Chem. Lett. 32 (2021) 849–853. doi: 10.1016/j.cclet.2020.05.025
9. [9]
  Q. Shen, Y. Liu, L. Jiao, X. Qu, J. Chen, Energy Storage Mater. 35 (2021) 400–430. doi: 10.1016/j.ensm.2020.11.002
10. [10]
  Y. Liu, J. Li, Q. Shen, et al., eScience 2 (2022) 10–31. doi: 10.1016/j.esci.2021.12.008
11. [11]
  H. Sheng, X.H. Meng, D.D. Xiao, et al., Adv. Mater. (2022) 2108947. doi: 10.1002/adma.202108947
12. [12]
  A. Aishova, G.T. Park, C.S. Yoon, Y.K. Sun, Adv. Energy Mater. 10 (2019) 1903179.
13. [13]
  S. Li, G. Tian, R. Xiong, et al., Energy Storage Mater. 46 (2022) 443–451. doi: 10.1016/j.ensm.2022.01.035
14. [14]
  Y. Cheng, Y. Sun, C. Chu, et al., Nano Res. 15 (2022) 4091–4099. doi: 10.1007/s12274-021-4035-2
15. [15]
  L.W. Liang, K. Du, Z.D. Peng, Y.B. Cao, G.R. Hu, Chin. Chem. Lett. 25 (2014) 883–886. doi: 10.1016/j.cclet.2014.04.005
16. [16]
  C.B. Sun, Y.W. Zhong, W.J. Fu, et al., Tungsten 2 (2020) 109–133. doi: 10.1007/s42864-020-00038-6
17. [17]
  G. Jia, F. Li, J. Wang, S. Liu, Y. Yang, ACS Appl. Mater. Interface. 13 (2021) 18733–18742. doi: 10.1021/acsami.1c01221
18. [18]
  Z. Feng, S. Zhang, R. Rajagopalan, et al., ACS Appl. Mater. Interface. 13 (2021) 43039–43050. doi: 10.1021/acsami.1c10799
19. [19]
  F. Wu, N. Liu, L. Chen, et al., Nano Energy 59 (2019) 50–57. doi: 10.1016/j.nanoen.2019.02.027
20. [20]
  B. Zhang, J. Shen, Q. Wang, et al., Energy Environ. Mater. 6 (2023) e12270. doi: 10.1002/eem2.12270
21. [21]
  A. Gomez-Martin, F. Reissig, L. Frankenstein, M. Heidbüchel, et al., Adv. Energy Mater. 12 (2022) 2103045. doi: 10.1002/aenm.202103045
22. [22]
  H.H. Ryu, G.T. Park, C.S. Yoon, Y.K. Sun, J. Mater. Chem. A 7 (2019) 18580–18588. doi: 10.1039/c9ta06402h
23. [23]
  G.T. Park, H.H. Ryu, N.Y. Park, C.S. Yoon, Y.K. Sun, J. Power Source. 442 (2019) 227242. doi: 10.1016/j.jpowsour.2019.227242
24. [24]
  G.T. Park, D.R. Yoon, U.H. Kim, et al., Energy Environ. Sci. 14 (2021) 6616–6626. doi: 10.1039/d1ee02898g
25. [25]
  B. Zhang, L. Cheng, P. Deng, et al., J. Alloys Compd. 872 (2021) 159619. doi: 10.1016/j.jallcom.2021.159619
26. [26]
  J. Zheng, Z. Yang, A. Dai, et al., Small 15 (2019) 1904854. doi: 10.1002/smll.201904854
27. [27]
  M. Guilmard, A. Rougier, M. Grüne, L. Croguennec, C. Delmas, J. Power Source. 115 (2003) 305–314. doi: 10.1016/S0378-7753(03)00012-0
28. [28]
  Y. Cho, P. Oh, J. Cho, Nano Lett. 13 (2013) 1145–1152. doi: 10.1021/nl304558t
29. [29]
  D.Y. Hwang, H.S. Kim, S.H. Lee, J. Mater. Chem. A 10 (2022) 16555–16569. doi: 10.1039/d1ta08441k
30. [30]
  G.T. Park, N.Y. Park, T.C. Noh, et al., Energy Environ. Sci. 14 (2021) 5084–5095. doi: 10.1039/d1ee01773j
31. [31]
  J. Wang, C. Liu, G. Xu, et al., Chem. Eng. J. 438 (2022) 135537. doi: 10.1016/j.cej.2022.135537
32. [32]
  J.H. Kim, K.J. Park, S.J. Kim, C.S. Yoon, Y.K. Sun, J. Mater. Chem. A 7 (2019) 2694–2701. doi: 10.1039/c8ta10438g
33. [33]
  H. Yu, Y. Cao, L. Chen, et al., Nat. Commun. 12 (2021) 4564. doi: 10.1038/s41467-021-24893-0
34. [34]
  U.H. Kim, H.H. Ryu, J.H. Kim, et al., Adv. Energy Mater. 9 (2019) 1803902. doi: 10.1002/aenm.201803902
35. [35]
  X.S. Tao, Y.G. Sun, Y.S. Xu, et al., Chem. Commun. 58 (2022) 2556–2559. doi: 10.1039/d1cc06131c
36. [36]
  Y. Liu, X. Fan, B. Luo, et al., J. Colloid Interface Sci. 604 (2021) 776–784. doi: 10.1093/schbul/sbaa174
37. [37]
  J. Shen, D. Deng, X. Li, et al., J. Alloys Compd. 903 (2022) 163999. doi: 10.1016/j.jallcom.2022.163999
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced rate capability and mitigated capacity decay of ultrahigh-nickel cobalt-free LiNi0.9Mn0.1O2 cathode at high-voltage by selective tungsten substitution

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通讯作者: 陈斌, bchen63@163.com

Enhanced rate capability and mitigated capacity decay of ultrahigh-nickel cobalt-free LiNi_0.9Mn_0.1O₂ cathode at high-voltage by selective tungsten substitution