Citation: Xiao-Xuan Guo, Zhao-Tian Cai, Yaseen Muhammad, Feng-Lei Zhang, Rui-Ping Wei, Li-Jing Gao, Guo-Min Xiao. Silver-anchored porous aromatic framework for efficient conversion of propargylic alcohols with CO₂ at ambient pressure[J]. Chinese Chemical Letters, ;2023, 34(4): 107740. doi: 10.1016/j.cclet.2022.08.020 shu

Silver-anchored porous aromatic framework for efficient conversion of propargylic alcohols with CO₂ at ambient pressure

Xiao-Xuan Guo ^{a, 1} ,
Zhao-Tian Cai ^{a, 1} ,
Yaseen Muhammad ^b ,
Feng-Lei Zhang ^c ,
Rui-Ping Wei ^a ,
Li-Jing Gao ^a ,
Guo-Min Xiao ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China
b.
Institute of Chemical Sciences, University of Peshawar, 25120, KP, Pakistan
c.
Intelligent Transportation System Research Center, Southeast University, Nanjing 211189, China

xiaogm426@gmail.com

Received Date: 19 April 2022
Revised Date: 26 July 2022
Accepted Date: 9 August 2022
Available Online: 11 August 2022

Figures(5)

The conversion of propargylic alcohols and carbon dioxide (CO₂) into fine chemicals suffers from issues of harsh reaction conditions and difficult catalyst recovery. To achieve efficient CO₂ activation at low energy consumption, a silver-anchored porous aromatic framework catalyst Ag@PAF-DAB with high active phase density and CO₂ adsorption capacity was proposed. Since Ag@PAF-DAB has the dual functions of CO₂ capture and conversion, propargylic alcohols were completely converted into α-alkylidene cyclic carbonate or α‑hydroxy ketone as high value-added product under atmospheric pressure (CO₂, 0.1 MPa) and low silver equivalent (0.5 mol%). Notably, Ag@PAF-DAB exhibited broad substrate diversity, high stability, and excellent reusability. By applying FTIR and GC, the key to green synthetic route of α‑hydroxy ketone was confirmed to lie in the further hydration of α-alkylidene cyclic carbonate.
- Porous aromatic framework,
- CO₂ capture,
- CO₂ conversion,
- α-Alkylidene cyclic carbonate,
- α-Hydroxy ketone
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沈阳化工大学材料科学与工程学院沈阳 110142

Silver-anchored porous aromatic framework for efficient conversion of propargylic alcohols with CO2 at ambient pressure

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通讯作者: 陈斌, bchen63@163.com

Silver-anchored porous aromatic framework for efficient conversion of propargylic alcohols with CO₂ at ambient pressure