Citation: Zhuoga Cirena, Yu Nie, Yanfang Li, Huilin Hu, Xiang Huang, Xin Tan, Tao Yu. Fe doped g-C₃N₄ composited ZnIn₂S₄ promoting Cr(Ⅵ) photoreduction[J]. Chinese Chemical Letters, ;2023, 34(4): 107726. doi: 10.1016/j.cclet.2022.08.006 shu

Fe doped g-C₃N₄ composited ZnIn₂S₄ promoting Cr(Ⅵ) photoreduction

Zhuoga Cirena ^a ,
Yu Nie ^a ,
Yanfang Li ^a ,
Huilin Hu ^c ,
Xiang Huang ^d ,
Xin Tan ^{a, d} ,
Tao Yu ^{b, *,}

a.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
b.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
c.
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China
d.
School of Science, Tibet University, Lhasa 850000, China

yutao@tju.edu.cn

Received Date: 23 May 2022
Revised Date: 15 July 2022
Accepted Date: 4 August 2022
Available Online: 6 August 2022

Figures(4)

30% FeCN/ZIS (30% Fe doped g-C₃N₄ composited ZnIn₂S₄) was synthesized by a simple water bath method, via in-situ growth of abundant well-dispersed ZnIn₂S₄ nanosheets on the Fe doped g-C₃N₄ surface. Experimental results showed the optimized 30% FeCN/ZIS achieved the best photoreduction of Cr(Ⅵ) performance within a wide pH range, which was 9.5 times and 700 times higher than that of pure ZnIn₂S₄ and 30% FeCN (Fe doped g-C₃N₄). This is due to the intense synergy between the Fe-N_x bond and close interface contact produces a high-speed charge transfer channel, thus significantly improving the efficiency of optical carrier separation and migration. Meanwhile, UV-vis diffuse reflection spectra and photoluminescence spectroscopy showed that iron doping significantly narrowed the bandgap of g-C₃N₄, preventing electron-hole pair recombination. Further, the microstructures and charge separation properties were analyzed by scanning electron microscope, Photoluminescence Spectroscopy and time-resolved photoluminescence, which revealed the structure-activity relationship of composite structure and the synergistic mechanism of each functional component. This research should provide a viable technique for creating composites with high photocatalytic activity for the treatment of chromium-containing wastewater.
- Hexavalent chromium,
- 30% FeCN/ZIS composites,
- Interfacial interaction,
- Synergistic effect
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Fe doped g-C3N4 composited ZnIn2S4 promoting Cr(Ⅵ) photoreduction

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Fe doped g-C₃N₄ composited ZnIn₂S₄ promoting Cr(Ⅵ) photoreduction