Citation: Yupeng Xing, Na Li, Shipeng Qiu, Gang Zhao, Shuhua Hao, Baojie Zhang. Interfacial coupling of sea urchin-like (Mo₄O₁₁-MoS₂-VO₂) promoted electron redistributions for significantly boosted hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2023, 34(4): 107724. doi: 10.1016/j.cclet.2022.08.004 shu

Interfacial coupling of sea urchin-like (Mo₄O₁₁-MoS₂-VO₂) promoted electron redistributions for significantly boosted hydrogen evolution reaction

Laboratory of Functional Micro-nano Materials and Devices, School of Physics and Technology, University of Jinan, Ji'nan 250022, China

sps_zhaog@ujn.edu.cn

Received Date: 29 April 2022
Revised Date: 8 July 2022
Accepted Date: 1 August 2022
Available Online: 3 August 2022

Figures(7)

Developing efficient electrocatalysts for hydrogen evolution reaction (HER) is of great importance in contemporary water electrolysis technology. Here, a novel hierarchically sea urchin-like electrocatalyst (Mo₄O₁₁-MoS₂-VO₂) is synthesized by hydrothermal deposition and post-annealing strategy. The optimized electrocatalyst behaves as a high active hydrogen evolution electrode in 0.5 mol/L H₂SO₄. This electrode needs overpotential of only 43 mV to achieve 10 mA/cm² with a Tafel slope of 37 mV/dec and maintains its catalytic activity for at least 36 h. Better than most previously reported non-noble metal electrocatalysts anchored on carbon cloth. It is worth mentioning that the hierarchical sea urchin-like structure promotes the redistribution of electrons and provides more catalytic active sites. This strategy shows a way for the construction of inexpensive non-noble metal electrocatalysts in the future.
- Non-noble metal,
- Hierarchical sea urchin-like (Mo₄O₁₁-MoS₂-VO₂),
- Interfacial coupling,
- Electron redistribution,
- HER
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Interfacial coupling of sea urchin-like (Mo4O11-MoS2-VO2) promoted electron redistributions for significantly boosted hydrogen evolution reaction

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通讯作者: 陈斌, bchen63@163.com

Interfacial coupling of sea urchin-like (Mo₄O₁₁-MoS₂-VO₂) promoted electron redistributions for significantly boosted hydrogen evolution reaction