Citation: Zhihong Wang, Huawei Zhu, Haifeng Yu, Tao Zhang, Yanjie Hu, Hao Jiang, Chunzhong Li. Complementary dual-doping of LiNi_0.8Co_0.1Mn_0.1O₂ cathode enhances ion-diffusion and stability for Li-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(6): 107718. doi: 10.1016/j.cclet.2022.07.061 shu

Complementary dual-doping of LiNi_0.8Co_0.1Mn_0.1O₂ cathode enhances ion-diffusion and stability for Li-ion batteries

Zhihong Wang ^{a, c} ,
Huawei Zhu ^a ,
Haifeng Yu ^a ,
Tao Zhang ^c ,
Yanjie Hu ^{a, b} ,
Hao Jiang ^{a, b, *,} ,
Chunzhong Li ^{a, b, *,}

a.
Shanghai Engineering Research Center of Hierarchical Nanomaterials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Key Laboratory for Ultrafine Materials of Ministry of Education, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
c.
State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

jianghao@ecust.edu.cn

czli@ecust.edu.cn

Received Date: 26 March 2022
Revised Date: 25 July 2022
Accepted Date: 30 July 2022
Available Online: 31 July 2022

Figures(5)

The Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) layered cathodes endow Li-ion batteries (LIBs) with high energy density. However, they usually suffer from limited ion-diffusion and structural instability during cycling. Although doping strategy can effectively alleviate these issues, the coupling effects of multi-element doping and the corresponding performance enhancement mechanism have been yet unclear. Here, we report a Zr/Ti dual-doped NCM811 cathode material (ZT-NCM811), in which Zr-ion is doped into both transition metal (TM) layers and lithium layers and Ti-ion is only distributed in TM layers. The dual-doping can effectively enhance crystal structure stability via inhibiting the lattice collapse along c-axis and decreasing the Li/Ni disorder. Meantime, the lattice oxygen escape is also greatly reduced due to the presence of stronger Zr-O and Ti-O bonds, further mitigating the crystal surface parasitic reactions with electrolyte. The resultant ZT-NCM811 exhibits high specific capacity of 124 mAh/g at even 10 C, much higher than undoped and single-doped NCM811, and a retention of 98.8% at 1 C after 100 cycles. The assembled ZT-NCM811/graphite full cell also delivers superior battery performances and durability.
- LiNi_0.8Co_0.1Mn_0.1O₂,
- Dual-doping,
- High power,
- Cycling stability,
- Li-ion batteries
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Complementary dual-doping of LiNi0.8Co0.1Mn0.1O2 cathode enhances ion-diffusion and stability for Li-ion batteries

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通讯作者: 陈斌, bchen63@163.com

Complementary dual-doping of LiNi_0.8Co_0.1Mn_0.1O₂ cathode enhances ion-diffusion and stability for Li-ion batteries