Citation: Yijia Huang, Yidan Zhu, Hongyu Cheng, Meng Liu, Yingying Song, Xiaoliang Ding, Kaiyun Xu, Yinping Qin, Yang Liu, Bingkun Guo. Synergistic effect of fluorinated solvent and Mg²⁺ enabling 4.6 V LiCoO₂ performances[J]. Chinese Chemical Letters, ;2023, 34(6): 107711. doi: 10.1016/j.cclet.2022.07.054 shu

Synergistic effect of fluorinated solvent and Mg²⁺ enabling 4.6 V LiCoO₂ performances

Yijia Huang ^a ,
Yidan Zhu ^a ,
Hongyu Cheng ^a ,
Meng Liu ^a ,
Yingying Song ^a ,
Xiaoliang Ding ^a ,
Kaiyun Xu ^a ,
Yinping Qin ^a ,
Yang Liu ^{a, *,} ,
Bingkun Guo ^{a, b, *,}

a.
Materials Genome Institute, Shanghai University, Shanghai 200444, China
b.
Tianmu Lake Institute of Advanced Energy Storage Technology, Liyang 213300, China

liuyang81@shu.edu.cn

guobingkun@shu.edu.cn

Received Date: 3 June 2022
Revised Date: 14 July 2022
Accepted Date: 26 July 2022
Available Online: 27 July 2022

Figures(4)

Increasing the charging cut-off potential of lithium cobalt oxide (LiCoO₂, LCO) can effectively improve the energy density of the lithium-ion batteries, which are the mainstream energy storage devices used in 3C electronic products. However, the continuous decomposition of the electrolyte and dissolution of Co from the electrode will occur at high-potential operation, which deteriorate the performances of LCO. Here, a cathode-electrolyte interface (CEI) layer containing MgF₂ is constructed to enhance the electrochemical stability of LCO at 4.6 V (vs. Li⁺/Li). The Mg²⁺ added to the cathode gradually releases into the electrolyte during cycling, which forms a stable MgF₂-rich protective layer. In addition, 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether (TTE) is added to the electrolyte acting as a F source to increase the content of MgF₂ in the CEI layer. The MgF₂-rich CEI layer effectively suppresses the decomposition of electrolyte components and the dissolution of Co of LCO, which makes the Li||LiCoO₂ (Li||LCO) cell cycled stably at 3~4.6 V (vs. Li⁺/Li) in 200 cycles with a retention of 83.9%.
- 4.6 V,
- LiCoO₂,
- Fluorinated solvent,
- Mg²⁺ additive,
- Lithium metal
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沈阳化工大学材料科学与工程学院沈阳 110142

Synergistic effect of fluorinated solvent and Mg2+ enabling 4.6 V LiCoO2 performances

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通讯作者: 陈斌, bchen63@163.com

Synergistic effect of fluorinated solvent and Mg²⁺ enabling 4.6 V LiCoO₂ performances