Citation: Xianyu Liu, Qiongqiong Lu, Aikai Yang, Yitai Qian. High ionic conductive protection layer on Zn metal anode for enhanced aqueous zinc-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(6): 107703. doi: 10.1016/j.cclet.2022.07.046 shu

High ionic conductive protection layer on Zn metal anode for enhanced aqueous zinc-ion batteries

Xianyu Liu ^{a, d} ,
Qiongqiong Lu ^{b, *,} ,
Aikai Yang ^c ,
Yitai Qian ^d

a.
School of Chemical Engineering, Lanzhou City University, Lanzhou 730070, China
b.
Leibniz Institute for Solid State and Materials Research (IFW) Dresden e.V., Helmholtzstraße 20, 01069 Dresden, Germany
c.
Materials Synthesis and Processing (IEK-1), Institute of Energy and Climate Research, Forschungszentrum Jülich GmbH, 52425, Jülich, Germany
d.
Hefei National Laboratory for Physical Science at the Microscale, Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026, China

q.lu@ifw-dresden.de

Received Date: 21 June 2022
Revised Date: 15 July 2022
Accepted Date: 20 July 2022
Available Online: 23 July 2022

Figures(4)

Aqueous zinc-ion batteries (ZIBs) has been regarded as a promising energy storage system for large-scale application due to the advantages of low cost and high safety. However, the growth of Zn dendrite, hydrogen evolution and passivation issues induce the poor electrochemical performance of ZIBs. Herein, a Na₃Zr₂Si₂PO₁₂ (NZSP) protection layer with high ionic conductivity of 2.94 mS/cm on Zn metal anode was fabricated by drop casting approach. The protection layer prevents Zn dendrites formation, hydrogen evolution as well as passivation, and facilitates a fast Zn²⁺ transport. As a result, the symmetric cells based on NZSP-coated Zn show a stable cycling over 1360 h at 0.5 mA/cm² with 0.5 mAh/cm² and 1000 h even at a high current density of 5 mA/cm² with 2 mAh/cm². Moreover, the full cells combined with V₂O₅-based cathode displays high capacities and high rate capability. This work offers a facile and effective approach to stabilizing Zn metal anode for enhanced ZIBs.
- Na₃Zr₂Si₂PO₁₂,
- High ionic conductivity,
- Drop casting,
- Surface coating,
- Zinc metal anode,
- Aqueous zinc-ion batteries
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