Citation: Xianqiang Huang, Weilong Cui, Sen Liu, Gang Liu, Yalin Zhang, Zhihao Zhang, Guodong Shen, Zhen Li, Jianyong Wang, Yifa Chen. One-step assembly of Pd-Keggin-polyoxometalates for catalytic benzothiadiazole generation and derived cell-imaging probe application[J]. Chinese Chemical Letters, ;2023, 34(6): 107692. doi: 10.1016/j.cclet.2022.07.035 shu

One-step assembly of Pd-Keggin-polyoxometalates for catalytic benzothiadiazole generation and derived cell-imaging probe application

Xianqiang Huang ^{a, *,} ,
Weilong Cui ^b ,
Sen Liu ^a ,
Gang Liu ^a ,
Yalin Zhang ^a ,
Zhihao Zhang ^b ,
Guodong Shen ^a ,
Zhen Li ^a ,
Jianyong Wang ^{b, *,} ,
Yifa Chen ^{c, d, *,}

a.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059, China
b.
Key Laboratory of Biobased Material and Green Papermaking, Key Laboratory of Pulp & Paper Science and Technology of Shandong Province/Ministry of Education, Qilu University of Technology (Shandong Academy of Sciences), Ji'nan 250353, China
c.
National and Local Joint Engineering Research Center of MPTES in High Energy and Safety LIBs, Engineering Research Center of MTEES (Ministry of Education), Key Lab. of ETESPG(GHEI), South China Normal University, Guangzhou 510006, China
d.
Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China

hxq@lcu.edu.cn

wjy@qlu.edu.cn

chyf927821@163.com

Received Date: 2 May 2022
Revised Date: 1 June 2022
Accepted Date: 17 July 2022
Available Online: 19 July 2022

Figures(7)

One-step assembly of organic-ligand modified Pd-Keggin-POMs has been rarely reported, so as for their applications in catalytic benzothiadiazole generation and derived cell-imaging probing. Herein, three Pd-Keggin-POMs (compounds 1–3) have been successfully synthesized via a one-step assembly strategy. Thus-obtained Pd-Keggin-POMs with well-defined structures and heterogeneous properties enable highly efficient catalytic benzothiadiazole generation. Specifically, compound 3 showed outstanding catalytic activities in Suzuki-Miyaura coupling reactions for the generation of benzothiadiazole derivatives (yields, 90%-97%) and was represented as one of the best catalysts reported to date. Consequently, the obtained benzothiadiazoles were used as the bio-probe for tracking lipid droplets in living-cells and exhibited large Stokes shifts (130 nm), low cytotoxicity and good targeting, which could be also applied to mark the distribution of LDs in living HeLa cells. Systematic investigations clearly decipher the functions of Pd-Keggin-POMs toward finding novel bio-probe materials, highlighting a new insight into the generation of sustainable materials in life-science.
- Metal-organic-pallidum-POMs,
- Crystal structure,
- Suzuki-Miyaura,
- Fluorescent probe,
- LDs
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