Citation: Yali Hou, Ruping Shi, Hongye Yuan, Mingming Zhang. Highly emissive perylene diimide-based bowtie-shaped metallacycles[J]. Chinese Chemical Letters, ;2023, 34(4): 107688. doi: 10.1016/j.cclet.2022.07.031 shu

Highly emissive perylene diimide-based bowtie-shaped metallacycles

State Key Laboratory for Mechanical Behavior of Materials, Shaanxi International Research Center for Soft Matter, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China

hongye.yuan@xjtu.edu.cn

mingming.zhang@xjtu.edu.cn

Received Date: 7 May 2022
Revised Date: 9 July 2022
Accepted Date: 15 July 2022
Available Online: 19 July 2022

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Metallacycles hold great promise for fluorescence-based sensing due to their synthetic advantages and unique physicochemical properties. However, it remains highly challenging to develop a versatile methodology for constructing highly emissive metallacycles with targeted functionalities and therefore sought-after properties. Herein, we report a general strategy to construct a series of highly emissive perylene diimide-based metallacycles via the self-assembly of perylene diimide-based tetrapyridyl ligand with different dicarboxylic ligands featuring fixed angles and cis-Pt(PEt₃)₂(OTf)₂. Single crystal X-ray diffraction analyses verify the formation of bowtie-like metallacycles with two triangular cavities. Notably, the fluorescence quantum yields of most assemblies exceed 98%, amongst the highest values for metallacycles. Additionally, such metallacycles exhibit sensitive fluorescence responses toward picric acid with a detection limit of 2.8 × 10⁻⁶ mol/L. This study not only provides a rational strategy for preparing highly emissive bowtie-shaped metallacycles, but also sheds light on their usage in the detection of picric acid and associated compounds.
- Fluorescence materials,
- Emissive metallacycles,
- Self-assembly,
- Perylene diimide,
- Picric acid sensing
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