Citation: Na Li, Xixi Zhang, Shunshun Zhao, Chuanlin Li, Xiaojuan Li, Tongkai Wang, Yupeng Xing, Gangmeng Qu, Xijin Xu. Amorphous nickel borate nanosheets as cathode material with high capacity and better cycling performance for zinc ion battery[J]. Chinese Chemical Letters, ;2023, 34(6): 107669. doi: 10.1016/j.cclet.2022.07.012 shu

Amorphous nickel borate nanosheets as cathode material with high capacity and better cycling performance for zinc ion battery

Na Li ^a ,
Xixi Zhang ^a ,
Shunshun Zhao ^b ,
Chuanlin Li ^a ,
Xiaojuan Li ^a ,
Tongkai Wang ^a ,
Yupeng Xing ^a ,
Gangmeng Qu ^a ,
Xijin Xu ^{a, *,}

a.
School of Physics and Technology, University of Jinan, Ji'nan 250022, China
b.
School of Electronic and Information Engineering (Department of Physics), Qilu University of Technology (Shandong Academy of Sciences), Ji'nan 250353, China

sps_xuxj@ujn.edu.cn

Received Date: 20 May 2022
Revised Date: 16 June 2022
Accepted Date: 6 July 2022
Available Online: 12 July 2022

Figures(5)

Zinc-ion batteries are under current research focus because of their uniqueness in low cost and high safety. However, the pursuing of high-performance cathode materials of aqueous Zinc ion batteries (AZBs) with low cost, high energy density and long cycle life has become the key problem to be solved. Herein we synthesized a series of amorphous nickel borate (AM-NiBO) nanosheets by varying corrosion time with in-situ electrochemical corrosion method. The AM-NiBO-T13 as electrode material possesses a high areal capacity of 0.65 mAh/cm² with the capacity retention of 95.1% after 2000 cycles. In addition, the assembled AM-NiBO-T13//Zn provides high energy density (0.77 mWh/cm² at 1.76 mW/cm²). The high areal capacity and better cycling performance can be owing to the amorphous nanosheets structure and the stable coordination characteristics of boron and oxygen in borate materials. It shows that amorphous nickel borate nanosheets have great prospects in the field of energy storage.
- Amorphous,
- Nickel borate,
- Nanosheets structure,
- Alkaline,
- Aqueous zinc ion battery
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