Citation: Shan Li, Jian-Hui Wang, Long-Zhang Dong, Yu Zhang, Xiao-Man Yao, Yifa Chen, Shun-Li Li, Ya-Qian Lan. Three-in-one Fe-porphyrin based hybrid nanosheets for enhanced CO₂ reduction and evolution kinetics in Li-CO₂ battery[J]. Chinese Chemical Letters, ;2023, 34(6): 107633. doi: 10.1016/j.cclet.2022.06.056 shu

Three-in-one Fe-porphyrin based hybrid nanosheets for enhanced CO₂ reduction and evolution kinetics in Li-CO₂ battery

Shan Li ^{a, 1} ,
Jian-Hui Wang ^{a, 1} ,
Long-Zhang Dong ^{a, 1} ,
Yu Zhang ^a ,
Xiao-Man Yao ^b ,
Yifa Chen ^{a, b, *,} ,
Shun-Li Li ^{a, b} ,
Ya-Qian Lan ^{a, b, *,}

a.
Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China
b.
National and Local Joint Engineering Research Center of MPTES in High Energy and Safety LIBs, Engineering Research Center of MTEES (Ministry of Education), Key Lab. of ETESPG (GHEI), School of Chemistry, South China Normal University, Guangzhou 510006, China

chyf927821@163.com

yqlan@m.scnu.edu.cn

Received Date: 4 May 2022
Revised Date: 31 May 2022
Accepted Date: 21 June 2022
Available Online: 25 June 2022

Figures(4)

Efficient cathode-catalysts with multi-functional properties are essential for Li-CO₂ battery, while the construction of them with simultaneously enhanced CO₂ reduction and evolution kinetics is still challenging. Here, a kind of hybrid nanosheets based on Ru nanoparticles, Fe-TAPP and grapheme oxide (GO) has been designed through a one-pot self-assembly strategy. The Ru, Fe-porphyrin and GO based hybrid nanosheets (denoted as Ru/Fe-TAPP@GO) with integrated multi-components offer characteristics of ultrathin thickness (~4 nm), high electro-redox property, uniformly dispersed morphology, and high electrical conductivity, etc. These features endow Ru/Fe-TAPP@GO with ultra-low overpotential (0.82 V) and fully reversible discharge/charge property with a high specific-capacity of 39,000 mAh/g within 2.0–4.5 V at 100 mA/g, which are much superior to Ru@GO and Fe-TAPP@GO. The achieved performance was presented as one of the best cathode-catalysts reported to date. The synergistically enhanced activity originated from the integrated hybrid nanosheets may provide a new pathway for designing efficient cathode-catalysts for Li-CO₂ batteries.
- Single-metal sites,
- Porphyrin,
- Li-CO₂ battery,
- Cathode catalyst,
- Ru nanoparticles
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沈阳化工大学材料科学与工程学院沈阳 110142

Three-in-one Fe-porphyrin based hybrid nanosheets for enhanced CO2 reduction and evolution kinetics in Li-CO2 battery

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通讯作者: 陈斌, bchen63@163.com

Three-in-one Fe-porphyrin based hybrid nanosheets for enhanced CO₂ reduction and evolution kinetics in Li-CO₂ battery