Citation: Guoling Li, Yang Liu, Wei Wang, Zhu Zhuo, Yougui Huang. A cobalt redox switch driving alcohol dehydrogenation by redox coupled molecular swing[J]. Chinese Chemical Letters, ;2023, 34(6): 107630. doi: 10.1016/j.cclet.2022.06.053 shu

A cobalt redox switch driving alcohol dehydrogenation by redox coupled molecular swing

Guoling Li ^{a, b} ,
Yang Liu ^{a, b} ,
Wei Wang ^{a, b} ,
Zhu Zhuo ^{a, b} ,
Yougui Huang ^{a, b, c, *,}

a.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Xiamen 361021, China
b.
Xiamen Institute of Rare Earth Materials, Haixi Institute, Chinese Academy of Sciences, Xiamen 361021, China
c.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

yghuang@fjirsm.ac.cn

Received Date: 6 June 2022
Revised Date: 16 June 2022
Accepted Date: 21 June 2022
Available Online: 24 June 2022

Figures(4)

Developing redox switches that not only perform specific mechanical movements but also drive important chemical reactions is important but a great challenge. Herein, we report a redox pair of cobalt species (Co^Ⅲ/Co^Ⅱ) that switches through photo-dehydrogenation of alcohol and hydrogenation of azo-ligand. The cobalt species is equipped with a flexible azo-ligand containing two bulky planar substituents. A planar oxidated sate (Co^Ⅲ species) can be photo-reduced to a saddle-like reduced state (Co^Ⅱ) with alcohol molecules as electron donors, and in turn the Co^Ⅲ species can be recovered with azo-ligand as oxidant under acidic surrounding. Both the redox states of the pair are isolated and characterized by single crystal X-ray diffraction. In the switching cycle, alcohol is oxidized to aldehyde by azo-ligand through proton coupled electron transfer and the cobalt complex acts as a redox catalyst. These results provide important insights into alcohol dehydrogenation catalyzed by redox complexes.
- Redox switch,
- Alcohol dehydrogenation,
- Azo-ligand hydrogenation,
- Cobalt complex,
- Mechanical motion
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