Citation: Pengna Shang, Xiaoli Yan, Yang Li, Junji Liu, Guang Zhang, Long Chen. Heterogeneous photocatalytic borylation of aryl iodides mediated by isoreticular 2D covalent organic frameworks[J]. Chinese Chemical Letters, ;2023, 34(5): 107584. doi: 10.1016/j.cclet.2022.06.007 shu

Heterogeneous photocatalytic borylation of aryl iodides mediated by isoreticular 2D covalent organic frameworks

Pengna Shang ^{a, 1} ,
Xiaoli Yan ^{a, 1} ,
Yang Li ^a ,
Junji Liu ^{a, *,} ,
Guang Zhang ^{a, *,} ,
Long Chen ^{a, b, *,}

a.
Department of Chemistry and Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300072, China
b.
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

liujunji@tju.edu.cn

gzhdream@live.com

longchen@jlu.edu.cn

Received Date: 6 April 2022
Revised Date: 22 May 2022
Accepted Date: 6 June 2022
Available Online: 10 June 2022

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Metal-free heterogeneous photocatalysts provide an environmental-friendly and cost-efficient avenue for green organic synthesis. Covalent organic frameworks (COFs) as heterogeneous photocatalysts showcase promising potential in the field of photocatalytic organic reactions due to their high porosity, insolubility and tailor-made functions. However, thus far, COF-based catalysts only mediated a few types of reactions. Herein, we developed a series of isoreticular nitrogen-rich covalent organic frameworks (N-COFs) with comparable porous structures as photocatalysts which effectively mediated the borylation of aryl iodides with broad substrate scope. Remarkably, 6N-COF exhibits excellent photocatalytic efficiency and superior recyclability. It suggests a new pathway to construct efficient heterogeneous photocatalysts for the borylation of aryl halides.
- Covalent organic frameworks,
- Nitrogen-rich,
- Heterogeneous photocatalysis,
- Borylation,
- Green organic synthesis
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