Citation: Yan Zhang, Lei Zhou, Lei Zhang, Wei Luo, Wei Shen, Ming Li, Rongxing He. Highly stable metal halides Cs₂ZnX₄ (X = Cl, Br) with Sn²⁺ as dopants for efficient deep-red photoluminescence[J]. Chinese Chemical Letters, ;2023, 34(2): 107556. doi: 10.1016/j.cclet.2022.05.070 shu

Highly stable metal halides Cs₂ZnX₄ (X = Cl, Br) with Sn²⁺ as dopants for efficient deep-red photoluminescence

Key Laboratory of Luminescence Analysis and Molecular Sensing (Southwest University), Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

herx@swu.edu.cn

Received Date: 7 February 2022
Revised Date: 26 April 2022
Accepted Date: 21 May 2022
Available Online: 26 May 2022

Figures(4)

The development of deep-red emitting lead-free metal-halide perovskites with high photoluminescence quantum yields (PLQYs) and outstanding stability remains a major challenge for displays and deep-tissue bioimaging. In this work, we report a facile and convenient solvothermal method to synthesize metal halides Cs₂ZnX₄ (X = Cl, Br) that however is PL innert at room temperature. Upon composition engineering utilizing Sn²⁺ as the dopant, the resulting Cs₂ZnCl₄: Sn not only emits strong deep-red PL peaked at 700 nm with the highest 99.4% PLQY among the similar materials so far, but also exhibits excellent structure stability in air (PLQY remains 96% after one year exposure to the atmosphere). Detailed experimental characterizations and theoretical calculations reveal that the deep-red emission stems from self-trapped excitons induced by the Sn²⁺ dopant. Particularly, triplet emission (³P₂→¹S₀) from Sn-5s² orbitals has been observed at low temperature due to the break of parity-forbidden transition. This work provides an important guidance for the development of deep-red light-emitting materials with low price, high efficiency and excellent stability.
- Lead-free metal halides,
- Deep-red emission,
- Photoluminescence,
- High efficiency,
- Stability
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沈阳化工大学材料科学与工程学院沈阳 110142

Highly stable metal halides Cs2ZnX4 (X = Cl, Br) with Sn2+ as dopants for efficient deep-red photoluminescence

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通讯作者: 陈斌, bchen63@163.com

Highly stable metal halides Cs₂ZnX₄ (X = Cl, Br) with Sn²⁺ as dopants for efficient deep-red photoluminescence