Citation: Qiangqiang Jia, Ting Shao, Liang Tong, Changyuan Su, Dawei Fu, Haifeng Lu. Lead-free bilayer heterometallic halide perovskite with reversible phase transition and photoluminescence properties[J]. Chinese Chemical Letters, ;2023, 34(4): 107539. doi: 10.1016/j.cclet.2022.05.053 shu

Lead-free bilayer heterometallic halide perovskite with reversible phase transition and photoluminescence properties

Qiangqiang Jia ^a ,
Ting Shao ^a ,
Liang Tong ^c ,
Changyuan Su ^{b, *,} ,
Dawei Fu ^{a, b, **,} ,
Haifeng Lu ^{a, *,}

a.
Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China
b.
Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China
c.
School of Environment and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212002, China

^**

ScyWmy@163.com

dawei@zjnu.edu.cn

luhaifeng@zjnu.edu.cn

Received Date: 17 April 2022
Revised Date: 11 May 2022
Accepted Date: 17 May 2022
Available Online: 20 May 2022

Figures(4)

The layered heterometallic halide perovskites, as a newly explored material, have attracted great scientific attention. As one of the representatives of perovskite, lead-free or lead-substituted perovskite materials are widely applied in photovoltaic, sensors, catalysis, detectors and other fields. Therefore, it is urgent to carry out more systematic exploration and expand applicable preresearch, so as to make more interesting discoveries in this new hot spot. As an interesting candidate, heterometallic compounds will introduce more structural adjustability and novel physical properties, which is the main feature to be selected as the research hotspot. Here, we reported a lead-free bilayer heterometallic Ruddlesden-Popper (RP) type perovskite, [(MACH)₂CsAgBiBr₇] (MACH = cyclohexanemethylamine), which possesses a reversible phase transition at 379.6 K/375.1 K during heating-cooling cycle. Besides, it exhibits reddish-brown light emission under 365 nm, meanwhile, CIE chromaticity coordinate is (0.32, 0.45) on the yellow side and correlated color temperature is about 6000 K. Moreover, both the experimental data and theoretical calculation results suggest that [(MACH)₂CsAgBiBr₇] shows indirect semiconducting characteristics. In summary, this work will inspire the design of lead-free heterometallic perovskite materials for the application of sensors and light-emitting diodes (LEDs) fields.
- Lead-free,
- Heterometallic,
- Perovskite,
- Phase transition,
- Photoluminescence
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