Citation: Shuli Yao, Hui Xu, Tengfei Zheng, Yunwu Li, Haiping Huang, Jun Wang, Jinglin Chen, Suijun Liu, Herui Wen. Blue-shifted and naked-eye recognition of H₂PO₄⁻ and acetylacetone based on a luminescent metal−organic framework with new topology and good stability[J]. Chinese Chemical Letters, ;2023, 34(4): 107532. doi: 10.1016/j.cclet.2022.05.046 shu

Blue-shifted and naked-eye recognition of H₂PO₄⁻ and acetylacetone based on a luminescent metal−organic framework with new topology and good stability

Shuli Yao ^a ,
Hui Xu ^a ,
Tengfei Zheng ^a ,
Yunwu Li ^c ,
Haiping Huang ^a ,
Jun Wang ^b ,
Jinglin Chen ^a ,
Suijun Liu ^{a, b, *,} ,
Herui Wen ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China
b.
Fujian Key Laboratory of Functional Marine Sensing Materials, Minjiang University, Fuzhou 350108, China
c.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China

sjliu@jxust.edu.cn

wenherui63@163.com

Received Date: 17 March 2022
Revised Date: 8 May 2022
Accepted Date: 13 May 2022
Available Online: 17 May 2022

Figures(6)

Fluorescence detecting both organic and inorganic analytes has aroused tremendous scientific interests, because fluorescence techniques have high sensitivity and are easy to operate. A new three-dimensional (3D) MOF {[(CH₃)₂NH₂][Zn₃(bbip)(BTDI)_1.5(OH)]·DMF·MeOH·3H₂O}_n (JXUST-13, bbip = 2,6-bis(benzimidazol-1-yl)pyridine and H₄BTDI = 5,5′-(benzo[c][1,2,5]thiadiazole-4,7-diyl)diisophthalic acid) with new 4,4,8-connceted topology has been successfully synthesized and structurally characterized. Importantly, JXUST-13 could recognize H₂PO₄⁻ and acetylacetone (Acac) by obvious fluorescence blue shift and slight enhancement with the detection limits of 2.70 µmol/L and 0.21 mmol/L, respectively. In addition, JXUST-13 exhibits relatively good thermal stability, chemical stabilities as well as reusability, and the analytes could be distinguished by naked eye and fluorescence test paper. Remarkably, JXUST-13 is the first dual-responsive MOF sensor based on fluorescence blue shift for the detection of H₂PO₄⁻ and Acac with good selectivity in a handy, economic, and environmentally friendly manner.
- Metal-organic framework,
- Fluorescence sensing,
- Naked-eye recognition,
- Fluorescence blue shift,
- H₂PO₄⁻ and acetylacetone
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Blue-shifted and naked-eye recognition of H2PO4− and acetylacetone based on a luminescent metal−organic framework with new topology and good stability

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通讯作者: 陈斌, bchen63@163.com

Blue-shifted and naked-eye recognition of H₂PO₄⁻ and acetylacetone based on a luminescent metal−organic framework with new topology and good stability