Citation: Zongyuan You, Wei Hua, Na Li, Huanyan Liu, Jian-Gan Wang. An in-depth mechanistic insight into the redox reaction and degradation of aqueous Zn-MnO₂ batteries[J]. Chinese Chemical Letters, ;2023, 34(4): 107525. doi: 10.1016/j.cclet.2022.05.039 shu

An in-depth mechanistic insight into the redox reaction and degradation of aqueous Zn-MnO₂ batteries

State Key Laboratory of Solidication Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Shaanxi Joint Lab of Graphene (NPU), Xi'an 710072, China

wangjiangan@nwpu.edu.cn

Received Date: 19 April 2022
Revised Date: 6 May 2022
Accepted Date: 12 May 2022
Available Online: 16 May 2022

Figures(5)

Rechargeable aqueous Zn/MnO₂ batteries raise massive research activities in recent years. However, both the working principle and the degradation mechanism of this battery chemistry are still under debate. Herein, we provide an in-depth electrochemical and structural investigation on this controversial issue based on α-MnO₂ crystalline nanowires. Mechanistic analysis substantiates a two-electron reaction pathway of Mn²⁺/Mn⁴⁺ redox couple from part of MnO₂ accompanying with a reversible precipitation/dissolution of flaky zinc sulfate hydroxide (ZSH) during the discharge/charge processes. The formation of the ZSH layer is double-edged, which passivates the deep dissolution of MnO₂ upon discharging, but promotes the electrochemical deposition kinetics of active MnO₂ upon charging. The cell degradation originates primarily from the corrosion failure of metallic zinc anode and the accumulation of irreversible ZnMn₂O₄ phases on the cathode. The addition of MnSO₄ to the electrolyte could afford supplementary capacity contribution via electro-oxidation of Mn²⁺. However, a high MnSO₄ concentration will expedite the cell failure by corroding the metallic zinc anodes. The present study will shed a fundamental insight on developing new strategies toward practically viable Zn/MnO₂ batteries.
- Zinc-ion battery,
- MnO₂ cathode,
- Working mechanism,
- Degradation mechanism,
- Zinc anode
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An in-depth mechanistic insight into the redox reaction and degradation of aqueous Zn-MnO2 batteries

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通讯作者: 陈斌, bchen63@163.com

An in-depth mechanistic insight into the redox reaction and degradation of aqueous Zn-MnO₂ batteries