Citation: Yu Tian, Yuling Zhao, Fanqi Meng, Kaicheng Zhang, Yanyuan Qi, Yujie Zeng, Congcong Cai, Yuli Xiong, Zelang Jian, Yang Sun, Lin Gu, Wen Chen. Boosting Li-ion storage in Li₂MnO₃ by unequal-valent Ti⁴⁺-substitution and interlayer Li vacancies building[J]. Chinese Chemical Letters, ;2023, 34(4): 107494. doi: 10.1016/j.cclet.2022.05.008 shu

Boosting Li-ion storage in Li₂MnO₃ by unequal-valent Ti⁴⁺-substitution and interlayer Li vacancies building

Yu Tian ^{a, 1} ,
Yuling Zhao ^{b, 1} ,
Fanqi Meng ^{d, 1} ,
Kaicheng Zhang ^a ,
Yanyuan Qi ^a ,
Yujie Zeng ^a ,
Congcong Cai ^a ,
Yuli Xiong ^{a, e} ,
Zelang Jian ^{a, *,} ,
Yang Sun ^{b, c, *,} ,
Lin Gu ^{d, *,} ,
Wen Chen ^a

a.
School of Materials Science and Engineering Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
b.
School of Materials, Shenzhen Campus of Sun Yat-sen University, Shenzhen 518107, China
c.
21C Innovation Laboratory, Contemporary Amperex Technology Ltd. (CATL), Ningde 352100, China
d.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
e.
Sanya Science and Education Innovation Park of Wuhan University of Technology, Wuhan 430070, China

zelangjian@whut.edu.cn

sunyang5@mail.sysu.edu.cn

l.gu@iphy.ac.cn

Received Date: 7 February 2022
Revised Date: 10 March 2022
Accepted Date: 7 May 2022
Available Online: 11 May 2022

Figures(7)

Lithium rich layered oxide (LRLO) has been considered as one of the promising cathodes for lithium-ion batteries (LIBs). The high voltage and large capacity of LRLO depend on Li₂MnO₃ phase. To ameliorate the electrochemical performance of Li₂MnO₃, also written as Li(Li_1/3Mn_2/3)O₂, we propose a strategy to substitute Mn⁴⁺ and Li⁺ in Mn/Li transition metal layer with Ti⁴⁺, which can stabilize the structure of Li₂MnO₃ by inhibiting the excessive oxidation of O²⁻ above 4.5 V. More significantly, the unequal-valent substitution brings about the emergence of interlayer Li vacancies, which can promote the Li-ion diffusion based on the enlarged interlayer and increase the capacity by activating the Mn^3+/4+ redox. We designed Li_0.7[Li_1/3Mn_2/3]_0.7Ti_0.3O₂ with high interlayer Li vacancies, which presents a high capacity (290 mAh/g at 10 mA/g) and stable cycling performance (84% over 60 cycles at 50 mA/g). We predict that this strategy will be helpful to further improve the electrochemical performance of LRLOs.
- Lithium-ion batteries,
- Li₂MnO₃,
- Unequal-valent Ti⁴⁺-substitution,
- Interlayer Li vacancies,
- Activated Mn^3+/4+ redox
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沈阳化工大学材料科学与工程学院沈阳 110142

Boosting Li-ion storage in Li2MnO3 by unequal-valent Ti4+-substitution and interlayer Li vacancies building

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通讯作者: 陈斌, bchen63@163.com

Boosting Li-ion storage in Li₂MnO₃ by unequal-valent Ti⁴⁺-substitution and interlayer Li vacancies building