Citation: Mingming Han, Jingjing Yao, Jiwu Huang, Yan Tang, Xianwen Wu, Bingan Lu, Jiang Zhou. Synergistic chemical and electrochemical strategy for high-performance Zn//MnO₂ batteries[J]. Chinese Chemical Letters, ;2023, 34(2): 107493. doi: 10.1016/j.cclet.2022.05.007 shu

Synergistic chemical and electrochemical strategy for high-performance Zn//MnO₂ batteries

Mingming Han ^{a, 1} ,
Jingjing Yao ^{b, 1} ,
Jiwu Huang ^{a, *,} ,
Yan Tang ^a ,
Xianwen Wu ^c ,
Bingan Lu ^d ,
Jiang Zhou ^{a, *,}

a.
School of Materials Science & Engineering, Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials, Central South University, Changsha 410083, China
b.
Centre for Environment and Water Resources, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
c.
College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China
d.
School of Physics and Electronics, Hunan University, Changsha 410083, China

huangjw@csu.edu.cn

zhou_jiang@csu.edu.cn

Received Date: 18 March 2022
Revised Date: 28 April 2022
Accepted Date: 7 May 2022
Available Online: 11 May 2022

Figures(5)

Aqueous rechargeable Zn//MnO₂ batteries have been considered as the promising candidate for future energy storage system due to their economic and environmental merits. However, the high-performance Zn//MnO₂ batteries are plagued by poor sluggish reaction kinetics and capacity degradation due to the strong electrostatic interactions and complicated reaction process. Herein, the synergistic effect of atom defects engineering and phase transformation mechanism is confirmed as the effective strategy to enhance ion/charge transfer kinetics and structural stability. Defects gradient controlling and electrochemically induced phase transformation from spinel to layered structure render the aqueous Zn//λ-MnO₂ system delivers a high discharge capacity of 285 mAh/g and capacity retention of 81% after 500 cycles.
- Aqueous Zn//MnO₂ battery,
- Oxygen defects,
- Phase transformation,
- Electrochemical induce,
- Reaction mechanism
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synergistic chemical and electrochemical strategy for high-performance Zn//MnO2 batteries

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通讯作者: 陈斌, bchen63@163.com

Synergistic chemical and electrochemical strategy for high-performance Zn//MnO₂ batteries