Citation: Xinyi Liang, Xu Du, Ao Liu, Zhixiong Cai, Jingwen Li, Maosheng Zhang, Qingxiang Wang, Jingbin Zeng. Au/Ag₂S dimeric nanostructures for highly specific plasmonic sensing of mercury(Ⅱ)[J]. Chinese Chemical Letters, ;2023, 34(3): 107491. doi: 10.1016/j.cclet.2022.05.005 shu

Au/Ag₂S dimeric nanostructures for highly specific plasmonic sensing of mercury(Ⅱ)

Xinyi Liang ^a ,
Xu Du ^a ,
Ao Liu ^a ,
Zhixiong Cai ^b ,
Jingwen Li ^a ,
Maosheng Zhang ^b ,
Qingxiang Wang ^{b, *,} ,
Jingbin Zeng ^{a, *,}

a.
College of Chemistry and Chemical Engineering and State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, China
b.
College of Chemistry and Environment, Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, Minnan Normal University, Zhangzhou 363000, China

axiang236@vip.163.com

xmuzjb@163.com

Received Date: 15 January 2022
Revised Date: 16 April 2022
Accepted Date: 5 May 2022
Available Online: 10 May 2022

Figures(7)

Although many plasmonic nanosenosrs have been established for the detection of mercury(Ⅱ) (Hg²⁺), few of them is feasible for analyzing natural samples with very complex matrices because of insufficient method selectivity. To address this challenge, we propose an epitaxial and lattice-mismatch approach to the synthesis of a unique Au/Ag₂S dimeric nanostructure, which consists of an Au segment with excellent plasmonic characteristics, and a highly stable Ag₂S portion with minimum solubility product (K_sp(Ag₂S) = 6.3 × 10⁻⁵⁰). The detection relies on the chemical conversion of Ag₂S to HgS when reacting with Hg²⁺, resulting in a red shift in the absorption band of the connecting Au NPs. The concurrent color changes of the solution from gray purple to dark green and finally to navy correlate well with Hg²⁺ concentration, thus enables UV–vis quantitation and a naked-eye readout of the Hg²⁺ concentration. This method exhibits superior selectivity towards Hg²⁺ over other interfering ions tested because Hg²⁺ is the only ion that can react with Ag₂S to form HgS with even smaller solubility product (K_sp(HgS) = 4 × 10⁻⁵³). The detection limit of this method is 1.21 µmol/L, calculated by the signal-to-noise of 3. The practicability of the method was verified by analyzing the Hg²⁺ in sewage water samples without sample pretreatment with satisfactory recoveries (93.1%-102.8%) and relative standard deviations (1.38%-2.89%). We believe this method holds great potential for on-the-spot detection of Hg²⁺ in environmental water samples with complex matrices.
- Au/Ag₂S dimeric nanoparticles,
- Mercury ion,
- Colorimetric detection,
- High selectivity
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沈阳化工大学材料科学与工程学院沈阳 110142

Au/Ag2S dimeric nanostructures for highly specific plasmonic sensing of mercury(Ⅱ)

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通讯作者: 陈斌, bchen63@163.com

Au/Ag₂S dimeric nanostructures for highly specific plasmonic sensing of mercury(Ⅱ)