Citation: Longjiang Sun, Dongxu Wang, Yuxin Li, Baogang Wu, Qi Li, Cheng Wang, Shuao Wang, Baojiang Jiang. Fully conversing and highly selective oxidation of benzene to phenol based on MOFs-derived CuO@CN photocatalyst[J]. Chinese Chemical Letters, ;2023, 34(4): 107490. doi: 10.1016/j.cclet.2022.05.004 shu

Fully conversing and highly selective oxidation of benzene to phenol based on MOFs-derived CuO@CN photocatalyst

Longjiang Sun ^{a, b} ,
Dongxu Wang ^a ,
Yuxin Li ^{a, *,} ,
Baogang Wu ^a ,
Qi Li ^a ,
Cheng Wang ^{a, d, *,} ,
Shuao Wang ^c ,
Baojiang Jiang ^{a, *,}

a.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
b.
School of Pharmacy, Jiamusi University, Jiamusi 154007, China
c.
State Key Laboratory of Radiation Medicine and Protection School for Radiological and interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China
d.
Guangdong Laboratory of Chemitry and Fine Chemical Industry Jieyang Center, Guangdong University of Technology, Jieyang 510006, China

liyuxin@hlju.edu.cn

wangc_93@163.com

jbj@hlju.edu.cn

Received Date: 13 March 2022
Revised Date: 2 April 2022
Accepted Date: 4 May 2022
Available Online: 10 May 2022

Figures(4)

Developing highly efficient photocatalysts for selective oxidation of benzene to phenol is of great significance. However, it is still challenging to simultaneously achieve high conversion rate and selectivity. Herein, we demonstrate 99.9% of benzene photoconversion and 99.1% of phenol selectivity under the illumination of AM 1.5 for 12 h. For this purpose, an advanced CuO@CN photocatalyst has been fabricated by loading tubular carbon nitride (CN) with CuO nanoparticles thermally polymerized from Cu-based metal-organic frameworks (MOFs). The sluggish photocharge carrier recombination rate and the excellent stability indicate that the as-prepared nanocomposite is an ideal photocatalyst for benzene oxidation application. This work paves a new avenue for designing novel photocatalyst based on MOFs and carbon nitride materials.
- Photocatalysis,
- MOF,
- CuO@CN,
- Selectivity oxidation,
- Highly conversion rate
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