Citation: Jiaxing Qi, Jichao Gao, Ying Wang, Masaki Yoshio, Hongyu Wang. Intercalation behavior of spiro-bipyrrolidinium cation into graphite electrodes from ethylene carbonate[J]. Chinese Chemical Letters, ;2023, 34(4): 107475. doi: 10.1016/j.cclet.2022.04.073 shu

Intercalation behavior of spiro-bipyrrolidinium cation into graphite electrodes from ethylene carbonate

Jiaxing Qi ^{a, b} ,
Jichao Gao ^c ,
Ying Wang ^d ,
Masaki Yoshio ^e ,
Hongyu Wang ^{a, b, *,}

a.
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
c.
School of Chemistry and Chemical Engineering, Linyi University, Linyi 276000, China
d.
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
e.
Advanced Research Center, Saga University, 1341 Yoga-machi, Saga 840-0047, Japan

hongyuwang@ciac.ac.cn

Received Date: 18 April 2022
Accepted Date: 26 April 2022
Available Online: 1 May 2022

Figures(5)

The intercalation behavior of spiro-(1,1′)-bipyrrolidinium cation (SBP⁺) into graphite electrode from spiro-(1,1′)-bipyrrolidinium tetrafluoroborate-ethylene carbonate (SBPBF₄-EC) solutions is investigated by conventional electrochemical tests and in situ X-ray diffraction measurements. Two kinds of graphite intercalation compounds (GICs) with discrete characteristic intercalated gallery heights (IGHs) (ca. 0.95 and 0.75 nm) can be obtained with varying the salt concentration. The effect of graphite type is also addressed.
- Spiro-(1,1′)-bipyrrolidinium,
- Ethylene carbonate,
- Graphite intercalation compounds,
- Intercalated gallery height,
- Solvation,
- In situ XRD
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