Citation: Xue Dong, Zhifeng Xin, Dong He, Jia-Ling Zhang, Ya-Qian Lan, Qian-Feng Zhang, Yifa Chen. Boosting CO₂ electroreduction performance over fullerene-modified MOF-545-Co promoted by π–π interaction[J]. Chinese Chemical Letters, ;2023, 34(4): 107459. doi: 10.1016/j.cclet.2022.04.057 shu

Boosting CO₂ electroreduction performance over fullerene-modified MOF-545-Co promoted by π–π interaction

Xue Dong ^a ,
Zhifeng Xin ^{a, *,} ,
Dong He ^a ,
Jia-Ling Zhang ^a ,
Ya-Qian Lan ^{b, c} ,
Qian-Feng Zhang ^a ,
Yifa Chen ^{b, c, **,}

a.
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan 243002, China
b.
National and Local Joint Engineering Research Center of MPTES in High Energy and Safety LIBs, Engineering Research Center of MTEES (Ministry of Education), Key Lab. of ETESPG(GHEI), School of Chemistry, South China Normal University, Guangzhou 510006, China
c.
Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China

^**

xinzf521@ahut.edu.cn

chyf927821@163.com

Received Date: 23 February 2022
Revised Date: 30 March 2022
Accepted Date: 22 April 2022
Available Online: 27 April 2022

Figures(4)

Metal-organic frameworks (MOFs) have showed high promise in CO₂-electroreduction, yet their generally insufficient conductivity or low electron-transfer efficiency have largely restricted the wide-spread applications. Herein, fullerene molecules (i.e., C₆₀ and C₇₀) have been successfully introduced into the pore-channels of a Co-porphyrin based MOF through a facile strategy. Thus-obtained hybrid materials present higher electron-transfer ability, enhanced CO₂ adsorption-enthalpy and CO₂ electroreduction activity. Notably, the charge transfer resistance (R_ct) of C₆₀@MOF-545-Co is almost 5 times lower of than that of MOF-545-Co, as well as 1.5 times increased for the CO₂ adsorption enthalpy. As expect, the FE_CO of C₆₀@MOF-545-Co (97.0%) is largely higher than MOF-545-Co (70.2%), C₆₀@MOF-545 (19.4%), C₆₀ (11.5%) and physical mixture (70.3%) and presented as one of the best CO₂ electroreduction catalysts reported in H-cell system. The facile strategy would give rise to new insight into the exploration of powerful MOF-based hybrid materials in high-efficiency CO₂ electroreduction.
- Fullerene,
- Metal organic framework,
- Electrocatalytic performance,
- π-π interaction,
- CO₂RR
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Boosting CO2 electroreduction performance over fullerene-modified MOF-545-Co promoted by π–π interaction

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通讯作者: 陈斌, bchen63@163.com

Boosting CO₂ electroreduction performance over fullerene-modified MOF-545-Co promoted by π–π interaction