Citation: Qianxia Gu, Xiao-Li Zhao, Min Meng, Zhiyu Shao, Qi Zheng, Weimin Xuan. Crystalline porous ionic salts assembled from polyoxometalates and cationic capsule for the selective photocatalytic aerobic oxidation of aromatic alcohols to aldehydes[J]. Chinese Chemical Letters, ;2023, 34(4): 107444. doi: 10.1016/j.cclet.2022.04.042 shu

Crystalline porous ionic salts assembled from polyoxometalates and cationic capsule for the selective photocatalytic aerobic oxidation of aromatic alcohols to aldehydes

Qianxia Gu ^{a, 1} ,
Xiao-Li Zhao ^{b, 1} ,
Min Meng ^a ,
Zhiyu Shao ^{a, *,} ,
Qi Zheng ^{c, *,} ,
Weimin Xuan ^{a, *,}

a.
College of Chemistry, Chemical Engineering and Biotechnology & State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
b.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China
c.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials & College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

zyshao@dhu.edu.cn

qi.zheng@dhu.edu.cn

weiminxuan@dhu.edu.cn

Received Date: 23 February 2022
Revised Date: 16 March 2022
Accepted Date: 18 April 2022
Available Online: 21 April 2022

Figures(4)

Crystalline porous ionic salts (CPISs) represent a new type of porous materials constructed by electrostatic interaction, however, synthesis of CPISs bearing pre-designed functionality while exhibiting permanent porosity is still challenging. Herein we report the facile synthesis of a series of CPISs 1-3 built from photocatalytic-active polyoxometalate (POM) clusters and cationic Zr-based capsules, which showed open porous frameworks with BET surface area up to 33 m²/g and high activity and selectivity for photo-driven aerobic oxidation of alcohols to aldehydes. Compared with the pristine POM cluster {W₁₀}, 1 can promote the reaction in much higher efficiency due to the concerted catalysis of preinstalled {W₁₀} and Zr-based capsule together with open channels. This work highlights the advantage of CPISs as porous heterogeneous catalysts in organic transformation, and may shed light on the rational design of more delicate CPISs-derived functional materials.
- Crystalline porous ionic salts,
- Polyoxometalates,
- Cationic capsule,
- Photocatalysis,
- Oxidation
1. [1]
  M.E. Davis, Nature 417 (2002) 813–821. doi: 10.1038/nature00785
2. [2]
  A.G. Slater, A.I. Cooper, Science 348 (2015) aaa8075. doi: 10.1126/science.aaa8075
3. [3]
  T. Hasell, A.I. Cooper, Nat. Rev. Mater. 1 (2016) 16053. doi: 10.1038/natrevmats.2016.53
4. [4]
  L.H. Chen, M.H. Sun, Z. Wang, et al., Chem. Rev. 120 (2020) 11194–11294. doi: 10.1021/acs.chemrev.0c00016
5. [5]
  Y. Cui, B. Li, H. He, et al., Acc. Chem. Res. 49 (2016) 483–493. doi: 10.1021/acs.accounts.5b00530
6. [6]
  S.J. Lyle, P.J. Waller, O.M. Yaghi, Trends Chem. 1 (2019) 172–184. doi: 10.1016/j.trechm.2019.03.001
7. [7]
  B. Wang, R.B. Lin, Z. Zhang, et al., J. Am. Chem. Soc. 142 (2020) 14399–14416. doi: 10.1021/jacs.0c06473
8. [8]
  S. Yu, G.L. Xing, L.H. Chen, et al., Adv. Mater. 32 (2020) e2003270. doi: 10.1002/adma.202003270
9. [9]
  S. Uchida, Struct. Bond. 176 (2018) 65–88.
10. [10]
  G. Xing, T. Yan, S. Das, et al., Angew. Chem. Int. Ed. 57 (2018) 5345–5349. doi: 10.1002/anie.201800423
11. [11]
  X. Meng, H.N. Wang, S.Y. Song, et al., Chem. Soc. Rev. 46 (2017) 464–480. doi: 10.1039/C6CS00528D
12. [12]
  S. Uchida, A. Lesbani, Y. Ogasawara, et al., Inorg. Chem. 51 (2012) 775–777. doi: 10.1021/ic2025186
13. [13]
  R. Kawahara, R. Osuga, J.N. Kondo, et al., Dalton Trans. 46 (2017) 3105–3109. doi: 10.1039/C6DT04552A
14. [14]
  S. Seino, R. Kawahara, Y. Ogasawara, et al., Angew. Chem. Int. Ed. 55 (2016) 3987–3991. doi: 10.1002/anie.201511633
15. [15]
  G. Xing, I. Bassanetti, S. Bracco, et al., Chem. Sci. 10 (2019) 730–736. doi: 10.1039/c8sc04376k
16. [16]
  A. Comotti, S. Bracco, P. Sozzani, Acc. Chem. Res. 49 (2016) 1701–1710. doi: 10.1021/acs.accounts.6b00215
17. [17]
  L. Cronin, A. Mgller (Eds.), Themed issue: Polyoxometalate Cluster Science, Chem. Soc. Rev. 41 (2012) 7325–7648.
18. [18]
  A. Müller, M.T. Pope, Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications, Kluwer, Dordrecht, 2001.
19. [19]
  Z. Wei, Y. Chang, H. Yu, et al., Acta Chim. Sin. 78 (2020) 725–732. doi: 10.6023/a20050187
20. [20]
  J. Wang, H. Yu, Z. Wei, et al., Research 2020 (2020) 3875920.
21. [21]
  Y. Gu, Q. Li, D. Zang, et al., Angew. Chem. Int. Ed. 60 (2021) 13310–13316. doi: 10.1002/anie.202011164
22. [22]
  M. Zhang, Y. Zhai, S. Ru, et al., Chem. Commun. 54 (2018) 10164–10167. doi: 10.1039/C8CC03722A
23. [23]
  Z. Wei, S. Ru, Q. Zhao, et al., Green Chem. 21 (2019) 4069–4075. doi: 10.1039/c9gc01248f
24. [24]
  G.P. Yang, X.L. Zhang, Y.F. Liu, et al., Inorg. Chem. Front. 8 (2021) 4650–4656. doi: 10.1039/d1qi00485a
25. [25]
  Y. Ma, F. Gao, W. Xiao, et al., Chin. Chem. Lett. 33 (2022) 4395–4399. doi: 10.1016/j.cclet.2021.12.023
26. [26]
  K. Suzuki, Y. Kikukawa, S. Uchida, et al., Angew. Chem. Int. Ed. 51 (2012) 1597–1601. doi: 10.1002/anie.201107041
27. [27]
  R. Kawahara, K. Niinomi, J.N. Kondo, et al., Dalton Trans. 45 (2016) 2805–2809. doi: 10.1039/C5DT04556H
28. [28]
  K. Mizuno, T. Mura, S. Uchida, Cryst. Growth Des. 16 (2016) 4968–4974. doi: 10.1021/acs.cgd.6b00555
29. [29]
  H. Vardhan, M. Yusubov, F. Verpoort, Coord. Chem. Rev. 306 (2016) 171–194. doi: 10.1016/j.ccr.2015.05.016
30. [30]
  S. Lee, H. Jeong, D. Nam, et al., Chem. Soc. Rev. 50 (2021) 528–555. doi: 10.1039/d0cs00443j
31. [31]
  J.L. Bolliger, A.M. Belenguer, J.R. Nitschke, Angew. Chem. Int. Ed. 52 (2013) 7958–7962. doi: 10.1002/anie.201302136
32. [32]
  G. Liu, Z. Ju, D. Yuan, et al., Inorg. Chem. 52 (2013) 13815–13817. doi: 10.1021/ic402428m
33. [33]
  Y.P. He, L.B. Yuan, G.H. Chen, et al., J. Am. Chem. Soc. 139 (2017) 16845–16851. doi: 10.1021/jacs.7b09463
34. [34]
  H. Takezawa, R. Tabuchi, H. Sunohara, et al., J. Am. Chem. Soc. 142 (2020) 17919–17922. doi: 10.1021/jacs.0c08835
35. [35]
  Y. Zhang, X. Wang, S. Li, et al., Inorg. Chem. 55 (2016) 8770–8775. doi: 10.1021/acs.inorgchem.6b01338
36. [36]
  E.J. Gosselin, G.E. Decker, A.M. Antonio, et al., J. Am. Chem. Soc. 142 (2020) 9594–9598. doi: 10.1021/jacs.0c02806
37. [37]
  B. Le Ouay, H. Yoshino, K. Sasaki, et al., Chem. Commun. 57 (2021) 5187–5190. doi: 10.1039/D1CC01185E
38. [38]
  A.L. Spek, Acta Crystallogr. C: Struct. Chem. 71 (2015) 9–18. doi: 10.1107/S2053229614024929
39. [39]
  K. Suzuki, N. Mizuno, K. Yamaguchi, ACS Catal. 8 (2018) 10809–10825. doi: 10.1021/acscatal.8b03498
40. [40]
  R.A. Sheldon, I.W.C.E. Arends, A. Dijksman, Catal. Today 57 (2000) 157–166. doi: 10.1016/S0920-5861(99)00317-X
41. [41]
  G. Tojo, M. Fernández, Oxidations of Alcohols to Aldehydes and Ketones, Springer, New York, 2006.
42. [42]
  G.J. Brink, I.W.C.E. Arends, R.A. Sheldon, Science 287 (2000) 1636–1639. doi: 10.1126/science.287.5458.1636
43. [43]
  R.A. Sheldon, I.W.C.E. Arends, G.J. Ten Brink, et al., Acc. Chem. Res. 35 (2002) 774–781. doi: 10.1021/ar010075n
44. [44]
  M.D. Tzirakis, I.N. Lykakis, M. Orfanopoulos, Chem. Soc. Rev. 38 (2009) 2609–2621. doi: 10.1039/b812100c
45. [45]
  J. Li, B. Chang, H. Zhao, et al., J. Mater. Sci. 56 (2021) 6676–6688. doi: 10.1007/s10853-020-05707-y
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