Citation: Yong Tong, Yuanji Wu, Zihao Liu, Yongshi Yin, Yingjuan Sun, Hongyan Li. Fabricating multi-porous carbon anode with remarkable initial coulombic efficiency and enhanced rate capability for sodium-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(1): 107443. doi: 10.1016/j.cclet.2022.04.041 shu

Fabricating multi-porous carbon anode with remarkable initial coulombic efficiency and enhanced rate capability for sodium-ion batteries

College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou 510632, China

lihongyan@jnu.edu.cn

Received Date: 14 March 2022
Accepted Date: 18 April 2022
Available Online: 20 April 2022

Figures(5)

Due to the abundant sodium reserves and high safety, sodium ion batteries (SIBs) are foreseen a promising future. While, hard carbon materials are very suitable for the anode of SIBs owing to their structure and cost advantages. However, the unsatisfactory initial coulombic efficiency (ICE) is one of the crucial blemishes of hard carbon materials and the slow sodium storage kinetics also hinders their wide application. Herein, with spherical nano SiO₂ as pore-forming agent, gelatin and polytetrafluoroethylene as carbon sources, a multi-porous carbon (MPC) material can be easily obtained via a co-pyrolysis method, by which carbonization and template removal can be achieved synchronously without the assistance of strong acids or strong bases. As a result, the MPC anode exhibited remarkable ICE of 83% and a high rate capability (208 mAh/g at 5 A/g) when used in sodium-ion half cells. Additionally, coupling with Na₃V₂(PO₄)₃ as the cathode to assemble full cells, the as-fabricated MPC//NVP full cell delivered a good rate capability (146 mAh/g at 5 A/g) as well, implying a good application prospect the MPC anode has
- Multi-porous carbon,
- Initial coulombic efficiency,
- Rate capability,
- Sodium ion batteries,
- Silica template
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