Citation: Caocao Sun, Guoyin Yin. Integrating aryl chlorides into nickel-catalyzed 1,1-difunctionalization of alkenes[J]. Chinese Chemical Letters, ;2022, 33(12): 5096-5100. doi: 10.1016/j.cclet.2022.04.026 shu

Integrating aryl chlorides into nickel-catalyzed 1,1-difunctionalization of alkenes

Caocao Sun ,
Guoyin Yin ^*,

The Institute for Advanced Studies, Wuhan University, Wuhan 430072, China

yinguoyin@whu.edu.cn

Received Date: 19 February 2022
Revised Date: 8 April 2022
Accepted Date: 12 April 2022

Figures(5)

Difunctionalization of alkenes have developed into an important type of reactions for rapidly and efficiently assemble complex molecules. While extensive advancements have been achieved by the assistance of transition metal catalysis, the employment of cheap, abundant aryl chlorides as coupling partner is still a challenging task in this field. Herein, we report our first achievement in 1,1-difunctionalization of alkenes with aryl chlorides as coupling partners. The success is predominantly ascribed to the judicious selection of 1,2-diamine ligand. This study provides an efficient protocol for the synthesis of secondary benzyl boronates from easily accessible feedstock chemicals. Furthermore, the distinguished features of this method include excellent 1,1-regio- and chemoselectivity, good functional group tolerance and easily-operational catalytic reaction conditions.
- Aryl chlorides,
- Difunctionalization of alkenes,
- Regioselectivity,
- Nickel catalysis
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