Citation: Pengcheng Liu, Peng Xiao, Ming Lu, Hui Wang, Na Jin, Zifeng Lin. Lithium storage properties of Ti₃C₂T_x (T_x = F, Cl, Br) MXenes[J]. Chinese Chemical Letters, ;2023, 34(4): 107426. doi: 10.1016/j.cclet.2022.04.024 shu

Lithium storage properties of Ti₃C₂T_x (T_x = F, Cl, Br) MXenes

Pengcheng Liu ^a ,
Peng Xiao ^a ,
Ming Lu ^b ,
Hui Wang ^c ,
Na Jin ^a ,
Zifeng Lin ^{a, d, *,}

a.
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China
b.
The Joint Laboratory of MXene Materials, Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Changchun 130103, China
c.
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
d.
Engineering Research Center of Alternative Energy Materials and Devices, Ministry of Education, Chengdu 610065, China

linzifeng@scu.edu.cn

Received Date: 23 March 2022
Revised Date: 6 April 2022
Accepted Date: 7 April 2022
Available Online: 12 April 2022

Figures(4)

In this work, Ti₃C₂T_x MXene with -F, -Cl and -Br surface terminations are synthesized and the effect of these halogen terminations on the lithium storage properties is investigated. A maximum Li⁺ storage capacity of 189 mAh/g is achieved with Ti₃C₂Br_x MXene much higher than Ti₃C₂Cl_x and Ti₃C₂F_x with 138 mAh/g and 123 mAh/g, respectively. Density functional theory (DFT) calculation shows that the adsorption formation energy of halogen atoms on Ti atoms follows the trend of Ti-F > Ti-Cl > Ti-Br, leading to the same trend in the content of terminations on corresponding MXenes. In addition, inevitable exposure of MXene to oxygen causes competition between halogen and oxygen. Theoretical results show Ti₃C₂Br_x MXene has the highest Ti to O ratio and the lowest Ti to Br ratio, the high lithium affinity of O explains the maximum Li-ion storage capacity with Ti₃C₂Br_x MXene. This work shed light on the opportunity for achieving improved lithium storage properties of MXene electrodes by regulating the surface chemistry.
- MXene,
- Molten salt synthesis,
- Halogen termination,
- Li⁺ storage,
- Electrochemistry
1. [1]
  C.F. Zhang, L. McKeon, M.P. Kremer, et al., Nat. Commun. 10 (2019) 1795. doi: 10.1002/ese3.391
2. [2]
  B. Guan, X. Sun, Y. Zhang, et al., Chin. Chem. Lett. 32 (2021) 2249–2253. doi: 10.1016/j.cclet.2020.12.051
3. [3]
  J. Luo, X. Lu, E. Matios, et al., Nano Lett. 20 (2020) 7700–7708. doi: 10.1021/acs.nanolett.0c03215
4. [4]
  J. Luo, J. Zheng, J. Nai, et al., Adv. Funct. Mater. 29 (2019) 1808107. doi: 10.1002/adfm.201808107
5. [5]
  W. Yuan, X. Qu, Y. Lu, et al., Chin. Chem. Lett. 32 (2021) 2021–2026. doi: 10.1016/j.cclet.2020.12.003
6. [6]
  Y. Yao, J. Zhao, X. Yang, C. Chai, Chin. Chem. Lett. 32 (2021) 620–634. doi: 10.1016/j.cclet.2020.07.029
7. [7]
  T. Xu, J. Wang, Y. Cong, et al., Chin. Chem. Lett. 31 (2020) 1022–1025. doi: 10.1016/j.cclet.2019.11.038
8. [8]
  M.K. Han, C.E. Shuck, R. Rakhmanov, et al., ACS Nano 14 (2020) 5008–5016. doi: 10.1021/acsnano.0c01312
9. [9]
  Y. Gogotsi, B. Anasori, ACS Nano 13 (2019) 8491–8494. doi: 10.1021/acsnano.9b06394
10. [10]
  M. Naguib, M. Kurtoglu, V. Presser, et al., Adv. Mater. 23 (2011) 4248–4253. doi: 10.1002/adma.201102306
11. [11]
  M. Ghidiu, M.R. Lukatskaya, M.Q. Zhao, Y. Gogotsi, M.W. Barsoum, Nature 516 (2014) 78–81. doi: 10.1038/nature13970
12. [12]
  T. Li, L. Yao, Q. Liu, et al., Angew. Chem. Int. Ed. 57 (2018) 6115–6119. doi: 10.1002/anie.201800887
13. [13]
  M. Li, X.L. Li, G.F. Qin, et al., ACS Nano 15 (2021) 1077–1085. doi: 10.1021/acsnano.0c07972
14. [14]
  V. Kamysbayev, A.S. Filatov, H.C. Hu, et al., Science 369 (2020) 979–983. doi: 10.1126/science.aba8311
15. [15]
  Y.B. Li, H. Shao, Z.F. Lin, et al., Nat. Mater. 19 (2020) 894–899. doi: 10.1038/s41563-020-0657-0
16. [16]
  H.Y. Dong, P. Xiao, N. Jin, et al., ChemElectroChem 8 (2021) 957–962. doi: 10.1002/celc.202100142
17. [17]
  F.Y. Kong, X.D. He, Q.Q. Liu, et al., Electrochim. Acta 265 (2018) 140–150. doi: 10.1016/j.electacta.2018.01.196
18. [18]
  Z. Bao, C. Lu, X. Cao, et al., Chin. Chem. Lett. 32 (2021) 2648–2658. doi: 10.1016/j.cclet.2021.02.012
19. [19]
  Y. Xie, M. Naguib, V.N. Mochalin, et al., J. Am. Chem. Soc. 136 (2014) 6385–6394. doi: 10.1021/ja501520b
20. [20]
  Q. Tang, Z. Zhou, P. Shen, J. Am. Chem. Soc. 134 (2012) 16909–16916. doi: 10.1021/ja308463r
21. [21]
  M. Lu, H.J. Li, W.J. Han, et al., J. Energy Chem. 31 (2019) 148–153. doi: 10.1016/j.jechem.2018.05.017
22. [22]
  T. Hu, Z.J. Li, M.M. Hu, et al., J. Phys. Chem. C 121 (2017) 19254–19261. doi: 10.1021/acs.jpcc.7b05675
23. [23]
  X. Wang, X. Shen, Y. Gao, et al., J. Am. Chem. Soc. 137 (2015) 2715–2721. doi: 10.1021/ja512820k
24. [24]
  M. Li, J. Lu, K. Luo, et al., J. Am. Chem. Soc. 141 (2019) 4730–4737. doi: 10.1021/jacs.9b00574
25. [25]
  J. Halim, K.M. Cook, M. Naguib, et al., Appl. Surf. Sci. 362 (2016) 406–417. doi: 10.1016/j.apsusc.2015.11.089
26. [26]
  I. Persson, L.A. Naslund, J. Halim, et al., 2D Mater. (2018) 015002.
27. [27]
  V. Natu, M. Benchakar, C. Canaff, et al., Matter 4 (2021) 1224–1251. doi: 10.1016/j.matt.2021.01.015
28. [28]
  A.R.J. West, Solid State Chemistry and Its Applications, 2 ed., John Wiley & Sons Ltd., New York, 2014.
29. [29]
  W.Y. Chen, X.F. Jiang, S.N. Lai, D. Peroulis, L. Stanciu, Nat. Commun. 11 (2020) 1302. doi: 10.1038/s41467-020-15092-4
30. [30]
  Z.Y. Gu, J.Z. Guo, J.M. Cao, et al., Adv. Mater. (2022) 2110108. doi: 10.1002/adma.202110108
31. [31]
  M.Y. Wang, X.X. Zhao, J.Z. Guo, et al., Green Energy Environ. 7 (2022) 763–771. doi: 10.1016/j.gee.2020.11.026
1. [1]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
2. [2]
  Xiangyuan Zhao , Jinjin Wang , Jinzhao Kang , Xiaomei Wang , Hong Yu , Cheng-Feng Du . Ni nanoparticles anchoring on vacuum treated Mo2TiC2Tx MXene for enhanced hydrogen evolution activity. Chinese Journal of Structural Chemistry, 2023, 42(10): 100159-100159. doi: 10.1016/j.cjsc.2023.100159
3. [3]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
4. [4]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
5. [5]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
6. [6]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
7. [7]
  Xue Xin , Qiming Qu , Islam E. Khalil , Yuting Huang , Mo Wei , Jie Chen , Weina Zhang , Fengwei Huo , Wenjing Liu . Hetero-phase zirconia encapsulated with Au nanoparticles for boosting electrocatalytic nitrogen reduction. Chinese Chemical Letters, 2024, 35(5): 108654-. doi: 10.1016/j.cclet.2023.108654
8. [8]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
9. [9]
  Qiang Cao , Xue-Feng Cheng , Jia Wang , Chang Zhou , Liu-Jun Yang , Guan Wang , Dong-Yun Chen , Jing-Hui He , Jian-Mei Lu . Graphene from microwave-initiated upcycling of waste polyethylene for electrocatalytic reduction of chloramphenicol. Chinese Chemical Letters, 2024, 35(4): 108759-. doi: 10.1016/j.cclet.2023.108759
10. [10]
  Yuemin Chen , Yunqi Wu , Guoao Wang , Feihu Cui , Haitao Tang , Yingming Pan . Electricity-driven enantioselective cross-dehydrogenative coupling of two C(sp³)-H bonds enabled by organocatalysis. Chinese Chemical Letters, 2024, 35(9): 109445-. doi: 10.1016/j.cclet.2023.109445
11. [11]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
12. [12]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
13. [13]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
14. [14]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
15. [15]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
16. [16]
  Xiao-Tong Sun , Hao-Fei Ni , Yi Zhang , Da-Wei Fu . Hybrid perovskite shows temperature-dependent photoluminescence and dielectric response triggered by halogen substitution. Chinese Journal of Structural Chemistry, 2024, 43(6): 100212-100212. doi: 10.1016/j.cjsc.2024.100212
17. [17]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
18. [18]
  Kuan Deng , Fei Yang , Zhi-Qi Cheng , Bi-Wen Ren , Hua Liu , Jiao Chen , Meng-Yao She , Le Yu , Xiao-Gang Liu , Hai-Tao Feng , Jian-Li Li . Construction of wavelength-tunable DSE quinoline salt derivatives by regulating the hybridization form of the nitrogen atom and intramolecular torsion angle. Chinese Chemical Letters, 2024, 35(10): 109464-. doi: 10.1016/j.cclet.2023.109464
19. [19]
  Xuejie Gao , Xinyang Chen , Ming Jiang , Hanyan Wu , Wenfeng Ren , Xiaofei Yang , Runcang Sun . Long-lifespan thin Li anode achieved by dead Li rejuvenation and Li dendrite suppression for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109448-. doi: 10.1016/j.cclet.2023.109448
20. [20]
  Huimin Luan , Qinming Wu , Jianping Wu , Xiangju Meng , Feng-Shou Xiao . Templates for the synthesis of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100252-100252. doi: 10.1016/j.cjsc.2024.100252

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(266)
HTML views(33)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Lithium storage properties of Ti3C2Tx (Tx = F, Cl, Br) MXenes

Metrics

通讯作者: 陈斌, bchen63@163.com

Lithium storage properties of Ti₃C₂T_x (T_x = F, Cl, Br) MXenes