Citation: Xin-Yu Zhang, Wen-Li Yu, Jie Zhao, Jia-Yu Fu, Bin Dong, Fu-Li Wang, Jian-Feng Yu, Chen-Guang Liu, Yong-Ming Chai. Self-supported Fe_xNi_1-xMoO₄ with synergistic morphology and composition for efficient overall water splitting at large current density[J]. Chinese Chemical Letters, ;2023, 34(2): 107422. doi: 10.1016/j.cclet.2022.04.020 shu

Self-supported Fe_xNi_1-xMoO₄ with synergistic morphology and composition for efficient overall water splitting at large current density

State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China

dongbin@upc.edu.cn

ymchai@upc.edu.cn

Received Date: 18 January 2022
Revised Date: 12 February 2022
Accepted Date: 8 April 2022
Available Online: 14 April 2022

Figures(4)

Developing the high activity, low cost and robust large-current-density-based electrocatalysts is of great significance for the industrial electrolytic water splitting. However, the current range of most reported materials is small, which makes it difficult for them to play their roles in practical applications. Here, a self-supported amorphous Fe_xNi_1-xMoO₄/IF treated with ammonium fluoride (AF_0.1-FNMO/IF) is synthesized by one-step hydrothermal method. With the help of NH₄F, AF_0.1-FNMO/IF exhibits a vertically cross-linked nanosheet with spherical structure. Electrochemical measurement shows that AF_0.1-FNMO/IF affords a large current density ordeal and only need low overpotentials of 289 and 345 mV to reach a current response of 500 mA/cm² for oxygen evolution reaction and hydrogen evolution reaction, respectively, together with long-time stability (both at 500, 1000 and 2000 mA/cm²) in 1.0 mol/L KOH solution. Using it as bifunctional catalyst for overall water splitting, the current densities of 100, 500, 1000 and 1500 mA/cm² are achieved at a cell voltage of 1.71, 1.88, 1.94 and 1.97 V with excellent durability, which is much better than that of most published electrodes. The work provides valuable insight for designing higher activity nickel iron-based molybdate catalysts with large current density.
- Bimetallic molybdate,
- Bifunctional electrocatalysts,
- Overall water splitting,
- Large current density,
- Alkaline solution
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沈阳化工大学材料科学与工程学院沈阳 110142

Self-supported FexNi1-xMoO4 with synergistic morphology and composition for efficient overall water splitting at large current density

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通讯作者: 陈斌, bchen63@163.com

Self-supported Fe_xNi_1-xMoO₄ with synergistic morphology and composition for efficient overall water splitting at large current density