Citation: Zepeng Zhang, Yunyun Li, Longzhang Dong, Zhonglong Yin, Ziqi Tian, Weiben Yang, Zhen Yang. MIL-101(Cr)-decorated Ti/TiO₂ anode for electrochemical oxidation of aromatic pollutants from water[J]. Chinese Chemical Letters, ;2023, 34(2): 107404. doi: 10.1016/j.cclet.2022.04.002 shu

MIL-101(Cr)-decorated Ti/TiO₂ anode for electrochemical oxidation of aromatic pollutants from water

Zepeng Zhang ^{a, 1} ,
Yunyun Li ^{a, 1} ,
Longzhang Dong ^a ,
Zhonglong Yin ^a ,
Ziqi Tian ^b ,
Weiben Yang ^a ,
Zhen Yang ^{a, *,}

a.
School of Chemistry and Materials Science, Jiangsu Provincial Key Laboratory of Material Cycling and Pollution Control, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Nanjing Normal University, Nanjing 210046, China
b.
Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315000, China

yangzhen@njnu.edu.cn

Received Date: 17 January 2022
Revised Date: 11 February 2022
Accepted Date: 1 April 2022
Available Online: 5 April 2022

Figures(4)

Hydroxyl radicals (^•OH) generated on anode play a vital role in electrochemical oxidation (EO) of organic pollutants for water treatment. Inspired by the four-electron oxygen evolution reaction (OER), we supposed an anode-selection strategy to stabilize deeply oxidized states (*O and *OOH) which are beneficial to generating ^•OH. To verify the hypothesis, a candidate anode component (MIL-101(Cr), a well-known metal-organic framework with active variable-valence transition metal centers) was used to coat Ti/TiO₂ plate to fabricate anodes. Compared to TiO₂(101) plane on undecorated anode surface, fast and complete removal of aniline and phenol, and improved energy utilization were achieved on MIL-101(Cr)-coated-Ti/TiO₂ anode. Mechanism investigation, including pollutant degradation pathways, showed the predominate contribution (69.60%–75.13%) of ^•OH in pollutant mineralization. Density functional theory (DFT) computations indicated Cr site in MIL-101(Cr) was more conducive to stabilizing *O and *OOH, leading to thermodynamical spontaneous generation of ^•OH. This work opens up an exciting avenue to explore ^•OH production, and supplies a useful guidance to the development of anode materials for EO process.
- Active oxidation species,
- Electrocatalytic oxidation,
- DFT computation,
- MOF,
- Hydroxyl radical,
- Composite anode
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

MIL-101(Cr)-decorated Ti/TiO2 anode for electrochemical oxidation of aromatic pollutants from water

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通讯作者: 陈斌, bchen63@163.com

MIL-101(Cr)-decorated Ti/TiO₂ anode for electrochemical oxidation of aromatic pollutants from water