Citation: Qianyu Qiao, Yao Chen, Yue Wang, Yuqing Ren, Jiazhen Cao, Fengjiao Huang, Zhenfeng Bian. Surface modification of phosphate ion to promote photocatalytic recovery of precious metals[J]. Chinese Chemical Letters, ;2023, 34(2): 107394. doi: 10.1016/j.cclet.2022.03.117 shu

Surface modification of phosphate ion to promote photocatalytic recovery of precious metals

Qianyu Qiao ^{a, 1} ,
Yao Chen ^{a, b, 1} ,
Yue Wang ^a ,
Yuqing Ren ^a ,
Jiazhen Cao ^a ,
Fengjiao Huang ^a ,
Zhenfeng Bian ^{a, *,}

a.
MOE Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China
b.
Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, China

bianzhenfeng@shnu.edu.cn

Received Date: 8 January 2022
Revised Date: 19 February 2022
Accepted Date: 30 March 2022
Available Online: 2 April 2022

Figures(4)

Photocatalytic recovery, a novel precious metal recycling technology, dedicates to solving the environmental and energy consumption problems caused by traditional technologies. The activation of molecular oxygen (O₂) is one of the most critical steps in the whole process. Herein, we regulated the different adsorption intensity of oxygen on the surface by designing phosphate (PO₄³⁻) modified titanium oxide (TiO₂). The results show that the adsorption of oxygen on the photocatalyst surface is gradually enhanced, which effectively improves the dissolution rate of precious metals. PO₄³⁻ modification increased the photocatalytic dissolution rate of gold (Au) by 2.8 times. The photocatalytic activity of other precious metals dissolution (such as palladium (Pd), platinum (Pt), rhodium (Rh), ruthenium (Ru) and iridium (Ir)) was also significantly improved. It is applied to the recovery of precious metals from spent catalysts and electronic devices to significantly promote the recovery efficiency. This indicates the direction for designing more efficient photocatalysts for precious metal recovery.
- Photocatalysis,
- Precious metal recovery,
- Molecular oxygen activation,
- Carrier separation,
- Phosphate modification
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