Citation: Feihong Lu, Yi Chen, Boqiao Fu, Shigui Chen, Lu Wang. Multistimuli responsive supramolecular polymer networks via host-guest complexation of pillararene-containing polymers and sulfonium salts[J]. Chinese Chemical Letters, ;2022, 33(12): 5111-5115. doi: 10.1016/j.cclet.2022.03.103 shu

Multistimuli responsive supramolecular polymer networks via host-guest complexation of pillararene-containing polymers and sulfonium salts

Feihong Lu ^a ,
Yi Chen ^a ,
Boqiao Fu ^b ,
Shigui Chen ^{a, *,} ,
Lu Wang ^{a, *,}

a.
The Institute for Advanced Studies, Hubei Clinical Center & Key Lab of Intestinal & Colorectal Diseases, Wuhan University, Wuhan 430072, China
b.
Institute of Biomedical Materials Industry Technology, Hubei co-Innovation Center for Utilization of Biomass Waste, College of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China

sgchen@whu.edu.cn

wanglu-027@whu.edu.cn

Received Date: 23 January 2022
Revised Date: 25 March 2022
Accepted Date: 28 March 2022
Available Online: 1 April 2022

Figures(7)

A stimuli-responsive supramolecular polymer network has been constructed based on the host-guest interactions between the copolymer poly-P[5]A with pendent pillararene units and bis(sulfonium) diction guest G2. The formation mechanism of the supramolecular polymer network has been explored by the intensive study. With the addition of the competitive molecules and heating, the supramolecular polymer network could be dissociated and lead to clear changes in NMR spectroscopy and viscosity property.
- Supramolecular polymer network,
- Pillar[5]arene,
- Sulfonium salt,
- Stimuli-responsive,
- Supramolecular gel
1. [1]
  X. Yan, F. Wang, B. Zheng, F. Huang, Chem. Soc. Rev. 41 (2012) 6042–6065. doi: 10.1039/c2cs35091b
2. [2]
  X. Ma, H. Tian, Acc. Chem. Res. 47 (2014) 1971–1981. doi: 10.1021/ar500033n
3. [3]
  D. Xia, P. Wang, X. Ji, et al., Chem. Rev. 120 (2020) 6070–6123. doi: 10.1021/acs.chemrev.9b00839
4. [4]
  Y. Chen, S. Sun, D. Lu, et al., Chin. Chem. Lett. 30 (2019) 37–43. doi: 10.1016/j.cclet.2018.10.022
5. [5]
  T. Xiao, L. Zhou, X. Sun, et al., Chin. Chem. Lett. 31 (2020) 1–9. doi: 10.1016/j.cclet.2019.05.011
6. [6]
  M. Guo, L.M. Pitet, H.M. Wyss, et al., J. Am. Chem. Soc. 136 (2014) 6969–6977. doi: 10.1021/ja500205v
7. [7]
  X. Chang, Y. Geng, H. Cao, et al., Macromol. Rapid Commun. 39 (2018) 1700806. doi: 10.1002/marc.201700806
8. [8]
  X. Yan, Y. Huang, M. Cen, et al., Nanoscale Adv. 3 (2021) 1906–1909. doi: 10.1039/D0NA00938E
9. [9]
  A. Pappalardo, F.P. Ballistreri, G.L. Destri, et al., Macromolecules 45 (2012) 7549–7556. doi: 10.1021/ma3015239
10. [10]
  H. Yamaguchi, Y. Kobayashi, R. Kobayashi, et al., Nat. Commun. 3 (2012) 603. doi: 10.1038/ncomms1617
11. [11]
  Y. Cao, Y. Chen, Z. Zhang, et al., Chin. Chem. Lett. 32 (2021) 349–352. doi: 10.1016/j.cclet.2020.03.058
12. [12]
  R. Zhang, X. Yan, H. Guo, et al., Chem. Commun. 56 (2020) 948–951. doi: 10.1039/C9CC09155F
13. [13]
  S. Burattini, H.M. Colquhoun, J.D. Fox, et al., Chem. Commun. (2009) 6717–6719. doi: 10.1039/b910648k
14. [14]
  L.R. Hart, J.H. Hunter, N.A. Nguyen, et al., Polym. Chem. 5 (2014) 3680–3688. doi: 10.1039/C4PY00292J
15. [15]
  K.C. Bentz, S.M. Cohen, Angew. Chem. Int. Ed. 57 (2018) 14992–15001. doi: 10.1002/anie.201806912
16. [16]
  H. Liu, H. Peng, Y. Xin, J. Zhang, Polym. Chem. 10 (2019) 2263–2272. doi: 10.1039/C9PY00085B
17. [17]
  L. Chen, Y. Tian, Y. Ding, et al., Macromolecules 45 (2012) 8412–8419. doi: 10.1021/ma3016486
18. [18]
  X. Ji, Y. Yao, J. Li, et al., J. Am. Chem. Soc. 135 (2013) 74–77. doi: 10.1021/ja3108559
19. [19]
  W. Xia, M. Ni, C. Yao, et al., Macromolecules 48 (2015) 4403–4409. doi: 10.1021/acs.macromol.5b00889
20. [20]
  Y. Zhang, F. Chen, Y. Li, et al., Chin. J. Chem. 39 (2021) 2731–2737. doi: 10.1002/cjoc.202100325
21. [21]
  F. Zeng, Y. Shen, C. Chen, Soft Matter 9 (2013) 4875–4882. doi: 10.1039/c3sm50529d
22. [22]
  Q. Yang, P. Wang, C. Zhao, et al., Macromol. Rapid Commun. 38 (2017) 1600741. doi: 10.1002/marc.201600741
23. [23]
  L. Peng, H. Zhang, A. Feng, et al., Polym. Chem. 6 (2015) 3652–3659. doi: 10.1039/C5PY00296F
24. [24]
  K. Wang, Y. Chen, Y. Liu, Chem. Commun. 51 (2015) 1647–1649. doi: 10.1039/C4CC08721F
25. [25]
  W. Xu, Q. Song, J. Xu, et al., ACS Appl. Mater. Interfaces 9 (2017) 11368–11372. doi: 10.1021/acsami.7b02850
26. [26]
  J. Liu, C.S.Y. Tan, O.A. Scherman, Angew. Chem. Int. Ed. 57 (2018) 8854–8858. doi: 10.1002/anie.201800775
27. [27]
  T. Ogoshi, S. Kanai, S. Fujinami, et al., J. Am. Chem. Soc. 130 (2008) 5022–5023. doi: 10.1021/ja711260m
28. [28]
  T. Ogoshi, T.A. Yamagishi, Y. Nakamoto, Chem. Rev. 116 (2016) 7937–8002. doi: 10.1021/acs.chemrev.5b00765
29. [29]
  Z. Zhang, Y. Luo, B. Xia, et al., Chem. Commun. 47 (2011) 2417–2419. doi: 10.1039/C0CC03732J
30. [30]
  C. Han, G. Yu, B. Zheng, F. Huang, Org. Lett. 14 (2012) 1712–1715. doi: 10.1021/ol300284c
31. [31]
  X. Chi, M. Xue, RSC Adv. 4 (2014) 365–368. doi: 10.1039/C3RA45169K
32. [32]
  L. Shao, B. Hua, J. Liu, F. Huang, Chem. Commun. 55 (2019) 4527–4530. doi: 10.1039/C9CC01984G
33. [33]
  C. Li, L. Zhao, J. Li, et al., Chem. Commun. 46 (2010) 9016–9018. doi: 10.1039/c0cc03575k
34. [34]
  R. Wang, Y. Sun, F. Zhang, et al., Angew. Chem. Int. Ed. 56 (2017) 5294–5298. doi: 10.1002/anie.201702175
35. [35]
  J. Chang, Q. Zhao, L. Kang, et al., Macromolecules 49 (2016) 2814–2820. doi: 10.1021/acs.macromol.6b00270
36. [36]
  J. Chen, P. Chen, ACS Appl. Polym. Mater. 1 (2019) 2224–2229. doi: 10.1021/acsapm.9b00516
37. [37]
  C. Lee, J. Peng, D. Velayutham, et al., Electrochim. Acta 114 (2013) 303–308. doi: 10.1016/j.electacta.2013.09.087
38. [38]
  D.H. Hyun, P. Patil, J.Y. Kim, T.H. Kim, J. Appl. Polym. Sci. 103 (2007) 3157–3163. doi: 10.1002/app.24749
39. [39]
  C. Wang, X. Meng, Z. Li, et al., ACS Macro Lett. 9 (2020) 471–475. doi: 10.1021/acsmacrolett.0c00003
40. [40]
  D. Kaiser, I. Klose, R. Oost, et al., Chem. Rev. 119 (2019) 8701–8780. doi: 10.1021/acs.chemrev.9b00111
41. [41]
  A.D. St-Jacques, I.W. Wyman, D.H. Macartney, Chem. Commun. (2008) 4936–4938. doi: 10.1039/b811823j
42. [42]
  Y. Ling, A.E. Kaifer, Chem. Mater. 18 (2006) 5944–5949. doi: 10.1021/cm061629p
43. [43]
  P.C. Kearney, L.S. Mizoue, R.A. Kumpf, et al., J. Am. Chem. Soc. 115 (1993) 9907–9919. doi: 10.1021/ja00075a006
44. [44]
  J.C. Ma, D.A. Dougherty, Chem. Rev. 97 (1997) 1303–1324. doi: 10.1021/cr9603744
45. [45]
  C. Li, Q. Xu, J. Li, et al., Org. Biomol. Chem. 8 (2010) 1568–1576. doi: 10.1039/b920146g
46. [46]
  M.J. Frisch, G.W. Trucks, H.B. Schlegel, et al., Gaussian 09, Revision A. 02, Gaussian, Inc., Wallingford, CT, 2013.
47. [47]
  T. Lu, F. Chen, J. Comput. Chem. 33 (2012) 580–592. doi: 10.1002/jcc.22885
48. [48]
  C. Shen, Z. Gong, L. Gao, et al., J. Mol. Model. 24 (2018) 199. doi: 10.1007/s00894-018-3736-2
49. [49]
  Y. Zhang, Q. Yang, X. Ma, et al., J. Phys. Chem. A 124 (2020) 9811–9817. doi: 10.1021/acs.jpca.0c08367
50. [50]
  C. Lefebvre, G. Rubez, H. Khartabil, et al., Phys. Chem. Chem. Phys. 19 (2017) 17928–17936. doi: 10.1039/C7CP02110K
51. [51]
  L. Shao, J. Sun, B. Hua, F. Huang, Chem. Commun. 54 (2018) 4866–4869. doi: 10.1039/C8CC02077A
52. [52]
  X. Shu, S. Chen, J. Li, et al., Chem. Commun. 48 (2012) 2967–2969. doi: 10.1039/c2cc00153e
1. [1]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
2. [2]
  Huan Hu , Ying Zhang , Shi-Shuang Huang , Zhi-Gang Li , Yungui Liu , Rui Feng , Wei Li . Temperature- and pressure-responsive photoluminescence in a 1D hybrid lead halide. Chinese Journal of Structural Chemistry, 2024, 43(10): 100395-100395. doi: 10.1016/j.cjsc.2024.100395
3. [3]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
4. [4]
  Lei Zhou , Youjun Zhou , Lizhen Fang , Yiqiao Bai , Yujia Meng , Liang Li , Jie Yang , Yong Yao . Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications. Chinese Chemical Letters, 2024, 35(9): 109509-. doi: 10.1016/j.cclet.2024.109509
5. [5]
  Ting-Ting Huang , Jin-Fa Chen , Juan Liu , Tai-Bao Wei , Hong Yao , Bingbing Shi , Qi Lin . A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect. Chinese Chemical Letters, 2024, 35(7): 109281-. doi: 10.1016/j.cclet.2023.109281
6. [6]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
7. [7]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
8. [8]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
9. [9]
  Rui Wang , Yang Liang , Julius Rebek Jr. , Yang Yu . Stabilization and detection of labile reaction intermediates in supramolecular containers. Chinese Chemical Letters, 2024, 35(6): 109228-. doi: 10.1016/j.cclet.2023.109228
10. [10]
  Wenlong Li , Feishi Shan , Qingdong Bao , Qinghua Li , Hua Gao , Leyong Wang . Supramolecular assembly nanoparticle for trans-epithelial treatment of keratoconus. Chinese Chemical Letters, 2024, 35(10): 110060-. doi: 10.1016/j.cclet.2024.110060
11. [11]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
12. [12]
  Guoxing Liu , Yixin Li , Changming Tian , Yongmei Xiao , Lijie Liu , Zhanqi Cao , Song Jiang , Xin Zheng , Caoyuan Niu , Yun-Lai Ren , Liangru Yang , Xianfu Zheng , Yong Chen . Highly reversible photomodulated hydrosoluble stiff-stilbene supramolecular luminophor induced by cucurbituril. Chinese Chemical Letters, 2024, 35(8): 109403-. doi: 10.1016/j.cclet.2023.109403
13. [13]
  Xingwen Cheng , Haoran Ren , Jiangshan Luo . Boosting the self-trapped exciton emission in vacancy-ordered double perovskites via supramolecular assembly. Chinese Journal of Structural Chemistry, 2024, 43(6): 100306-100306. doi: 10.1016/j.cjsc.2024.100306
14. [14]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
15. [15]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
16. [16]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
17. [17]
  Junhan Luo , Qi Qing , Liqin Huang , Zhe Wang , Shuang Liu , Jing Chen , Yuexiang Lu . Non-contact gaseous microplasma electrode as anode for electrodeposition of metal and metal alloy in molten salt. Chinese Chemical Letters, 2024, 35(4): 108483-. doi: 10.1016/j.cclet.2023.108483
18. [18]
  Kuan Deng , Fei Yang , Zhi-Qi Cheng , Bi-Wen Ren , Hua Liu , Jiao Chen , Meng-Yao She , Le Yu , Xiao-Gang Liu , Hai-Tao Feng , Jian-Li Li . Construction of wavelength-tunable DSE quinoline salt derivatives by regulating the hybridization form of the nitrogen atom and intramolecular torsion angle. Chinese Chemical Letters, 2024, 35(10): 109464-. doi: 10.1016/j.cclet.2023.109464
19. [19]
  Kongchuan Wu , Dandan Lu , Jianbin Lin , Ting-Bin Wen , Wei Hao , Kai Tan , Hui-Jun Zhang . Elucidating ligand effects in rhodium(Ⅲ)-catalyzed arene–alkene coupling reactions. Chinese Chemical Letters, 2024, 35(5): 108906-. doi: 10.1016/j.cclet.2023.108906
20. [20]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(488)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142