Citation: Jing Zou, Yilun Zou, Haitao Wang, Wei Wang, Pingxiu Wu, Arramel, Jizhou Jiang, Xin Li. Tailoring the electronic acceptor–donor heterointerface between black phosphorus and Co₃O₄ for boosting oxygen bifunctional electrocatalysis[J]. Chinese Chemical Letters, ;2023, 34(2): 107378. doi: 10.1016/j.cclet.2022.03.101 shu

Tailoring the electronic acceptor–donor heterointerface between black phosphorus and Co₃O₄ for boosting oxygen bifunctional electrocatalysis

Jing Zou ^a ,
Yilun Zou ^a ,
Haitao Wang ^{a, *,} ,
Wei Wang ^c ,
Pingxiu Wu ^d ,
Arramel ^e ,
Jizhou Jiang ^{a, b, *,} ,
Xin Li ^{f, *,}

a.
School of Chemistry and Environmental Engineering, School of Environmental Ecology and Biological Engineering, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Hubei Tree Gorges Laboratory, Wuhan Institute of Technology, Wuhan 430205, China
b.
Key Laboratory of Rare Mineral, Ministry of Natural Resources, Geological Experimental Testing Center of Hubei Province, Wuhan 430034, China
c.
Key Laboratory of Hunan Province for Advanced Carbon-based Functional Materials, Hunan Institute of Science and Technology, Yueyang 414006, China
d.
Semiconductor Electronic Special Gas of Hubei Engineering Research Center, Jingzhou 434000, China
e.
Nano Center Indonesia, Jl. PUSPIPTEK Tangerang Selatan, Banten 15314, Indonesia
f.
Institute of Biomass Engineering, Key Laboratory of Energy Plants Resource and Utilization, Ministry of Agriculture and Rural Affairs, South China Agricultural University, Guangzhou 510642, China

wanghaitao@wit.edu.cn

027wit@163.com

xinli@scau.edu.cn

Received Date: 27 December 2021
Revised Date: 29 January 2022
Accepted Date: 25 March 2022
Available Online: 28 March 2022

Figures(4)

Black phosphorus (BP) as an uprising two-dimensional material exhibits attractive potential in the field of electrocatalysis due to the inherent advantages of high carrier mobility and abundant lone pair electrons. However, the exposed active electrons compel BP to be deactivated by oxidative degradation. Herein, the electronic signature of acceptor-donor heterointerfacial interactions between BP and Co₃O₄ is realized via wet ball milling. The preferential migration of active electrons from BP to Co₃O₄ is achieved at the heterointerface since the Fermi level of BP is higher than that of Co₃O₄. Such relative energetic consideration promotes reasonable oxygen electrocatalytic active sites. Moreover, it significantly suppresses the oxidative degradation of BP. Consequently, the resulting Co₃O₄/BP heterojunction possesses superior oxygen bifunctional electrocatalytic activity than its parent catalysts. Most importantly, this work promotes an efficient route towards BP-based multifunctional catalysts.
- Electronic acceptor-donor,
- Black phosphorus,
- Co₃O₄,
- Charge transfer,
- Oxygen bifunctional electrocatalysis
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Tailoring the electronic acceptor–donor heterointerface between black phosphorus and Co3O4 for boosting oxygen bifunctional electrocatalysis

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通讯作者: 陈斌, bchen63@163.com

Tailoring the electronic acceptor–donor heterointerface between black phosphorus and Co₃O₄ for boosting oxygen bifunctional electrocatalysis