Citation: Zeru Wang, Wenhao Li, Linzhen Wu, Zhuang Wang, Yalan Cao, Jingkai Cheng, Guangyuan Chen, Qian Zhao, Mei Jiang, Zhengguo Chen, Lin Zhu, Tao Duan. Nitrogen-rich carbon nitrogen polymers for enhancing the sorption of uranyl[J]. Chinese Chemical Letters, ;2022, 33(7): 3468-3473. doi: 10.1016/j.cclet.2022.03.097 shu

Nitrogen-rich carbon nitrogen polymers for enhancing the sorption of uranyl

Zeru Wang ^{a, b, 1} ,
Wenhao Li ^{a, b, 1} ,
Linzhen Wu ^{a, b} ,
Zhuang Wang ^c ,
Yalan Cao ^a ,
Jingkai Cheng ^{a, b} ,
Guangyuan Chen ^{a, b} ,
Qian Zhao ^{a, b, d} ,
Mei Jiang ^{a, b, d} ,
Zhengguo Chen ^e ,
Lin Zhu ^{a, b, *,} ,
Tao Duan ^{a, b, *,}

a.
National Co-Innovation Center for Nuclear Waste Disposal and Environmental Safety, Southwest University of Science and Technology, Mianyang 621010, China
b.
State Key Laboratory of Environment-friendly Energy Materials, School of National Defence Science and Technology, Southwest University of Science and Technology, Mianyang 621010, China
c.
College of Chemistry, Sichuan University, Chengdu 610064, China
d.
School of Physics and Astronomy, China West Normal University, Nanchong 637002, China
e.
NHC Key Laboratory of Nuclear Technology Medical Transformation, Mianyang Central Hospital, Mianyang 621010, China

zhulin@swust.edu.cn

duant@ustc.edu.cn

Received Date: 9 February 2022
Revised Date: 23 March 2022
Accepted Date: 23 March 2022
Available Online: 26 March 2022

Figures(6)

Nitrogen enrichment and increased nitrogen content is an effective strategy for enhancing adsorption of uranium by carbon nitride polymers. Herein, we reported the uranium absorption by using a structurally well-defined and nitrogen-rich carbon nitride polymer with C₃N₅ stoichiometry for the first time. In comparison with the adsorption performance of g-C₃N₄ for U(VI), the conjugation system of the material was increased by connecting the heptazine unit through the azo bridge in the structure of C₃N₅, so that C₃N₅ exhibited several times higher adsorption performance than that of g-C₃N₄. The C₃N₅ has high kinetics for uranyl ions, which can adsorb 100 mg/g U(VI) in only 10 min and reach complete adsorption equilibrium in 60 min; the theoretical maximum adsorption capacity is 207 mg/g, meanwhile, the material exhibits high selectivity. The results of spectral analysis and theoretical calculations indicate that the process of uranyl ion capture by C₃N₅ is a combination of physical and chemical adsorption, and its higher density of electronic states makes the electrostatic binding ability enhanced, which is favorable to the adsorption of uranyl ions by C₃N₅. This work indicates that C₃N₅ has great promise and application in the separation and enrichment of uranyl ions, and also provides a reference for the systematic investigation of the adsorption ability of nitrogen-rich carbon nitrogen polymers on uranyl ions.
- Uranium,
- Nitrogen enrichment,
- Carbon nitride,
- C₃N₅,
- Adsorption
1. [1]
  S. Chu, A. Majumdar, Nature 488 (2012) 294–303. doi: 10.1038/nature11475
2. [2]
  R. Taylor, Chem 1 (2016) 662–663. doi: 10.1016/j.chempr.2016.10.004
3. [3]
  Y. Xie, C. Chen, X. Ren, et al., Progress Mater. Sci. 103 (2019) 180–234. doi: 10.1016/j.pmatsci.2019.01.005
4. [4]
  B. Zhang, H.Y. Sun, J. Li, et al., Inorg. Chem. 58 (2019) 11622–11629. doi: 10.1021/acs.inorgchem.9b01531
5. [5]
  X. Qin, W. Yang, Y. Yang, et al., Inorg. Chem. 59 (2020) 9857–9865. doi: 10.1021/acs.inorgchem.0c01072
6. [6]
  D. Yang, S. Song, Y. Zou, et al., Chem. Eng. J. 323 (2017) 143–152. doi: 10.1016/j.cej.2017.03.158
7. [7]
  B. Zhao, L. Yuan, Y. Wang, T. Duan, W. Shi, ACS Appl. Mater. Interfaces 13 (2021) 16300–16308. doi: 10.1021/acsami.1c00364
8. [8]
  Z. Zhou, Y. Zhang, Y. Shen, S. Liu, Y. Zhang, Chem. Soc. Rev. 47 (2018) 2298–2321. doi: 10.1039/c7cs00840f
9. [9]
  W.J. Ong, L.L. Tan, Y.H. Ng, S.T. Yong, S.P. Chai, Chem. Rev. 116 (2016) 7159–7329. doi: 10.1021/acs.chemrev.6b00075
10. [10]
  G. Xiao, Y. Wang, S. Xu, et al., Chin. J. Chem. Eng. 27 (2019) 305–313. doi: 10.1016/j.cjche.2018.09.028
11. [11]
  R. Gusain, N. Kumar, S.S. Ray, Coordin. Chem. Rev. 405 (2020) 213111. doi: 10.1016/j.ccr.2019.213111
12. [12]
  C. Chang, W. Chen, Y. Chen, et al., Acta Phys. Chim. Sin. 0 (2021) 2108017-2108010. doi: 10.3866/pku.whxb202108017
13. [13]
  S.N. Talapaneni, G.P. Mane, A. Mano, et al., ChemSusChem 5 (2012) 700–708. doi: 10.1002/cssc.201100626
14. [14]
  G.P. Mane, S.N. Talapaneni, K.S. Lakhi, et al., Angew. Chem. Int. Ed. 56 (2017) 8481–8485. doi: 10.1002/anie.201702386
15. [15]
  I.Y. Kim, S. Kim, X. Jin, et al., Angew. Chem. Int. Ed. 57 (2018) 17135–17140. doi: 10.1002/anie.201811061
16. [16]
  B. Antil, L. Kumar, R. Ranjan, et al., ACS Appl. Energy Mater. 4 (2021) 3118–3129. doi: 10.1021/acsaem.0c02858
17. [17]
  B. Ren, J. Miao, S. Wang, et al., Adv. Powder Technol. 32 (2021) 1774–1784. doi: 10.1016/j.apt.2021.03.035
18. [18]
  L. Wu, X. Yang, T. Chen, et al., Chem. Eng. J. 427 (2022) 131773. doi: 10.1016/j.cej.2021.131773
19. [19]
  P. Kumar, E. Vahidzadeh, U.K. Thakur, et al., J. Am. Chem. Soc. 141 (2019) 5415–5436. doi: 10.1021/jacs.9b00144
20. [20]
  T. Wen, X. Wang, J. Wang, et al., Inorg. Chem. Front. 3 (2016) 1227–1235. doi: 10.1039/C6QI00091F
21. [21]
  Y. Zou, P. Wang, W. Yao, et al., Chem. Eng. J. 330 (2017) 573–584. doi: 10.1016/j.cej.2017.07.135
22. [22]
  L. Chen, Z. Bai, L. Zhu, et al., ACS Appl. Mater. Interfaces 9 (2017) 32446–32451. doi: 10.1021/acsami.7b12396
23. [23]
  P. Zhang, L. Wang, Z. Huang, et al., ACS Appl. Mater. Interfaces 12 (2020) 15579–15587. doi: 10.1021/acsami.0c00861
24. [24]
  B. Hu, H. Wang, R. Liu, M. Qiu, Chemosphere 274 (2021) 129743. doi: 10.1016/j.chemosphere.2021.129743
25. [25]
  S. Liu, Z. Wang, Y. Lu, et al., Appl. Catal. B Environ., 282 (2021) 119523. doi: 10.1016/j.apcatb.2020.119523
26. [26]
  H.B. Zheng, W. Chen, H. Gao, et al., J. Mater. Chem. C5 (2017) 10746–10753. doi: 10.1039/C7TC02966G
27. [27]
  V.W. Lau, M.B. Mesch, V. Duppel, et al., J. Am. Chem. Soc. 137 (2015) 1064–1072. doi: 10.1021/ja511802c
28. [28]
  H. Deng, X. Wang, L. Wang, et al., Chem. Eng. J. 401 (2020) 125977. doi: 10.1016/j.cej.2020.125977
29. [29]
  S. Kim, M. Hankel, W. Cha, et al., Nano Energy 72 (2020) 104702. doi: 10.1016/j.nanoen.2020.104702
30. [30]
  Q. Meng, X. Yang, L. Wu, et al., J. Hazard. Mater. 422 (2022) 126912. doi: 10.1016/j.jhazmat.2021.126912
31. [31]
  J. Xu, L. Zhang, R. Shi, Y. Zhu, J. Mater. Chem. A1 (2013) 14766–14772. doi: 10.1039/c3ta13188b
32. [32]
  X. Li, J. Zhang, L. Shen, et al., Appl. Phys. A94 (2008) 387–392.
33. [33]
  S.N. Talapaneni, G.P. Mane, D.H. Park, et al., J. Mater. Chem. A5 (2017) 18183–18192. doi: 10.1039/C7TA04041E
34. [34]
  J. Hu, P. Yang, C.M. Lieber, Phys. Rev. B57 (1998) R3185–R3188. doi: 10.1103/PhysRevB.57.R3185
35. [35]
  P. Chen, B. Lei, X. Dong, et al., ACS Nano 14 (2020) 15841–15852. doi: 10.1021/acsnano.0c07083
36. [36]
  H. Yu, R. Shi, Y. Zhao, et al., Adv. Mater. 29 (2017) 1605148. doi: 10.1002/adma.201605148
37. [37]
  Z. Mo, X. She, Y. Li, et al., RSC Adv. 5 (2015) 101552–101562. doi: 10.1039/C5RA19586A
38. [38]
  Q. Gu, Z. Gao, H. Zhao, et al., RSC Adv. 5 (2015) 49317–49325. doi: 10.1039/C5RA07284K
39. [39]
  P. Li, Y. Wang, J. Wang, et al., Chem. Eng. J. 414 (2021) 128810. doi: 10.1016/j.cej.2021.128810
40. [40]
  Z. Huang, Z. Li, L. Zheng, et al., Chem. Eng. J. 328 (2017) 1066–1074. doi: 10.1016/j.cej.2017.07.067
41. [41]
  K. Li, M. Li, D. Xue, J. Phys. Chem. A116 (2012) 4192–4198. doi: 10.1021/jp300603f
42. [42]
  J. Moens, G. Roos, P. Jaque, F. De Proft, P. Geerlings, Chemistry (Easton) 13 (2007) 9331–9343. doi: 10.1002/chem.200700547
43. [43]
  H. Zhang, W. Liu, A. Li, et al., Angew. Chem. Int. Ed. 58 (2019) 16110–16114. doi: 10.1002/anie.201909718
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