Citation: Liuyong Chen, Qinglin Liu, Jun Yang, Yinle Li, Guangqin Li. Thermal expansion-quench of nickel metal-organic framework into nanosheets for efficient visible light CO₂ reduction[J]. Chinese Chemical Letters, ;2023, 34(2): 107335. doi: 10.1016/j.cclet.2022.03.058 shu

Thermal expansion-quench of nickel metal-organic framework into nanosheets for efficient visible light CO₂ reduction

MOE Laboratory of Bioinorganic and Synthetic Chemistry, Lehn Institute of Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

liguangqin@mail.sysu.edu.cn

Received Date: 5 January 2022
Revised Date: 31 January 2022
Accepted Date: 14 March 2022
Available Online: 18 March 2022

Figures(4)

Metal-organic framework nanosheets (MOF NNs) offer potential opportunities for many applications, but an efficient strategy for the scalable preparation of few-layered two-dimensional (2D) MOF NNs are still a major challenge. Herein, we present an efficient top-down method for the synthesis of the Ni-BDC (Ni₂(OH)₂(1, 4-BDC); 1, 4-BDC = 1, 4-benzenedicarboxylate) nanosheets utilizing a novel thermal expansion-quench method of the flowerlike bulky MOFs in liquid N₂. The obtained Ni-BDC nanosheets exhibit significantly enhanced photocatalytic performance of reductive CO₂ deoxygenation (7.0 µmol h⁻¹ mg⁻¹) under visible light illumination compared with the bulky MOFs, due to much higher surface area for CO₂ adsorption, more abundant active sites exposed and stronger electron transport ability of the nanosheets. More importantly, this synthetic strategy can be extended to fabricate other MOF nanosheets which also exhibit significantly improved performance for deoxygenative CO₂ reduction compared to their bulky counterparts. This work may provide a guideline for preparing other 2D layered photocatalysts materials to realize energy conversion applications.
- Thermal expansion-quench,
- Metal-organic framework (MOF),
- Two-dimensional,
- Ni-BDC nanosheets,
- Visible light,
- CO₂ photoreduction
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沈阳化工大学材料科学与工程学院沈阳 110142

Thermal expansion-quench of nickel metal-organic framework into nanosheets for efficient visible light CO2 reduction

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通讯作者: 陈斌, bchen63@163.com

Thermal expansion-quench of nickel metal-organic framework into nanosheets for efficient visible light CO₂ reduction